An Experimental Study of the Gas-Phase Reactions of NO3 Radicals with a Series of Unsaturated Aldehydes: trans-2-Hexenal, trans-2-Heptenal, and trans-2-Octenal

2012 ◽  
Vol 116 (41) ◽  
pp. 10135-10142 ◽  
Author(s):  
Jamila Kerdouci ◽  
Bénédicte Picquet-Varrault ◽  
Régine Durand-Jolibois ◽  
Cécile Gaimoz ◽  
Jean-François Doussin
Keyword(s):  
Experimental Study ◽  
Gas Phase ◽  
Gas Phase Reactions ◽  
Unsaturated Aldehydes

An experimental study of the reactivity of the hydroxide anion in the gas phase at room temperature, and its perturbation by hydration

1981 ◽  
Vol 59 (11) ◽  
pp. 1615-1621 ◽  
Author(s):  
Scott D. Tanner ◽  
Gervase I. Mackay ◽  
Diethard K. Bohme
Keyword(s):  
Experimental Study ◽  
Proton Transfer ◽  
Gas Phase ◽  
Rate Constants ◽  
Room Temperature ◽  
Gas Phase Reactions ◽  
Flowing Afterglow ◽  
Hydroxide Anion

Flowing afterglow measurements are reported which provide rate constants and product identifications at 298 ± 2 K for the gas-phase reactions of OH− with CH3OH, C2H5OH, CH3OCH3, CH2O, CH3CHO, CH3COCH3, CH2CO, HCOOH, HCOOCH3, CH2=C=CH2, CH3—C≡CH, and C6H5CH3. The main channels observed were proton transfer and solvation of the OH−. Hydration with one molecule of H2O was observed either to reduce the rate slightly and lead to products which are the hydrated analogues of the "nude" reaction, or to stop the reaction completely, k ≤ 10−12 cm3 molecule−1 s−1. The reaction of OH−•H2O with CH3—C≡CH showed an uncertain intermediate behaviour.

An experimental study of the gas-phase reactions of the NO3 radical with three sesquiterpenes: isolongifolene, alloisolongifolene, and α-neoclovene

1999 ◽  
Vol 1 (12) ◽  
pp. 2929-2933 ◽  
Author(s):  
Carlos E. Canosa-Mas ◽  
Martin D. King ◽  
Phillip J. Scarr ◽  
Katherine C. Thompson ◽  
Richard P. Wayne
Keyword(s):  
Experimental Study ◽  
Gas Phase ◽  
Gas Phase Reactions ◽  
No3 Radical

Theoretical Study of the Gas-Phase Reactions of NO3 Radical with a Series of trans-2-Unsaturated Aldehydes: From Acrolein to trans-2-Octenal

2014 ◽  
Vol 118 (28) ◽  
pp. 5149-5155 ◽  
Author(s):  
Marie-Thérèse Rayez ◽  
Jean-Claude Rayez ◽  
Jamila Kerdouci ◽  
Bénédicte Picquet-Varrault
Keyword(s):  
Gas Phase ◽  
Theoretical Study ◽  
Gas Phase Reactions ◽  
Unsaturated Aldehydes ◽  
No3 Radical

An experimental study of the gas-phase reactions of the NO3 radical with pent-1-ene, hex-1-ene and hept-1-ene

1999 ◽  
Vol 1 (11) ◽  
pp. 2681-2685 ◽  
Author(s):  
Carlos E. Canosa-Mas ◽  
Martin D. King ◽  
Liam McDonnell ◽  
Richard P. Wayne
Keyword(s):  
Experimental Study ◽  
Gas Phase ◽  
Gas Phase Reactions ◽  
No3 Radical

Gas-Phase Reactions

1981 ◽  
Author(s):  
Victor N. Kondratiev ◽  
Evgeniĭ E. Nikitin
Keyword(s):  
Gas Phase ◽  
Gas Phase Reactions
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