Two-Photon Study on the Electronic Interactions between the First Excited Singlet States in Carotenoid−Tetrapyrrole Dyads

2011 ◽  
Vol 115 (16) ◽  
pp. 4082-4091 ◽  
Author(s):  
Pen-Nan Liao ◽  
Smitha Pillai ◽  
Devens Gust ◽  
Thomas A. Moore ◽  
Ana L. Moore ◽  
...  
Keyword(s):  
Excited Singlet ◽  
Electronic Interactions ◽  
Two Photon ◽  
Singlet States ◽  
Excited Singlet States

Quasiparticle Excitations in Polyenes and Polyacetylene

1987 ◽  
Vol 109 ◽  
Author(s):  
Paul Tavan ◽  
Klaus Schulten
Keyword(s):  
Dispersion Relations ◽  
Excited Singlet ◽  
Quasi Particle ◽  
Double Excitation ◽  
Singlet States ◽  
Excited Singlet States ◽  
Electron Excitations ◽  
Quasiparticle Excitations

ABSTRACTWe apply the Pariser-Parr-Pople Hamiltonian to study many-electron excitations in polyenes and polyacetylene. The excited singlet states of polyenes, calculated by a multireference double excitation expansion, are classified as quasi-particle excitations, namely as triplet-triplet magnons and particle-hole excitons. From finite polyene spectra we derive approximate dispersion relations for these quasi-particles in the infinite polyene, i.e. polyacetylene.

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