Intramolecular Hypervalent Interaction in the Conjugate Five-Membered Rings

2011 ◽  
Vol 115 (45) ◽  
pp. 12973-12982 ◽  
Author(s):  
Alexey A. Milov ◽  
Ruslan M. Minyaev ◽  
Vladimir I. Minkin
Keyword(s):  
Hypervalent Interaction

scholarly journals Interligand Hypervalent Interaction in the Bis(silyl) Hydride Derivatives of NioboceneJ.Am.Chem.Soc.1995,117, 10133

1996 ◽  
Vol 118 (26) ◽  
pp. 6333-6333 ◽  
Author(s):  
Georgii I. Nikonov ◽  
Ludmila G. Kuzmina ◽  
Dmitry A. Lemenovskii ◽  
Vasily V. Kotov
Keyword(s):  
Hypervalent Interaction ◽  
Derivatives Of

2-Acylidene-3,5-diaryl-2,3-dihydro-1,3,4-thiadiazoles and related compounds: a question of hypervalent S … O interactions

1993 ◽  
Vol 71 (4) ◽  
pp. 561-571 ◽  
Author(s):  
Naresh Pandya ◽  
Anthony J. Basile ◽  
Ajay K. Gupta ◽  
Patrick Hand ◽  
Cindy L. MacLaurin ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Carbonyl Oxygen ◽  
Side Chain ◽  
Molecular Mechanics Calculations ◽  
New Synthesis ◽  
Cell Dimensions ◽  
Thiadiazole Ring ◽  
Hypervalent Interaction ◽  
Related Compounds ◽  
Selective Deacetylation

A new synthesis of 1 by selective deacetylation of 2 is reported. The acylation step implied in earlier syntheses of 1 and related compounds is exemplified by direct acylations of 3 to give 4a and 4b. Several new 2-acylidene-3-(2,4-dibromophenyl)-5-phenyl-2,3-dihydro-1,3,4-thiadiazoles (11) and thioacylidene analogues (12) are described. The crystal structures of 11a, 11b, 11c, and 11d reveal a hypervalent interaction, ca. 2.45–2.7 Å long, between the sulfur and carbonyl oxygen atoms. The dibromophenyl ring is nearly perpendicular to the thiadiazole ring plane in the crystal structures, and NMR data suggest that this conformation is maintained in solution. Molecular mechanics calculations show that the S … O interaction need only be a few kilocalories in order to stabilize the observed acylidene side chain configuration over other possible isomers. Crystals of 11a are triclinic, [Formula: see text] with cell dimensions a = 12.937(2), b = 13.429(2), c = 13.489(2) Å, α = 60.14(1)°, β = 74.59(1)°, γ = 58.70(1)°, Z = 4, and R = 0.044 for 3287 observed reflections. Crystals of 11b are monoclinic, P21/c, with cell dimensions a = 10.512(1), b = 12.084(2), c = 16.268(4) Å, β = 96.91(1)°, Z = 4, R = 0.050 for 1938 observed reflections. Crystals of 11c are monoclinic, P21/c, with cell dimensions a = 17.492(4), b = 16.979(1), c = 14.962(1) Å, β = 106.46(1)°, Z = 8, R = 0.057 for 3112 observed reflections. Crystals of 11d are monoclinic, P21/c, with cell dimensions a = 11.749(1), b = 8.533(1), c = 22.670(4) Å, β = 100.17(1)°, Z = 4, and R = 0.059 for 2265 observed reflections.

Interligand Hypervalent Interaction in the Bis(silyl) Hydride Derivatives of Niobocene

1995 ◽  
Vol 117 (40) ◽  
pp. 10133-10134 ◽  
Author(s):  
Georgii I. Nikonov ◽  
Ludmila G. Kuzmina ◽  
Dmitry A. Lemenovskii ◽  
Vasily V. Kotov
Keyword(s):  
Hypervalent Interaction ◽  
Derivatives Of

scholarly journals Methyl (2Z)-2-{(2Z)-3-[(cyclopentylidene)amino]-4-oxo-2-phenylimino-1,3-thiazolidin-5-ylidene}acetate

2014 ◽  
Vol 70 (3) ◽  
pp. o366-o367 ◽  
Author(s):  
Joel T. Mague ◽  
Mehmet Akkurt ◽  
Shaaban K. Mohamed ◽  
Alaa A. Hassan ◽  
Mustafa R. Albayati
Keyword(s):  
Molecular Conformation ◽  
Ester Group ◽  
Thiazole Ring ◽  
Maximum Deviation ◽  
Stacking Interactions ◽  
Compound C ◽  
Twist Conformation ◽  
Centroid Distance ◽  
Cyclopentane Ring ◽  
Hypervalent Interaction

In the title compound, C17H17N3O3S, the thiazole ring is nearly planar [maximum deviation = 0.015 (1) Å for the ring N atom] and the cyclopentane ring has a twist conformation. The molecular conformation is stabilized by a hypervalent interaction between the S atom and the ester group carbonyl O atom, with an S...O distance of 2.7931 (10) Å. In the crystal, C—H...O interactions generate chains of molecules propagating along [110] and π–π stacking interactions [centroid–centroid distance = 3.4677 (7) Å] between the thiazole rings organize these chains into (001) layers.

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