scholarly journals Infrared Spectroscopy of Discrete Uranyl Anion Complexes

2008 ◽  
Vol 112 (3) ◽  
pp. 508-521 ◽  
Author(s):  
Gary S. Groenewold ◽  
Anita K. Gianotto ◽  
Michael E. McIlwain ◽  
Michael J. Van Stipdonk ◽  
Michael Kullman ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Anion Complexes

Anion–molecule complexes in solution. III. Nuclear magnetic resonance studies of halide ion–alcohol association

1969 ◽  
Vol 47 (10) ◽  
pp. 1639-1648 ◽  
Author(s):  
R. D. Green ◽  
John S. Martin ◽  
W. B. McG. Cassie ◽  
J. B. Hyne
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Infrared Spectroscopy ◽  
Magnetic Resonance ◽  
Electrostatic Interaction ◽  
Halide Ions ◽  
Alkyl Aryl ◽  
Hydroxyl Proton ◽  
Magnetic Resonance Studies ◽  
Anion Complexes ◽  
Electron Withdrawal

Certain alkyl-, aryl-, and arene-substituted alcohols form linear, hydrogen bonded complexes with bromide and other halide ions in tetrachloromethane. The hydroxyl proton shifts ca. 4 p.p.m. downfield in the complex, regardless of the degree or type of substitution. The interaction is enhanced by inductive electron withdrawal by substituents on the C—O—H moiety. A comparison of the present results with infrared spectroscopy shows that the absorption at ca. 3300 cm−1 is entirely due to 1:1 alcohol–anion complexes. The a coefficient in Buckingham's equation for electrostatic interaction of a molecule with an ion, δσE = aEz−bE2, is found to be 5.5 for alcohol O—H bonds.

Millimetre-wave and infrared spectroscopy of Br13 CN: anharmonic force field of cyanogen bromide from spectroscopic data and ab initio calculations

1997 ◽  
Vol 90 (3) ◽  
pp. 495-497
Author(s):  
CLAUDIO ESPOSTI ◽  
FILIPPO TAMASSIA ◽  
CRISTINA PUZZARINI ◽  
RICCARDO TARRONI ◽  
ZDENEK ZELINGER
Keyword(s):  
Infrared Spectroscopy ◽  
Force Field ◽  
Ab Initio Calculations ◽  
Ab Initio ◽  
Spectroscopic Data ◽  
Cyanogen Bromide ◽  
Millimetre Wave ◽  
Anharmonic Force

A long-term chemical and infrared spectroscopy study on a soil amended with municipal sewage sludge

Agronomie ◽  
2001 ◽  
Vol 21 (2) ◽  
pp. 169-178 ◽  
Author(s):  
Giovanni Gigliotti ◽  
Pier Lodovico Giusquiani ◽  
Daniela Businelli
Keyword(s):  
Infrared Spectroscopy ◽  
Sewage Sludge ◽  
Municipal Sewage ◽  
Municipal Sewage Sludge ◽  
Spectroscopy Study
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