Study of the Thermal Stability of Supported Catalytic Nanoparticles for the Growth of Single-Walled Carbon Nanotubes with Narrow Diameter Distribution by Chemical Vapor Deposition of Methane

2012 ◽  
Vol 116 (45) ◽  
pp. 24123-24129 ◽  
Author(s):  
Pierre Petit ◽  
Diana Salem ◽  
Maoshuai He ◽  
Matthieu Paillet ◽  
Romain Parret ◽  
...  
2015 ◽  
Vol 51 (43) ◽  
pp. 8974-8977 ◽  
Author(s):  
Ranajit Ghosh ◽  
Takahiro Maruyama ◽  
Hiroki Kondo ◽  
Koji Kimoto ◽  
Takuro Nagai ◽  
...  

Single-walled carbon nanotubes with a narrow diameter distribution are grown on graphene layers via chemical vapor deposition.


Author(s):  
Matthew R. Maschmann ◽  
Placidus B. Amama ◽  
Timothy S. Fisher

The physical properties of carbon nanotubes (CNTs) make them outstanding candidates for introduction into technologies ranging from high resolution flat panel displays to nanoscale transistors. Integration of carbon nanotubes into devices, however, requires precise control over the manufacturing processes used during their synthesis. To meet the specific requirements of a given application, alignment, diameter, length and chirality of carbon nanotubes must be strictly addressed. This work demonstrates the controlled synthesis of single-walled carbon nanotubes (SWCNTs) with low amount of undesired carbonaceous species using plasma enhanced chemical vapor deposition (PECVD). This report elucidates the role of DC bias applied to the growth substrate during synthesis, including the field-enhanced alignment of SWCNTs, selectivity in the diameter distribution and selectivity of semiconducting versus metallic nanotubes. Carbon nanotubes are characterized using Raman spectroscopy and electron microscopy.


Author(s):  
Shuhei Inoue ◽  
Takeshi Nakajima ◽  
Kazuya Nomura ◽  
Yoshihiro Kikuchi

Single-walled carbon nanotubes are considered the most attractive material and a lot of synthesis processes are developed. Among these synthesis processes chemical vapor deposition processes are considered to be most suitable for macroscopic production. In many CVD processes the alcohol catalytic CVD process can be the best process because it can produce very pure nanotubes without any purification. However, cobalt is essential as a catalyst that makes the flexibility of catalysts restricted. In this paper, our investigation mainly focused on as follows: The efficiency of combined catalysts with/without cobalt. The diameter distributions against catalysts density. The electrical states of catalysts near Fermi level. Consequently, almost all of cobalt containing catalysts worked well, and the diameter distributions were proportional to the particle size. Efficient catalysts had enough states around Fermi level and the cobalt-less efficient catalyst cluster model showed the similar density of state to the cobalt cluster. Thus, noticing to the DOS, other efficient catalysts can be discovered and the diameter distribution will be controllable by adjusting temperature, a catalyst size, and a catalyst combination without any complicated techniques and facilities.


2008 ◽  
Vol 1 (1) ◽  
pp. 014001 ◽  
Author(s):  
Huaping Liu ◽  
Daisuke Takagi ◽  
Hiroshi Ohno ◽  
Shohei Chiashi ◽  
Tomohito Chokan ◽  
...  

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