Hydrogen Bonding Interactions between a Representative Pyridinium-Based Ionic Liquid [BuPy][BF4] and Water/Dimethyl Sulfoxide

2010 ◽  
Vol 114 (26) ◽  
pp. 8689-8700 ◽  
Author(s):  
Nan-Nan Wang ◽  
Qing-Guo Zhang ◽  
Fu-Gen Wu ◽  
Qing-Zhong Li ◽  
Zhi-Wu Yu
Keyword(s):  
Ionic Liquid ◽  
Hydrogen Bonding ◽  
Dimethyl Sulfoxide ◽  
Hydrogen Bonding Interactions

The effect of introducing an ether group into an imidazolium-based ionic liquid in binary mixtures with DMSO

2020 ◽  
Vol 22 (27) ◽  
pp. 15734-15742 ◽  
Author(s):  
Yu Zhou ◽  
Xianzhen Xu ◽  
Zonghua Wang ◽  
Shida Gong ◽  
Hong Chen ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Hydrogen Bonding ◽  
Dimethyl Sulfoxide ◽  
Binary Mixtures ◽  
Ether Group ◽  
Hydrogen Bonding Interactions

Combined DFT and FTIR investigations reveal interesting hydrogen bonding interactions between dimethyl sulfoxide and an ether-functionalized imidazolium-based ionic liquid.

Hydrogen-bonding interactions between a pyridinium-based ionic liquid [C4Py][SCN] and dimethyl sulfoxide

2015 ◽  
Vol 121 ◽  
pp. 169-179 ◽  
Author(s):  
Hongyan He ◽  
Hui Chen ◽  
Yanzhen Zheng ◽  
Suojiang Zhang ◽  
Zhiwu Yu
Keyword(s):  
Ionic Liquid ◽  
Hydrogen Bonding ◽  
Dimethyl Sulfoxide ◽  
Hydrogen Bonding Interactions

scholarly journals Crystal structure of chlorido(dimethyl sulfoxide-κS)bis[4-(pyridin-2-yl)benzaldehyde-κ3C2,N]iridium(III) acetonitrile monosolvate

2017 ◽  
Vol 73 (9) ◽  
pp. 1279-1281 ◽  
Author(s):  
Andrew J. Peloquin ◽  
Madelyn B. Smith ◽  
Gary J. Balaich ◽  
Scott T. Iacono
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Dimethyl Sulfoxide ◽  
Coordination Sphere ◽  
Title Compound ◽  
Octahedral Coordination ◽  
Distorted Octahedral Coordination ◽  
Hydrogen Bonding Interactions ◽  
Distorted Octahedral ◽  
Chloride Ligand

The title compound, [IrCl(C12H8NO)2{(CH3)2SO}]·H3CCN or [IrCl(fppy)2(DMSO)]·H3CCN [where fppy is 4-(pyridin-2-yl)benzaldehyde and DMSO is dimethyl sulfoxide], is a mononuclear iridium(III) complex including two fppy ligands, a sulfur-coordinating DMSO ligand, and one terminal chloride ligand that define a distorted octahedral coordination sphere. The complex crystallizes from 1:1 DMSO–acetonitrile as an acetonitrile solvate. In the crystal, weak C—H...O and C—H...N hydrogen-bonding interactions between adjacent complexes and between the acetonitrile solvent and the complex consolidate the packing.

Synthesis and structural characterization of tube-type tetradecavanadates

2018 ◽  
Vol 74 (11) ◽  
pp. 1295-1299 ◽  
Author(s):  
Sho Kuwajima ◽  
Yuta Arai ◽  
Hiromasa Kitajima ◽  
Yuji Kikukawa ◽  
Yoshihito Hayashi
Keyword(s):  
Hydrogen Bonding ◽  
Dimethyl Sulfoxide ◽  
Ammonium Perchlorate ◽  
Structural Characterization ◽  
Equatorial Plane ◽  
Noncovalent Interactions ◽  
Rotation Axes ◽  
Hydrogen Bonding Interactions ◽  
Tube Type

By the reaction of ammonium perchlorate with anion-incorporated bowl-type dodecavanadates, viz. [V12O32(X)]5− [X = N3 − (1), OCN− and NO3 −], tube-type tetradecavanadates, viz. (NH4)7[V14O38(X)] [X = N3 − (2), OCN− (3) and NO3 − (4)] were synthesized. The crystal structures of penta(tetraethylammonium) azidododecavanadate nitromethane monosolvate, (C8H20N)5[V12O32(N3)]·CH3NO2, 1, heptaammonium azidotetradecavanadate dimethyl sulfoxide hexasolvate, (NH4)7[V14O38(N3)]·6C2H6OS, 2, heptaammonium cyanatotetradecavanadate dimethyl sulfoxide hexasolvate, (NH4)7[V14O38(OCN)]·6C2H6OS, 3, and heptaammonium nitratotetradecavanadate dimethyl sulfoxide hexasolvate, (NH4)7[V14O38(NO3)]·6C2H6OS, 4, were determined. The tube consists of two layers of V7 rings with a guest anion at the centre. The distances between the incorporated anions and the nearest V atoms are 3.058 (3), 3.039 (6) and 2.811 (9) Å for 2, 3 and 4, respectively, showing that the incorporated anions are stabilized via noncovalent interactions. Two ammonium cations cap both ends of the tube to stabilize the structures via hydrogen-bonding interactions. Linear OCN− and N3 − anions sit on the twofold rotation axes of the tube frameworks and the triangular plane of the NO3 − anion deviates from the equatorial plane of the tube by ca 30°.

Unique orientations and rotational dynamics of a 1-butyl-3-methyl-imidazolium hexafluorophosphate ionic liquid at the gas–liquid interface: the effects of the hydrogen bond and hydrophobic interactions

2018 ◽  
Vol 20 (17) ◽  
pp. 12043-12052 ◽  
Author(s):  
Deshuai Yang ◽  
Fangjia Fu ◽  
Li Li ◽  
Zhen Yang ◽  
Zheng Wan ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Ionic Liquid ◽  
Hydrogen Bonding ◽  
Hydrophobic Interactions ◽  
Liquid Interface ◽  
Rotational Dynamics ◽  
Two Stage ◽  
Hydrogen Bonding Interactions ◽  
Rotational Motions

Two-stage rotational motions of the interfacial [BMIM]+ cations are essentially determined by both hydrophobic and hydrogen-bonding interactions.

A Quantitative Structure Tribo-Ability Relationship Model for Predicting the Antiwear Properties of Ionic Liquids as Lubricant Additives in Dimethyl Sulfoxide

2020 ◽  
Vol 142 (10) ◽  
Author(s):  
Jiang Zhao ◽  
Xinlei Gao ◽  
Tao Chen ◽  
Tingting Wang ◽  
Yang Li
Keyword(s):  
Ionic Liquid ◽  
Hydrogen Bonding ◽  
Ionic Liquids ◽  
Dimethyl Sulfoxide ◽  
Structural Parameters ◽  
Structural Parameter ◽  
Quantitative Structure ◽  
Prediction Ability ◽  
Relationship Model ◽  
Antiwear Properties

Abstract The structural parameters of 23 ionic liquids were calculated by the Hartree–Fock ab initio method. The relationship between the antiwear properties of ionic liquids dissolved in dimethyl sulfoxide and the structural parameters of the ionic liquids was studied using multiple linear regression analysis. A quantitative structure tribo-ability relationship model with good fitting and prediction ability was established. The results show that entropy is the most important structural parameter affecting the antiwear performance of ionic liquid-dimethyl sulfoxide systems. The entropy of the ionic liquid is related to the hydrogen bonding in the system, and an orderly arrangement of this hydrogen bonding is beneficial in terms of improving antiwear performance.

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