Vertical Conducting Nanodomains Self-Assembled from Poly(3-hexyl thiophene)-Based Diblock Copolymer Thin Films

2011 ◽  
Vol 115 (10) ◽  
pp. 4228-4234 ◽  
Author(s):  
Yun Jae Lee ◽  
Se Hyun Kim ◽  
Hoichang Yang ◽  
Mi Jang ◽  
Seung Sang Hwang ◽  
...  
Keyword(s):  
Thin Films ◽  
Diblock Copolymer ◽  
Self Assembled

Electrochemically Triggered Selective Adsorption of Biotemplated Nanoparticles on Self-Assembled Organometallic Diblock Copolymer Thin Films

2012 ◽  
Vol 22 (15) ◽  
pp. 3273-3278 ◽  
Author(s):  
Jean-Charles Eloi ◽  
Sarah E. Ward Jones ◽  
Veronika Poór ◽  
Mitsuhiro Okuda ◽  
Jessica Gwyther ◽  
...  
Keyword(s):  
Thin Films ◽  
Diblock Copolymer ◽  
Selective Adsorption ◽  
Self Assembled

Investigation of Diblock Copolymer thin film Morphology for Nanolithography

1996 ◽  
Vol 461 ◽  
Author(s):  
Miri Park ◽  
Christopher Harrison ◽  
Paul M. Chaikin ◽  
Richard A. Register ◽  
Douglas Adamson ◽  
...  
Keyword(s):  
Thin Films ◽  
Silicon Nitride ◽  
Diblock Copolymer ◽  
Diblock Copolymers ◽  
Microphase Separation ◽  
Large Area ◽  
Etching Technique ◽  
Copolymer Films ◽  
Self Assembled ◽  
Self Assembled Layer

ABSTRACTThe microphase separated morphology of diblock copolymers can be used to generate well-ordered nanometer scale patterns over a large area. To achieve this goal, it is important to understand and control the behavior of diblock copolymer thin films on substrates, which can differ from the bulk behavior. We have investigated the morphologies and ordering in thin polystyrene-polybutadiene (PS-PB) diblock copolymer films on bare silicon and silicon nitride substrates, and also on polymethylmethacrylate (PMMA) coated substrates. The PS-PB copolymers are synthesized to form, in bulk, PB cylinders or spheres in a PS matrix. In thin films (10–60 nm thick), prepared by spin-coating, we observe that the morphology and ordering of the microdomains are affected by strong wetting constraints and a reduced chain mobility on the substrate. The thinnest self-assembled layer of the copolymer films shows no in-plane microphase separation on both types of substrates. The PS blocks wet the PMMA substrates whereas the PB blocks wet the bare substrates as well as the air interface. Hence, different film thicknesses are necessary on the two types of substrates to obtain a uniform film of the first self-assembled cylindrical or spherical microdomain layer. The first layer of the cylindrical copolymer can vary from cylindrical to spherical morphology with a few nanometer decrease in film thickness. In the case of spherical PS-PB diblock copolymer films, we observe that the ordering of the microdomains is improved in the films on the PMMA substrates, compared to those on the bare substrates. We also demonstrate a successful transfer of the microdomain patterns to silicon nitride substrates by a reactive ion etching technique.

Self-assembled diblock copolymer thin films for the analysis of bacteria-surface interactions

2008 ◽  
Author(s):  
Shuyan Li ◽  
Andras Komaromy ◽  
Reinhard I. Boysen ◽  
Dan V. Nicolau ◽  
Milton T. W. Hearn
Keyword(s):  
Thin Films ◽  
Diblock Copolymer ◽  
Surface Interactions ◽  
Self Assembled

Self-assembled Monolayers Preparation and Characterization of BiFeO3 Thin Films

2009 ◽  
Vol 25 (1) ◽  
pp. 83-86 ◽  
Author(s):  
Guo-Qiang TAN ◽  
Hai-Yang BO ◽  
Hong-Yan MIAO ◽  
Ao XIA ◽  
Zhong-Liang HE
Keyword(s):  
Thin Films ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Growth Modulation of Super‐Tetragonal PbTiO 3 Thin Films with Self‐Assembled Nanocolumn Structures

2021 ◽  
pp. 2100547
Author(s):  
Zeyu Zhang ◽  
Yanzhu Dai ◽  
Zhipeng Li ◽  
Lu Lu ◽  
Xin Zhang ◽  
...  
Keyword(s):  
Thin Films ◽  
Growth Modulation ◽  
Self Assembled

Nanoporous Thin Films Formed from Photocleavable Diblock Copolymers on Gold Substrates Modified with Thiolate Self-Assembled Monolayers

Langmuir ◽  
2020 ◽  
Vol 36 (31) ◽  
pp. 9259-9268 ◽  
Author(s):  
Takashi Ito ◽  
Herman Coceancigh ◽  
Yi Yi ◽  
Jay N. Sharma ◽  
Fred C. Parks ◽  
...  
Keyword(s):  
Thin Films ◽  
Diblock Copolymers ◽  
Self Assembled Monolayers ◽  
Gold Substrates ◽  
Assembled Monolayers ◽  
Self Assembled
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