H/D Isotopic and Temperature Effects in the Polarized IR Spectra of Hydrogen-Bond Cyclic Trimers in the Crystal Lattices of Acetone Oxime and 3,5-Dimethylpyrazole

2012 ◽  
Vol 116 (47) ◽  
pp. 11553-11567 ◽  
Author(s):  
Henryk T. Flakus ◽  
Barbara Hachuła ◽  
Aleksandra Garbacz
Keyword(s):  
Hydrogen Bond ◽  
Ir Spectra ◽  
Temperature Effects ◽  
Crystal Lattices ◽  
Acetone Oxime

Preparation and Research of Polymolybdate/Polymer Composite Membrane by Electrospinning and its Photo-Catalytic Property

2013 ◽  
Vol 395-396 ◽  
pp. 415-418
Author(s):  
Zhi Ming Zhang ◽  
Ting Ting Li ◽  
Ce Liu
Keyword(s):  
Hydrogen Bond ◽  
Ir Spectra ◽  
Composite Membrane ◽  
Phosphomolybdic Acid ◽  
Uv Spectra ◽  
Polarizing Microscopy ◽  
Optimum Parameters ◽  
Anhydrous Alcohol ◽  
Cellulosic Membrane ◽  
Strong Absorption Peak

Composite cellulosic membrane of PMMA and phosphomolybdic acid was prepared by electrospinning. During the progress, the factor of electrospinning and the optimum parameters was found out within the orthogonal combination experiment program. Then the morphology of the composite cellulosic membrane was observed by polarizing microscopy. To resolve PMMA, DMF and anhydrous alcohol were used. When their ratios were 1:1, the diameter of the fibre was the most homogeneous. During the electrospinning, the concentration of PMMA was the most important factor. When the concentrations were less then 10%, there were hardly fibres on the foil. The diameter of the fibre ranged from 0.5 to 1.2 μm along with the increment of the concentration of PMMA. The addition of phosphomolybdic acid made the diameter of the fibre decrease. IR-spectra showed that phosphomolybdic acid kept its Keggin structure, and it interacted with PMMA through hydrogen bond. The composite cellulosic membrane changed its color when imposed in bright space. UV spectra represented that the composite cellulosic membrane had a strong absorption peak at 700nm.

Aromatic amides. IX. Temperature effects on the N.M.R. spectra of substituted acetanilides

1974 ◽  
Vol 27 (12) ◽  
pp. 2617 ◽  
Author(s):  
ID Rae
Keyword(s):  
Hydrogen Bond ◽  
Chemical Shift ◽  
Benzene Ring ◽  
Intramolecular Hydrogen Bond ◽  
Temperature Effects ◽  
Dimethyl Sulphoxide ◽  
Intramolecular Hydrogen ◽  
Strong Intramolecular Hydrogen Bond ◽  
Ortho Substituent

N.m.r. spectra have been measured for several anilides in dimethyl sulphoxide solution for temperatures in the range 40-140�. The change of the N-H chemical shift with temperature depends on the nature of the ortho substituent on the benzene ring, being least when a strong intramolecular hydrogen bond is possible between the amide N-H and the ortho substituent. For 2?-nitroanilides, the 6?- proton becomes increasingly deshielded as the temperature is raised.

An infrared study of the interaction between ethyl N-(diphenylmethylene)glycinate with proton donors: comparison with N-benzylidenemethylamine

1986 ◽  
Vol 64 (12) ◽  
pp. 2305-2309 ◽  
Author(s):  
Marleen Ruysen ◽  
Thérèse Zeegers-Huyskens
Keyword(s):  
Hydrogen Bond ◽  
Ir Spectra ◽  
Equilibrium Constants ◽  
Lone Pair ◽  
Imino Group ◽  
Infrared Study ◽  
Hydrogen Bond Formation ◽  
Hydroxy Proton ◽  
Proton Donors ◽  
Intramolecular Hydrogen

The interaction between ethyl N-(diphenylmethylene)glycinate (DPG) and hydroxy proton donors or pyrrole has been investigated by ir spectrometry. The equilibrium constants, enthalpies, and entropies of complex formation have been determined in carbon tetrachloride solution and compared with the data obtained for the complexes involving N-benzylidene-methylamine and the same proton donors. The ir spectra studied mainly in the νOH, νC=N, νC=O, and νC—O regions suggest that hydrogen bond formation occurs at the N atom of the imino group and at the O atom of the carbonyl group. The results are discussed in terms of the basicity at the two acceptor sites and of the accessibility of the lone pair of electrons. The ir spectra of the solid adduct of DPG with HCl show that protonation takes place on the N atom. The protonated structure is possibly stabilized by an intramolecular hydrogen bond.

Rotational Isomers, Intramolecular Hydrogen Bond, and IR Spectra of o-Vinylphenol

2014 ◽  
Vol 81 (1) ◽  
pp. 15-22 ◽  
Author(s):  
V. P. Glazunov ◽  
D. V. Berdyshev ◽  
N. N. Balaneva ◽  
O. S. Radchenko ◽  
V. L. Novikov
Keyword(s):  
Hydrogen Bond ◽  
Ir Spectra ◽  
Intramolecular Hydrogen Bond ◽  
Rotational Isomers ◽  
Intramolecular Hydrogen
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