High-Accuracy Estimates for the Vinylidene-Acetylene Isomerization Energy and the Ground State Rotational Constants of :C═CH2

2013 ◽  
Vol 117 (46) ◽  
pp. 11679-11683 ◽  
Author(s):  
Hyunwoo Lee ◽  
Joshua H. Baraban ◽  
Robert W. Field ◽  
John F. Stanton
Keyword(s):  
Ground State ◽  
High Accuracy ◽  
Rotational Constants ◽  
Isomerization Energy

ROTATIONAL ANALYSIS OF THE β BANDS OF PHOSPHORUS MONOXIDE

1959 ◽  
Vol 37 (2) ◽  
pp. 136-143 ◽  
Author(s):  
Nand Lal Singh
Keyword(s):  
Ground State ◽  
Band System ◽  
Electronic States ◽  
Rotational Analysis ◽  
Rotational Constants ◽  
Fine Structures ◽  
Π State

The fine structures of three of the β bands of PO which occur near 3200 Å have been analyzed. The analysis shows that the upper state of this band system is a 2Σ and not a 2Π state as previously believed. The rotational constants of both electronic states have been determined and it is found that the ground state constants, previously determined from the γ bands, are incorrect.

scholarly journals The Microwave Spectrum of 3,4-Dihydro-1,2-Pyran

1985 ◽  
Vol 40 (9) ◽  
pp. 913-919
Author(s):  
Juan Carlos López ◽  
José L. Alonso
Keyword(s):  
Dipole Moment ◽  
Excited States ◽  
Ground State ◽  
Principal Axis ◽  
Microwave Spectrum ◽  
Average Intensity ◽  
Ring Conformation ◽  
Vibrationally Excited ◽  
Rotational Constants ◽  
Displacement Measurements

Abstract The rotational transitions of 3,4-dihydro-1,2-pyran in the ground state and six vibrationally excited states have been assigned. The rotational constants for the ground state (A = 5198.1847(24), B = 4747.8716(24) and C = 2710.9161(24) have been derived by fitting μa, μb and μc-type transitions. The dipole moment was determined from Stark displacement measurements to be 1.400(8) D with its principal axis components |μa| =1.240(2), |μb| = 0.588(10) and |μc| = 0.278(8) D. A model calculation to reproduce the ground state rotational constants indicates that the data are consistent with a twisted ring conformation. The average intensity ratio gives vibrational separations between the ground and excited states of the ring-bending and ring-twisting modes of ~ 178 and ~ 277 cm-1 respectively.

High accuracy measurement of the ground-state hyperfine splitting in a 113Cd+ microwave clock: erratum

2021 ◽  
Vol 46 (20) ◽  
pp. 5207
Author(s):  
K. Miao ◽  
J. W. Zhang ◽  
X. L. Sun ◽  
S. G. Wang ◽  
A. M. Zhang ◽  
...  
Keyword(s):  
Ground State ◽  
Hyperfine Splitting ◽  
High Accuracy ◽  
Accuracy Measurement ◽  
High Accuracy Measurement

High Resolution Infrared Spectra of the ν2 and 2ν1 Bands of 14N16O2

1975 ◽  
Vol 53 (19) ◽  
pp. 1902-1926 ◽  
Author(s):  
Aldée Cabana ◽  
Michel Laurin ◽  
Walter J. Lafferty ◽  
Robert L. Sams
Keyword(s):  
High Resolution ◽  
Infrared Spectra ◽  
Ground State ◽  
Equilibrium Structure ◽  
Coriolis Interaction ◽  
Rotational Constants ◽  
Average Structures

The infrared spectra of two B type bands, ν2 and 2ν1, of 14N16O2 have been recorded under high resolution. Ground state combination differences from these bands have been combined with combination differences obtained in previous studies and eight pure rotational microwave transitions to yield improved ground state rotational constants. Upper state constants and band centers for the ν2 and 2ν1 bands are also reported. The 2ν1 band contains internal intensity anomalies believed to arise from a weak Coriolis interaction with the much stronger ν1 + ν3 band. Equilibrium rotational constants have been calculated. The equilibrium structure of the molecule is: rc = 1.1945 ± 0.0005 Å and Θc = 133.85 ± 0.10°. For the sake of comparison, effective, substitution, and average structures are also reported.

Microwave Spectrum and Dipole Moment of Methylenecyclobutenone

1974 ◽  
Vol 29 (10) ◽  
pp. 1498-1500 ◽  
Author(s):  
W. Czieslik ◽  
L. Carpentier ◽  
D. H. Sutter
Keyword(s):  
Dipole Moment ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Ground State ◽  
Stark Effect ◽  
Microwave Spectrum ◽  
Least Square ◽  
Rotational Constants ◽  
Vibrational Ground State ◽  
Least Square Fit

Abstract The microwave spectrum of Methylenecyclobutenone has been investigated in the vibrational ground state in the range of 8 to 26.5 GHz. From a least square fit of 12 lines with J ≦ 4 the rotational constants have been calculated as A =5.775664±0.000009 GHz, B = 4.312314 ± 0.000007 GHz, C = 2.467814±0.000008 GHz. The inertia defect Δ = - 0.09 amuÅ2 indicates that the molecule is planar. From Stark-effect measurements the components of the molecular electric dipole moment were obtaied as |μa| = 2.04 ± 0.02 D, |μb| = 2.70±0.03 D, |μtotal| = 3.39 ± 0.05 D.

High accuracy measurement of the ground-state hyperfine splitting in a ^113Cd^+ microwave clock

2015 ◽  
Vol 40 (18) ◽  
pp. 4249 ◽  
Author(s):  
K. Miao ◽  
J. W. Zhang ◽  
X. L. Sun ◽  
S. G. Wang ◽  
A. M. Zhang ◽  
...  
Keyword(s):  
Ground State ◽  
Hyperfine Splitting ◽  
High Accuracy ◽  
Accuracy Measurement ◽  
High Accuracy Measurement
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