Nonequilibrium Phenomena in Charge Recombination of Excited Donor−Acceptor Complexes and Free Energy Gap Law

2010 ◽  
Vol 114 (50) ◽  
pp. 12998-13004 ◽  
Author(s):  
Vladislav V. Yudanov ◽  
Valentina A. Mikhailova ◽  
Anatoly I. Ivanov
Keyword(s):  
Free Energy ◽  
Energy Gap ◽  
Charge Recombination ◽  
Nonequilibrium Phenomena ◽  
Energy Gap Law ◽  
Donor Acceptor

scholarly journals The effect of solvent relaxation time constants on free energy gap law for ultrafast charge recombination following photoinduced charge separation

2018 ◽  
Vol 17 (5) ◽  
pp. 607-616 ◽  
Author(s):  
Valentina A. Mikhailova ◽  
Roman E. Malykhin ◽  
Anatoly I. Ivanov
Keyword(s):  
Free Energy ◽  
Charge Separation ◽  
Energy Gap ◽  
Charge Recombination ◽  
Solvent Relaxation ◽  
Equilibrium Mode ◽  
Energy Gap Law ◽  
Photoinduced Charge Separation ◽  
Relaxation Time Constants ◽  
Photoinduced Charge

Ultrafast low exergonic charge recombination following photoinduced charge separation proceeds in a non-equilibrium mode and its rate constant is nearly independent of the free energy gap.

Diffusional distortion of the free‐energy gap law

1995 ◽  
Vol 103 (18) ◽  
pp. 7927-7933 ◽  
Author(s):  
A. I. Burshtein
Keyword(s):  
Free Energy ◽  
Energy Gap ◽  
Energy Gap Law

Free Energy Gap Law under Diffusion Control

1996 ◽  
Vol 100 (8) ◽  
pp. 3005-3015 ◽  
Author(s):  
A. I. Burshtein ◽  
E. Krissinel
Keyword(s):  
Free Energy ◽  
Energy Gap ◽  
Diffusion Control ◽  
Energy Gap Law

A diffusional alternative to the Marcus free energy gap law

2007 ◽  
Vol 9 (3) ◽  
pp. 396-400 ◽  
Author(s):  
Anatoly I. Burshtein ◽  
Anatoly I. Ivanov
Keyword(s):  
Free Energy ◽  
Energy Gap ◽  
Energy Gap Law
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