Photophysical Properties, Self-Assembly Behavior, and Energy Transfer of Porphyrin-Based Functional Nanoparticles

2012 ◽  
Vol 116 (20) ◽  
pp. 11401-11407 ◽  
Author(s):  
Sadananda Mandal ◽  
Santanu Bhattacharyya ◽  
Victor Borovkov ◽  
Amitava Patra
2017 ◽  
Vol 196 ◽  
pp. 219-229 ◽  
Author(s):  
Yingjie Liu ◽  
Suqian Ma ◽  
Bin Xu ◽  
Wenjing Tian

Aggregation-induced emission (AIE) provides a new way of achieving highly efficient luminescent materials. In this contribution, the self-assembly behavior, molecular stacking structure and photophysical properties of two polymorphs of a supramolecular co-crystal (C1 and C2) are investigated. The block-like crystal C1, packed in segregated stacking with strong π–π interactions between the H and G molecules, shows weak green emission with a low efficiency (ΦF) of 2%. In comparison, the needle-like crystal C2, packed in segregated stacking with no obviously strong intermolecular interactions, shows bright yellow emission. More importantly, C1 exhibits mechanochromic behavior.


Soft Matter ◽  
2020 ◽  
Vol 16 (28) ◽  
pp. 6599-6607 ◽  
Author(s):  
Pijush Singh ◽  
Souvik Misra ◽  
Nayim Sepay ◽  
Sanjoy Mondal ◽  
Debes Ray ◽  
...  

The self-assembly and photophysical properties of 4-nitrophenylalanine (4NP) are changed with the alteration of solvent and final self-assembly state of 4NP in competitive solvent mixture and are dictated by the solvent ratio.


2021 ◽  
Author(s):  
Xinxian Ma ◽  
Jinlong Yue ◽  
Bo Qiao ◽  
LIli Zhou ◽  
Yang Gao ◽  
...  

Supramolecular fluorescent materials have attracted considerable attention in recent years since they endow specific and unique properties to materials. Nevertheless, the utilization of photo-responsive characteristics to modulate their fluorescence emission...


Author(s):  
Gourab Das ◽  
Sandeep Cherumukkil ◽  
Akhil Padmakumar ◽  
Vijay B. Banakar ◽  
Vakayil K. Praveen ◽  
...  

2021 ◽  
Author(s):  
Gourab Das ◽  
Sandeep Cherumukkil ◽  
Akhil Padmakumar ◽  
Vijay B. Banakar ◽  
Vakayil K. Praveen ◽  
...  

2021 ◽  
Author(s):  
Wei Wen ◽  
Aihua Chen

Self-assembly of amphiphilic single chain Janus nanoparticles (SCJNPs) is a novel and promising approach to fabricate assemblies with diversified morphologies. However, the experimental research of the self-assembly behavior of SCJNPs...


2020 ◽  
Vol 2020 ◽  
pp. 1-24 ◽  
Author(s):  
Carmen Cretu ◽  
Loredana Maiuolo ◽  
Domenico Lombardo ◽  
Elisabeta I. Szerb ◽  
Pietro Calandra

The involvement of metal ions within the self-assembly spontaneously occurring in surfactant-based systems gives additional and interesting features. The electronic states of the metal, together with the bonds that can be established with the organic amphiphilic counterpart, are the factors triggering new photophysical properties. Moreover, the availability of stimuli-responsive supramolecular amphiphile assemblies, able to disassemble in a back-process, provides reversible switching particularly useful in novel approaches and applications giving rise to truly smart materials. In particular, small amphiphiles with an inner distribution, within their molecular architecture, of various polar and apolar functional groups, can give a wide variety of interactions and therefore enriched self-assemblies. If it is joined with the opportune presence and localization of noble metals, whose chemical and photophysical properties are undiscussed, then very interesting materials can be obtained. In this minireview, the basic concepts on self-assembly of small amphiphilic molecules with noble metals are shown with particular reference to the photophysical properties aiming at furnishing to the reader a panoramic view of these exciting problematics. In this respect, the following will be shown: (i) the principles of self-assembly of amphiphiles that involve noble metals, (ii) examples of amphiphiles and amphiphile-noble metal systems as representatives of systems with enhanced photophysical properties, and (iii) final comments and perspectives with some examples of modern applications.


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