Tip-Enhanced Raman Spectroscopy Study of Local Interactions at the Interface of Styrene–Butadiene Rubber/Multiwalled Carbon Nanotube Nanocomposites

2013 ◽  
Vol 117 (3) ◽  
pp. 1436-1440 ◽  
Author(s):  
Toshiaki Suzuki ◽  
Xinlei Yan ◽  
Yasutaka Kitahama ◽  
Harumi Sato ◽  
Tamitake Itoh ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Carbon Nanotube ◽  
Multiwalled Carbon Nanotube ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Spectroscopy Study ◽  
Local Interactions ◽  
Multiwalled Carbon ◽  
Tip Enhanced Raman Spectroscopy ◽  
Styrene Butadiene

Nanoscale analysis of multiwalled carbon nanotube by tip-enhanced Raman spectroscopy

Carbon ◽  
2016 ◽  
Vol 99 ◽  
pp. 642-648 ◽  
Author(s):  
Songpol Chaunchaiyakul ◽  
Takeshi Yano ◽  
Kamonchanok Khoklang ◽  
Pawel Krukowski ◽  
Megumi Akai-Kasaya ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Carbon Nanotube ◽  
Multiwalled Carbon Nanotube ◽  
Multiwalled Carbon ◽  
Tip Enhanced Raman Spectroscopy

Transport characteristics of organic solvents through carbon nanotube filled styrene butadiene rubber nanocomposites: the influence of rubber–filler interaction, the degree of reinforcement and morphology

2015 ◽  
Vol 17 (17) ◽  
pp. 11217-11228 ◽  
Author(s):  
Jiji Abraham ◽  
Hanna J. Maria ◽  
Soney C. George ◽  
Nandakumar Kalarikkal ◽  
Sabu Thomas
Keyword(s):  
Carbon Nanotube ◽  
Organic Solvents ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Reinforcing Effect ◽  
Rubber Nanocomposites ◽  
Styrene Butadiene ◽  
Degree Of Reinforcement ◽  
Rubber Filler

The aim of the present work is to investigate the role of the sorption technique in analysing the compatibility and the reinforcing effect of MWCNTs as a filler in the SBR matrix.

EFFECT OF IONIC LIQUID MODIFIED MWCNT ON THE RHEOLOGICAL AND MICROSTRUCTURAL DEVELOPMENTS IN STYRENE BUTADIENE RUBBER NANOCOMPOSITES

2019 ◽  
Vol 92 (3) ◽  
pp. 531-545
Author(s):  
Jiji Abraham ◽  
Ajesh K. Zachariah ◽  
Runcy Wilson ◽  
Rigoberto Ibarra-Gómez ◽  
Rene Muller ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Large Strain ◽  
Three Dimensional ◽  
Rubber Matrix ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Multiwalled Carbon ◽  
Nonlinear Viscoelastic ◽  
Roll Mill ◽  
Styrene Butadiene

ABSTRACT Ionic liquid modified multiwalled carbon nanotube (MWCNT) based styrene–butadiene rubber (SBR) nanocomposites were prepared with the two-roll mill mixing method, and the rheological measurements were used to study the dispersion of MWCNTs on a microscopic scale and its compatibility with the SBR matrix. Viscous liquid-like rheological behavior at low MWCNT loadings and pseudo-solid-like rheological response at high MWCNT loadings were observed, showing the gradual transformation from individual structures of MWCNTs to polymer bridged MWCNT networks. A decrease in the mobility of SBR macromolecular chains by the geometric confinement of three-dimensional networks of MWCNTs further confirms the interdeveloped pseudo-solid behavior of filled composites. Dynamic viscoelasticity data have been compared with the theoretical Carreau–Yasuda equation. Transmission electron microscopy of the samples reveals that MWCNTs are randomly dispersed in the rubber matrix. Finally the nature of the filler association and its role in the nonlinear viscoelastic properties at large strain amplitudes were investigated.

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