Study of Direct Synthesis of Hydrogen Peroxide Acid Solutions at a Heat-Treated MnCl–Porphyrin/Activated Carbon Cathode from H2 and O2

2012 ◽  
Vol 116 (7) ◽  
pp. 4572-4583 ◽  
Author(s):  
Ichiro Yamanaka ◽  
Takeshi Onizawa ◽  
Hirobumi Suzuki ◽  
Noriko Hanaizumi ◽  
Naoya Nishimura ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Activated Carbon ◽  
Direct Synthesis ◽  
Acid Solutions ◽  
Carbon Cathode ◽  
Heat Treated

scholarly journals Laser-Induced Photochemical Reaction of Maleic Acid Solutions in the Presence of Hydrogen Peroxide

1997 ◽  
Vol 17 (2) ◽  
pp. 97-108 ◽  
Author(s):  
Yuichi Shimizu ◽  
Shun'ichi Sugimoto ◽  
Shunichi Kawanishi ◽  
Nobutake Suzuki
Keyword(s):  
Hydrogen Peroxide ◽  
Maleic Acid ◽  
Photochemical Reaction ◽  
Room Temperature ◽  
Direct Synthesis ◽  
Reaction Scheme ◽  
Photochemical Reactions ◽  
The Other ◽  
Acid Solutions ◽  
Selective Formation

Targeting the selective and direct synthesis of tartaric acid (TA), the photochemical reactions of maleic acid (MA) solutions containing H2O2. in various solvents have been investigated using four wavelengths in the UV region between 193 and 351 nm, with high intensity from an excimer laser. All the laser irradiations in H2O resulted in the direct synthesis of TA with lower selectivity and it was found that, with XeF-laser (351 nm) irradiation in 1,4-dioxane, TA is selectively and directly synthesized from MA containing H2O2 of lower concentration at room temperature. On the other hand, none of the irradiations in methanol, N,N-dimethylformamide, acetonitrile, and tetrahydrofuran gave the selective formation of TA. On the basis of these results, the reaction scheme for the selective formation of TA is discussed.

Direct synthesis of hydrogen peroxide from hydrogen and oxygen over activated-carbon-supported Pd–Ag alloy catalysts

2016 ◽  
Vol 6 (3) ◽  
pp. 809-817 ◽  
Author(s):  
Junjie Gu ◽  
Suli Wang ◽  
Zhiyuan He ◽  
You Han ◽  
Jinli Zhang
Keyword(s):  
Hydrogen Peroxide ◽  
Activated Carbon ◽  
Direct Synthesis ◽  
Carbon Support ◽  
Electronic Effects ◽  
Alloy Catalysts ◽  
Supported Pd

A series of bimetallic PdAg catalysts on an activated carbon support were prepared for the direct synthesis of hydrogen peroxide from hydrogen and oxygen. The addition of Ag to Pd caused an increase in selectivity due to ensemble and electronic effects.

Oxidation of ethylenediphosphinetetraacetate anions

1983 ◽  
Vol 48 (9) ◽  
pp. 2604-2608
Author(s):  
Jana Podlahová ◽  
Jaroslav Podlaha
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Peroxide ◽  
Electronic Structure ◽  
Acid Solutions ◽  
Tetraacetic Acid ◽  
Single Product ◽  
Weakly Acid ◽  
Inhibiting Effect ◽  
Oxidation By Molecular Oxygen ◽  
Protonated Forms

The oxidation of the ethylenediphosphinetetraacetate anion and its protonated forms by iodine, periodate, hydrogen peroxide, and oxygen has been studied in aqueous solution. The oxidation by the first three reagents is fast and yields a single product, bis(phosphine oxide), which has been isolated and characterized as ethylenebis(phosphinyl)tetraacetic acid. The oxidation by molecular oxygen proceeds considerably more slowly; in weakly acid solutions its rate is determined by the properties of the oxygen rather than by the electronic structure of the various protonated substrate species. The inhibiting effect of the phosphonium structures takes place only in strongly acid solutions.

A review on research progress in the direct synthesis of hydrogen peroxide from hydrogen and oxygen: noble-metal catalytic method, fuel-cell method and plasma method

2016 ◽  
Vol 6 (6) ◽  
pp. 1593-1610 ◽  
Author(s):  
Yanhui Yi ◽  
Li Wang ◽  
Gang Li ◽  
Hongchen Guo
Keyword(s):  
Hydrogen Peroxide ◽  
Fuel Cell ◽  
Noble Metal ◽  
Direct Synthesis ◽  
Research Progress ◽  
Pd Catalyst ◽  
Catalytic Method ◽  
Plasma Method ◽  
Cell Method ◽  
Plasma Methods

The direct synthesis of H2O2 from H2 and O2 using Pd catalyst, fuel cell and plasma methods have been reviewed systematically.

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