Impact of Nanoclay on Isothermal Cold Crystallization Kinetics and Polymorphism of Poly(l-Lactic Acid) Nanocomposites

2011 ◽  
Vol 115 (31) ◽  
pp. 9556-9563 ◽  
Author(s):  
Nadarajah Vasanthan ◽  
Hoang Ly ◽  
Subhas Ghosh
Keyword(s):  
Lactic Acid ◽  
Crystallization Kinetics ◽  
Cold Crystallization

scholarly journals Nonisothermal Cold Crystallization Kinetics of Poly(lactic acid)/Bacterial Poly(hydroxyoctanoate) (PHO)/Talc

2019 ◽  
Vol 17 (1) ◽  
pp. 1266-1278
Author(s):  
Omaima Alhaddad ◽  
Safaa H. El-Taweel ◽  
Yasser Elbahloul
Keyword(s):  
Thermal Stability ◽  
Lactic Acid ◽  
Crystallization Kinetics ◽  
Crystallization Rate ◽  
Cold Crystallization ◽  
Poly Lactic Acid ◽  
Gravimetric Analysis ◽  
Scanning Calorimetry ◽  
Kinetics Of ◽  
Thermal Stability Of

AbstractThe effects of bacterial poly(hydroxyoctanoate) (PHO) and talc on the nonisothermal cold crystallization behaviours of poly(lactic acid) (PLA) were analysed with differential scanning calorimetry (DSC), and the thermal stability of the samples was observed with thermal gravimetric analysis (TGA). The modified Avrami’s model was used to describe the nonisothermal cold crystallization kinetics of neat PLA and its blends. The activation energies E for nonisothermal cold crystallization were calculated by the isoconversional method of Kissinger-Akahira-Sunose (KAS). The DSC results showed that the PLA/PHO blends were immiscible in the whole studied range, and as the PHO and talc content increased, the crystallization rate of PLA accelerated, and the crystallinity of PLA in the PLA samples increased. The values of the Avrami exponent indicated that the nonisothermal cold crystallization of the neat PLA and its blends exhibited heterogeneous, three-dimensional spherulitic growth. The E values were strongly dependent on PHO and talc. The TGA results showed that the presence of PHO and talc slightly influenced the thermal stability of PLA.

Isothermal cold crystallization kinetics of borassus powder/poly(lactic acid) biocomposites

2020 ◽  
Vol 3 (1) ◽  
Author(s):  
Yogesh Nana Marathe ◽  
Chellaswamy Ramesh ◽  
Manohar Virupax Badiger
Keyword(s):  
Lactic Acid ◽  
Crystallization Kinetics ◽  
Cold Crystallization ◽  
Poly Lactic Acid ◽  
Kinetics Of

Crystallization kinetics of poly (L-lactic acid)/montmorillonite nanocomposites under isothermal crystallization condition

2011 ◽  
Vol 124 (3) ◽  
pp. 2216-2226 ◽  
Author(s):  
Jiunn-Jer Hwang ◽  
Su-Mei Huang ◽  
Hsin-Jiant Liu ◽  
Hawn-Chung Chu ◽  
Li-Huei Lin ◽  
...  
Keyword(s):  
Lactic Acid ◽  
Crystallization Kinetics ◽  
Isothermal Crystallization ◽  
Crystallization Condition ◽  
Kinetics Of ◽  
Montmorillonite Nanocomposites

The role of cold crystallization of homochiral crystallites in the superb heat resistant poly(lactic acid)

2020 ◽  
Vol 31 (5) ◽  
pp. 1077-1087 ◽  
Author(s):  
Caixia Zhao ◽  
Miaomiao Yu ◽  
Qicheng Fan ◽  
Guoxiang Zou ◽  
Jinchun Li
Keyword(s):  
Lactic Acid ◽  
Cold Crystallization ◽  
Poly Lactic Acid ◽  
Heat Resistant
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