C−H Activation of Ethane by Group 4 Metal Atoms:  Observation and Characterization of the MH−CH2CH3, MH2−(CH2)2, and MH3−CHCH2Complexes

Han-Gook Cho; Lester Andrews

doi:10.1021/jp077704g

C−H Activation of Ethane by Group 4 Metal Atoms: Observation and Characterization of the MH−CH2CH3, MH2−(CH2)2, and MH3−CHCH2Complexes

The Journal of Physical Chemistry A ◽

10.1021/jp077704g ◽

2008 ◽

Vol 112 (7) ◽

pp. 1519-1525 ◽

Cited By ~ 15

Author(s):

Han-Gook Cho ◽

Lester Andrews

Keyword(s):

Group 4 ◽

Metal Atoms ◽

Group 4 Metal

Download Full-text

New Types of Constrained Geometry Group 4 Metal Complexes Derived from the Aminomethyldicarbollyl Ligand System: Synthesis and Structural Characterization of Mono-dicarbollylamino and Bis-dicarbollylamino Group 4 Metal Complexes

Organometallics ◽

10.1021/om0701569 ◽

2007 ◽

Vol 26 (14) ◽

pp. 3374-3384 ◽

Cited By ~ 33

Author(s):

Jong-Dae Lee ◽

Young-Joo Lee ◽

Ki-Chul Son ◽

Minserk Cheong ◽

Jaejung Ko ◽

...

Keyword(s):

Metal Complexes ◽

Structural Characterization ◽

System Synthesis ◽

Ligand System ◽

Group 4 ◽

Constrained Geometry ◽

Group 4 Metal

Download Full-text

Experimental Characterization of the Alkene-Addition/-Insertion Energy Profile at Homogeneous Group 4 Metal Ziegler-Type Catalysts

Journal of the American Chemical Society ◽

10.1021/ja0005338 ◽

2000 ◽

Vol 122 (33) ◽

pp. 7986-7998 ◽

Cited By ~ 34

Author(s):

Marc Dahlmann ◽

Gerhard Erker ◽

Klaus Bergander

Keyword(s):

Homogeneous Group ◽

Energy Profile ◽

Experimental Characterization ◽

Group 4 ◽

Group 4 Metal

Download Full-text

Synthesis and characterization of group 4 metal alkoxide complexes containing imine based bis-bidentate ligands: effective catalysts for the ring opening polymerization of lactides, epoxides and polymerization of ethylene

Dalton Transactions ◽

10.1039/c5dt01092f ◽

2015 ◽

Vol 44 (22) ◽

pp. 10352-10367 ◽

Cited By ~ 22

Author(s):

Sagnik K. Roymuhury ◽

Debashis Chakraborty ◽

Venkatachalam Ramkumar

Keyword(s):

Ring Opening ◽

Ring Opening Polymerization ◽

Synthesis And Characterization ◽

Metal Alkoxide ◽

Bidentate Ligands ◽

Group 4 ◽

Group 4 Metal

A series of group 4 complexes containing imine based bis-bidentate ligands were synthesized and used as catalysts for various polymerizations.

Download Full-text

Synthesis and Structural Characterization of Group 4 Metal Alkoxide Complexes of N,N,N′,N′-Tetrakis(2-hydroxyethyl)ethylenediamine and Their Use As Initiators in the Ring-Opening Polymerization (ROP) of rac-Lactide under Industrially Relevant Conditions

Inorganic Chemistry ◽

10.1021/ic400667z ◽

2013 ◽

Vol 52 (19) ◽

pp. 10804-10811 ◽

Cited By ~ 27

Author(s):

Christopher J. Chuck ◽

Matthew G. Davidson ◽

Gerrit Gobius du Sart ◽

Petya K. Ivanova-Mitseva ◽

Gabriele I. Kociok-Köhn ◽

...

Keyword(s):

Structural Characterization ◽

Ring Opening ◽

Ring Opening Polymerization ◽

Metal Alkoxide ◽

Group 4 ◽

Group 4 Metal

Download Full-text

ChemInform Abstract: Oxygen-Atom Transfer from Nitrous Oxide. Identification of Intermediates in the Oxidation of Diphenylacetylene at Group 4 Metal Centers and the Structural Characterization of (η-C5Me5)2Ti(N(O)NCPh=CPh)·1/2 C7H8.

ChemInform ◽

10.1002/chin.198941254 ◽

1989 ◽

Vol 20 (41) ◽

Author(s):

G. A. VAUGHAN ◽

C. D. SOFIELD ◽

G. L. HILLHOUSE ◽

A. L. RHEINGOLD

Keyword(s):

Nitrous Oxide ◽

Oxygen Atom ◽

Structural Characterization ◽

Atom Transfer ◽

Oxygen Atom Transfer ◽

Metal Centers ◽

Group 4 ◽

Group 4 Metal

Download Full-text

The synthesis and characterization of Group 4 metal—chromium complexes bridged by an OCH2C5H4 group the molecular structure of Cp2TiCl[(OCH2C5H4)Cr(CO)2(NO)]

Journal of Organometallic Chemistry ◽

10.1016/s0022-328x(97)00059-4 ◽

1997 ◽

Vol 539 (1-2) ◽

pp. 155-161 ◽

Cited By ~ 1

Author(s):

Ming-Ke Jiang ◽

Chu-Chieh Lin ◽

Han-Mou Gau

Keyword(s):

Molecular Structure ◽

Synthesis And Characterization ◽

Chromium Complexes ◽

Group 4 ◽

Group 4 Metal

Download Full-text

Synthesis and Structural Characterization of Group 4 Metal Carboxylates for Nanowire Production

Inorganic Chemistry ◽

10.1021/ic501904m ◽

2014 ◽

Vol 53 (23) ◽

pp. 12449-12458 ◽

Cited By ~ 6

Author(s):

Timothy J. Boyle ◽

Daniel T. Yonemoto ◽

Thu Q. Doan ◽

Todd M. Alam

Keyword(s):

Structural Characterization ◽

Metal Carboxylates ◽

Group 4 ◽

Group 4 Metal

Download Full-text

Oxygen-atom transfer from nitrous oxide. Identification of intermediates in the oxidation of diphenylacetylene at Group 4 metal centers and the structural characterization of (.eta.-C5Me5)2Ti{N(O)NCPh:CPh}.cntdot.1/2C7H8

Journal of the American Chemical Society ◽

10.1021/ja00196a080 ◽

1989 ◽

Vol 111 (14) ◽

pp. 5491-5493 ◽

Cited By ~ 41

Author(s):

G. Alan Vaughan ◽

Chadwick D. Sofield ◽

Gregory L. Hillhouse ◽

Arnold L. Rheingold

Keyword(s):

Nitrous Oxide ◽

Oxygen Atom ◽

Structural Characterization ◽

Atom Transfer ◽

Oxygen Atom Transfer ◽

Metal Centers ◽

Group 4 ◽

Group 4 Metal

Download Full-text

Synthesis and spectroscopic characterization of α-keto ylide-containing Group 4 metal complexes. The X-ray molecular structure of [CpZrCl3(2-TCMP)], Cp=η5-C5Me5, 2-TCMP=[{2-thiazolylcarbonyl}methylene]triphenylphosphorane

Journal of Organometallic Chemistry ◽

10.1016/s0022-328x(01)00815-4 ◽

2001 ◽

Vol 629 (1-2) ◽

pp. 68-76 ◽

Cited By ~ 1

Author(s):

A. Otero ◽

J. Fernández-Baeza ◽

A. Antiñolo ◽

F. Carrillo-Hermosilla ◽

J. Tejeda ◽

...

Keyword(s):

Molecular Structure ◽

Metal Complexes ◽

Spectroscopic Characterization ◽

X Ray ◽

Group 4 ◽

Group 4 Metal

Download Full-text

Synthesis and Structural Characterization of Group 4 Metal Complexes Bearing Pentavalent Phosphorus-Bridged Ligands [(C13H8)(iPr2N)P(−O)(C2B10H10)]2−and [(C13H9)(iPr2N)P(O)(C2B9H10)]2−

Organometallics ◽

10.1021/om800319w ◽

2008 ◽

Vol 27 (15) ◽

pp. 3964-3970 ◽

Cited By ~ 20

Author(s):

Hong Wang ◽

Hao Shen ◽

Hoi-Shan Chan ◽

Zuowei Xie

Keyword(s):

Metal Complexes ◽

Structural Characterization ◽

Pentavalent Phosphorus ◽

Group 4 ◽

Group 4 Metal

Download Full-text

C−H Activation of Ethane by Group 4 Metal Atoms: Observation and Characterization of the MH−CH2CH3, MH2−(CH2)2, and MH3−CHCH2Complexes

New Types of Constrained Geometry Group 4 Metal Complexes Derived from the Aminomethyldicarbollyl Ligand System: Synthesis and Structural Characterization of Mono-dicarbollylamino and Bis-dicarbollylamino Group 4 Metal Complexes

Experimental Characterization of the Alkene-Addition/-Insertion Energy Profile at Homogeneous Group 4 Metal Ziegler-Type Catalysts

Synthesis and characterization of group 4 metal alkoxide complexes containing imine based bis-bidentate ligands: effective catalysts for the ring opening polymerization of lactides, epoxides and polymerization of ethylene

Synthesis and Structural Characterization of Group 4 Metal Alkoxide Complexes of N,N,N′,N′-Tetrakis(2-hydroxyethyl)ethylenediamine and Their Use As Initiators in the Ring-Opening Polymerization (ROP) of rac-Lactide under Industrially Relevant Conditions

ChemInform Abstract: Oxygen-Atom Transfer from Nitrous Oxide. Identification of Intermediates in the Oxidation of Diphenylacetylene at Group 4 Metal Centers and the Structural Characterization of (η-C5Me5)2Ti(N(O)NCPh=CPh)·1/2 C7H8.

The synthesis and characterization of Group 4 metal—chromium complexes bridged by an OCH2C5H4 group the molecular structure of Cp2TiCl[(OCH2C5H4)Cr(CO)2(NO)]

Synthesis and Structural Characterization of Group 4 Metal Carboxylates for Nanowire Production

Oxygen-atom transfer from nitrous oxide. Identification of intermediates in the oxidation of diphenylacetylene at Group 4 metal centers and the structural characterization of (.eta.-C5Me5)2Ti{N(O)NCPh:CPh}.cntdot.1/2C7H8

Synthesis and spectroscopic characterization of α-keto ylide-containing Group 4 metal complexes. The X-ray molecular structure of [Cp*ZrCl3(2-TCMP)], Cp*=η5-C5Me5, 2-TCMP=[{2-thiazolylcarbonyl}methylene]triphenylphosphorane

Synthesis and Structural Characterization of Group 4 Metal Complexes Bearing Pentavalent Phosphorus-Bridged Ligands [(C13H8)(iPr2N)P(−O)(C2B10H10)]2−and [(C13H9)(iPr2N)P(O)(C2B9H10)]2−

Synthesis and spectroscopic characterization of α-keto ylide-containing Group 4 metal complexes. The X-ray molecular structure of [CpZrCl3(2-TCMP)], Cp=η5-C5Me5, 2-TCMP=[{2-thiazolylcarbonyl}methylene]triphenylphosphorane