Mesoporous Cobalt Oxalate Nanostructures as High-Performance Anode Materials for Lithium-Ion Batteries: Ex Situ Electrochemical Mechanistic Study

2013 ◽  
Vol 117 (32) ◽  
pp. 16316-16325 ◽  
Author(s):  
Wei An Ang ◽  
Yan Ling Cheah ◽  
Chui Ling Wong ◽  
Raghavan Prasanth ◽  
Huey Hoon Hng ◽  
...  
2021 ◽  
Vol 361 ◽  
pp. 115562
Author(s):  
Chunli Zhou ◽  
Dengke Wang ◽  
Hui Yang ◽  
Ang Li ◽  
Huaihe Song ◽  
...  

Author(s):  
Huitian Liu ◽  
Xu Liu ◽  
Zhaolin Liu ◽  
Junyan Tao ◽  
Xiaoqian Dai ◽  
...  

Engineering of graphite@Si/carbon composites is considered as an effective strategy to surmount the shortcomings of low conductivity and large volume expansion of bare Si anode materials for lithium-ion batteries. Nevertheless,...


Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4348
Author(s):  
Chi Zhang ◽  
Zheng Wang ◽  
Yu Cui ◽  
Xuyao Niu ◽  
Mei Chen ◽  
...  

The volume expansion during Li ion insertion/extraction remains an obstacle for the application of Sn-based anode in lithium ion-batteries. Herein, the nanoporous (np) Cu6Sn5 alloy and Cu6Sn5/Sn composite were applied as a lithium-ion battery anode. The as-dealloyed np-Cu6Sn5 has an ultrafine ligament size of 40 nm and a high BET-specific area of 15.9 m2 g−1. The anode shows an initial discharge capacity as high as 1200 mA h g−1, and it remains a capacity of higher than 600 mA h g−1 for the initial five cycles at 0.1 A g−1. After 100 cycles, the anode maintains a stable capacity higher than 200 mA h g−1 for at least 350 cycles, with outstanding Coulombic efficiency. The ex situ XRD patterns reveal the reverse phase transformation between Cu6Sn5 and Li2CuSn. The Cu6Sn5/Sn composite presents a similar cycling performance with a slightly inferior rate performance compared to np-Cu6Sn5. The study demonstrates that dealloyed nanoporous Cu6Sn5 alloy could be a promising candidate for lithium-ion batteries.


2009 ◽  
Vol 189 (1) ◽  
pp. 16-21 ◽  
Author(s):  
Zhaojun Luo ◽  
Dongdong Fan ◽  
Xianlong Liu ◽  
Huanyu Mao ◽  
Caifang Yao ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (77) ◽  
pp. 63012-63016 ◽  
Author(s):  
Yourong Wang ◽  
Wei Zhou ◽  
Liping Zhang ◽  
Guangsen Song ◽  
Siqing Cheng

A SiO2@NiO core–shell electrode exhibits almost 100% coulombic efficiency, excellent cycling stability and rate capability after the first few cycles.


2019 ◽  
Vol 833 ◽  
pp. 79-92 ◽  
Author(s):  
Nithyadharseni Palaniyandy ◽  
Funeka P. Nkosi ◽  
Kumar Raju ◽  
Kenneth I. Ozoemena

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