Effects of Solvent Structure on Interfacial Polarity at Strongly Associating Silica/Alcohol Interfaces

2011 ◽  
Vol 115 (19) ◽  
pp. 9637-9643 ◽  
Author(s):  
A. Renee Siler ◽  
Robert A. Walker
Keyword(s):  
Solvent Structure ◽  
Interfacial Polarity

Kinetics and mechanism of redox reactions of U(III) ions with monochloroacetic and dichloroacetic acids

1979 ◽  
Vol 44 (2) ◽  
pp. 401-405 ◽  
Author(s):  
Ľubica Adamčíková ◽  
Ľudovít Treindl
Keyword(s):  
Redox Reactions ◽  
Reaction Rate ◽  
Activation Parameters ◽  
Outer Sphere ◽  
Alcohol Concentration ◽  
Kinetics And Mechanism ◽  
Solvent Structure ◽  
Influence Of Ph ◽  
Sphere Mechanism

The kinetics and mechanism of the redox reactions of U3+ ions with mono- and dichloroacetic acids were studied. The influence of pH was observed mainly in the second case and led to the determination of the rate constants and activation parameters corresponding to two parallel steps, namely oxidation of U3+ with CHCl2COO- ions and oxidation of U3+ with CHCl2.COOH molecules. The influence of binary mixtures of water with methanol, ethanol, isopropanol, or tert-butenol on the reaction rate was followed. Increasing alcohol concentration influences the rate constant not only through changing dielectric constant and solvation of the reactants but also through a change of the solvent structure which plays a role in reactions with an outer sphere mechanism of the electron transfer.

scholarly journals Solvent Structure and Hammerhead Ribozyme Catalysis

2008 ◽  
Vol 15 (4) ◽  
pp. 332-342 ◽  
Author(s):  
Monika Martick ◽  
Tai-Sung Lee ◽  
Darrin M. York ◽  
William G. Scott
Keyword(s):  
Hammerhead Ribozyme ◽  
Solvent Structure

Contributions of higher-order proximal distribution functions to solvent structure around proteins

2021 ◽  
Vol 155 (10) ◽  
pp. 104110
Author(s):  
Razie Yousefi ◽  
Gillian C. Lynch ◽  
Madeline Galbraith ◽  
B. Montgomery Pettitt
Keyword(s):  
Higher Order ◽  
Distribution Functions ◽  
Solvent Structure

Voronoi polyhedra and solvent structure for aqueous solutions (III)

1982 ◽  
Vol 77 (12) ◽  
pp. 6251-6254 ◽  
Author(s):  
Elaine Eisler David ◽  
Carl W. David
Keyword(s):  
Aqueous Solutions ◽  
Solvent Structure ◽  
Voronoi Polyhedra

Research on the Effect of the Solvent Structure and Group on Separation of 1-Hexene, Benzene, and Thiophene

2019 ◽  
Vol 33 (6) ◽  
pp. 5162-5172 ◽  
Author(s):  
Yuhao Zhang ◽  
Haoran Gao ◽  
Mengxuan Wang ◽  
Liang Zhao ◽  
Jinsen Gao ◽  
...  
Keyword(s):  
Solvent Structure
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