Viscosity Dependence of the Kinetic Parameters of the Radical Ion Pair in Homogeneous Solution Determined by Optically Detected X- and Ku-Band Electron Spin Resonance

2008 ◽  
Vol 112 (3) ◽  
pp. 347-352 ◽  
Author(s):  
Yasutaka Kitahama ◽  
Yoshio Sakaguchi
Keyword(s):  
Electron Spin Resonance ◽  
Kinetic Parameters ◽  
Electron Spin ◽  
Homogeneous Solution ◽  
Ion Pair ◽  
Band Electron ◽  
Spin Resonance ◽  
Optically Detected ◽  
Viscosity Dependence ◽  
Ku Band

Identification of the neutralV4+impurity in cubic 3C-SiC by electron-spin resonance and optically detected magnetic resonance

1994 ◽  
Vol 50 (24) ◽  
pp. 18034-18039 ◽  
Author(s):  
K. F. Dombrowski ◽  
U. Kaufmann ◽  
M. Kunzer ◽  
K. Maier ◽  
J. Schneider ◽  
...  
Keyword(s):  
Electron Spin Resonance ◽  
Magnetic Resonance ◽  
Electron Spin ◽  
Spin Resonance ◽  
Optically Detected Magnetic Resonance ◽  
Optically Detected

A PARAMAGNETIC RESONANCE STUDY OF HINDERED DIARYLMETHYL RADICALS AND RELATED COMPOUNDS: I. ANALYSIS OF THE SPECTRA

1966 ◽  
Vol 44 (12) ◽  
pp. 1387-1395 ◽  
Author(s):  
H. R. Falle ◽  
F. C. Adam
Keyword(s):  
Electron Spin Resonance ◽  
Electron Spin ◽  
Ion Pair ◽  
Coupling Constants ◽  
Methyl Groups ◽  
Steric Repulsion ◽  
Paramagnetic Resonance ◽  
Spin Resonance ◽  
Phenyl Rings ◽  
Related Compounds

Several ortho-substituted radicals of the benzhydryl type and a variety of diaryl ketyls have been studied through the nuclear hyperfine structure of their electron spin resonance spectra. A strong similarity is found between the spectra of a given ketyl and its hydrocarbon analogue. This suggests that when ketones are reduced, a very tight ion pair is formed between the ketyl anion and its cation. Although the coupling constants of the protons vary with different reducing agents, larger variations are observed when bulky groups are substituted into ortho positions. These larger changes are attributed to a forced internal rotation of the phenyl rings. The distortion results from the steric repulsion between the ortho groups. The effect of 'buttressing' of ortho methyl groups is also studied. Deuterium and 13C substitutions have been effected in some of the compounds.

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