Pronounced Hydrogen Bonding Giving Rise to Apparent Probe Hyperpolarity in Ionic Liquid Mixtures with 2,2,2-Trifluoroethanol

2012 ◽  
Vol 116 (4) ◽  
pp. 1360-1369 ◽  
Author(s):  
Shruti Trivedi ◽  
Shubha Pandey ◽  
Sheila N. Baker ◽  
Gary A. Baker ◽  
Siddharth Pandey
Keyword(s):  
Ionic Liquid ◽  
Hydrogen Bonding ◽  
Liquid Mixtures

scholarly journals A structural investigation of ionic liquid mixtures

2016 ◽  
Vol 18 (12) ◽  
pp. 8608-8624 ◽  
Author(s):  
Richard P. Matthews ◽  
Ignacio J. Villar-Garcia ◽  
Cameron C. Weber ◽  
Jeraime Griffith ◽  
Fiona Cameron ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Hydrogen Bonding ◽  
Structural Investigation ◽  
Experimental Approach ◽  
Liquid Mixtures

The role of hydrogen bonding, π+–π+ stacking and anion–π+ interactions on the structure of ionic liquid mixtures has been elucidated through a combined theoretical and experimental approach.

Understanding the mechanism of LCST phase separation of mixed ionic liquids in water by MD simulations

2016 ◽  
Vol 18 (33) ◽  
pp. 23238-23245 ◽  
Author(s):  
Yuling Zhao ◽  
Huiyong Wang ◽  
Yuanchao Pei ◽  
Zhiping Liu ◽  
Jianji Wang
Keyword(s):  
Ionic Liquid ◽  
Hydrogen Bonding ◽  
Ionic Liquids ◽  
Phase Separation ◽  
Amino Acid ◽  
Driving Force ◽  
Md Simulations ◽  
Liquid Mixtures ◽  
Hydrogen Bonding Interaction ◽  
Bonding Interaction

Hydrogen bonding interaction between amino acid anions is the driving force for the phase separation of aqueous ionic liquid mixtures.

General Trend of Negative Transference Number in Li Salt/Ionic Liquid Mixtures

2019 ◽  
Author(s):  
Nicola Molinari ◽  
Jonathan P. Mailoa ◽  
Boris Kozinsky
Keyword(s):  
Ionic Liquid ◽  
Transference Number ◽  
Liquid Mixtures ◽  
Single Linkage ◽  
Self Diffusion ◽  
Wide Range ◽  
Single Linkage Cluster ◽  
Concentrated Solution ◽  
The One ◽  
Dynamics Simulations

We show that strong cation-anion interactions in a wide range of lithium-salt/ionic liquid mixtures result in a negative lithium transference number, using molecular dynamics simulations and rigorous concentrated solution theory. This behavior fundamentally deviates from the one obtained using self-diffusion coefficient analysis and agrees well with experimental electrophoretic NMR measurements, which accounts for ion correlations. We extend these findings to several ionic liquid compositions. We investigate the degree of spatial ionic coordination employing single-linkage cluster analysis, unveiling asymmetrical anion-cation clusters. Additionally, we formulate a way to compute the effective lithium charge that corresponds to and agrees well with electrophoretic measurements and show that lithium effectively carries a negative charge in a remarkably wide range of chemistries and concentrations. The generality of our observation has significant implications for the energy storage community, emphasizing the need to reconsider the potential of these systems as next generation battery electrolytes.<br>

Rapid relaxation NMR measurements to predict rate coefficients in ionic liquid mixtures. An examination of reaction outcome changes in a homologous series of ionic liquids

2021 ◽  
Author(s):  
Daniel C Morris ◽  
Stuart W Prescott ◽  
Jason B Harper
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Homologous Series ◽  
Rate Coefficient ◽  
Liquid Mixtures ◽  
Solvent Mixture ◽  
Rate Coefficients ◽  
Substitution Process

A series of ionic liquids based on the 1-alkyl-3-methylimidazolium cations were examined as components of the solvent mixture for a bimolecular substitution process. The effects on both the rate coefficient...

Eutectic ionic liquid mixtures and their effect on CO2 solubility and conductivity

RSC Advances ◽  
2015 ◽  
Vol 5 (63) ◽  
pp. 51407-51412 ◽  
Author(s):  
Anna S. Ivanova ◽  
Thomas Brinzer ◽  
Elliot A. Roth ◽  
Victor A. Kusuma ◽  
John D. Watkins ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Binary System ◽  
Liquid Mixtures ◽  
Short Chain ◽  
Co2 Solubility

A simple binary system of compounds resembling short-chain versions of popular ionic liquids has been shown to have alloying properties.

Computational analysis of the effect of [Tea][Ms] and [Tea][H2PO4] ionic liquids on the structure and stability of Aβ(17–42) amyloid fibrils

2021 ◽  
Vol 23 (11) ◽  
pp. 6695-6709
Author(s):  
D. Gobbo ◽  
A. Cavalli ◽  
P. Ballone ◽  
A. Benedetto
Keyword(s):  
Ionic Liquid ◽  
Hydrogen Bonding ◽  
Ionic Liquids ◽  
Liquid Water ◽  
Computational Analysis ◽  
Amyloid Fibrils ◽  
Aβ Peptides ◽  
Structure And Stability ◽  
Water Solutions ◽  
Kinetics Of

Tight coordination of peptides by organic anions driven by hydrogen bonding affects the fibrillation kinetics of Aβ peptides in ionic liquid/water solutions.

scholarly journals Two-Stage Prediction of the Effects of Imidazolium and Pyridinium Ionic Liquid Mixtures on Luciferase

Molecules ◽  
2014 ◽  
Vol 19 (5) ◽  
pp. 6877-6890 ◽  
Author(s):  
Hui-Lin Ge ◽  
Shu-Shen Liu ◽  
Bing-Xia Su ◽  
Xiang-Wei Zhu
Keyword(s):  
Ionic Liquid ◽  
Liquid Mixtures ◽  
Two Stage
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