Screening Metal–Organic Frameworks by Analysis of Transient Breakthrough of Gas Mixtures in a Fixed Bed Adsorber

2011 ◽  
Vol 115 (26) ◽  
pp. 12941-12950 ◽  
Author(s):  
Rajamani Krishna ◽  
Jeffrey R. Long
Keyword(s):  
Metal Organic Frameworks ◽  
Fixed Bed ◽  
Gas Mixtures ◽  
Metal Organic

Metal–organic frameworks for the removal of the emerging contaminant atenolol under real conditions

2021 ◽  
Vol 50 (7) ◽  
pp. 2493-2500
Author(s):  
Sara Rojas ◽  
Jorge A. R. Navarro ◽  
Patricia Horcajada
Keyword(s):  
Continuous Flow ◽  
Metal Organic Frameworks ◽  
Fixed Bed ◽  
Emerging Contaminant ◽  
Flow Conditions ◽  
Metal Organic ◽  
Fixed Bed System

A defective Metal-Organic Frameworks as an improved material for the construction of a fixed-bed system working under continuous flow conditions for the removal of the emerging contaminant atenolol.

scholarly journals Screening metal–organic frameworks for mixture separations in fixed-bed adsorbers using a combined selectivity/capacity metric

RSC Advances ◽  
2017 ◽  
Vol 7 (57) ◽  
pp. 35724-35737 ◽  
Author(s):  
Rajamani Krishna
Keyword(s):  
Metal Organic Frameworks ◽  
Fixed Bed ◽  
Metal Organic

For screening purposes, mixture separations with MOFs are evaluated on the basis of a combined selectivity/capacity metric.

scholarly journals Influence of Co-adsorbates on CO2 induced phase transition in functionalized pillared-layered metal–organic frameworks

2016 ◽  
Vol 4 (33) ◽  
pp. 12963-12972 ◽  
Author(s):  
Andreas Schneemann ◽  
Yukiko Takahashi ◽  
Robin Rudolf ◽  
Shin-ichiro Noro ◽  
Roland A. Fischer
Keyword(s):  
Phase Transition ◽  
Gas Separation ◽  
Metal Organic Frameworks ◽  
Co Adsorption ◽  
Gas Mixtures ◽  
Metal Organic ◽  
Separation Behavior

Co-adsorption measurements reveal the flexible and gas separation behavior of functionalized pillared-layered MOFs when exposed to gas mixtures.

scholarly journals Methodologies for evaluation of metal–organic frameworks in separation applications

RSC Advances ◽  
2015 ◽  
Vol 5 (64) ◽  
pp. 52269-52295 ◽  
Author(s):  
Rajamani Krishna
Keyword(s):  
Metal Organic Frameworks ◽  
Fixed Bed ◽  
Separation Performance ◽  
Uptake Capacity ◽  
Adsorption Selectivity ◽  
Diffusion Limitations ◽  
Number Of Factors ◽  
Metal Organic ◽  
B Uptake

The separation performance of fixed-bed adsorbers is governed by a number of factors that include (a) adsorption selectivity, (b) uptake capacity, and (c) intra-crystalline diffusion limitations.

scholarly journals Predicting adsorption selectivities from pure gas isotherms for gas mixtures in metal–organic frameworks

2020 ◽  
Vol 11 (3) ◽  
pp. 643-655 ◽  
Author(s):  
Arpan Kundu ◽  
Kaido Sillar ◽  
Joachim Sauer
Keyword(s):  
Geometric Mean ◽  
Metal Organic Frameworks ◽  
Gas Mixtures ◽  
Mixing Rule ◽  
Lateral Interactions ◽  
Solution Theory ◽  
Ideal Adsorbed Solution Theory ◽  
Metal Organic ◽  
Adsorbed Solution ◽  
Adsorbed Solution Theory

A new mixing rule (geometric mean) is proposed with substantial improvements compared to the widely used ideal adsorbed solution theory for adsorbates with strong lateral interactions.

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