Intramolecular Electron Transfer within a Covalent, Fixed-Distance Donor−Acceptor Molecule in an Ionic Liquid

2007 ◽  
Vol 111 (40) ◽  
pp. 11638-11641 ◽  
Author(s):  
Jenny V. Lockard ◽  
Michael R. Wasielewski
Keyword(s):  
Electron Transfer ◽  
Ionic Liquid ◽  
Intramolecular Electron Transfer ◽  
Acceptor Molecule ◽  
Fixed Distance ◽  
Donor Acceptor

scholarly journals Electrostatically driven folding following light-induced intramolecular electron transfer in a trichromophoric electron donor—acceptor molecule

1991 ◽  
Vol 186 (6) ◽  
pp. 481-489 ◽  
Author(s):  
A.M. Brouwer ◽  
R.D. Mout ◽  
P.H.Maassen van den Brink ◽  
H.J. van Ramesdonk ◽  
J.W. Verhoeven ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Electron Donor ◽  
Intramolecular Electron Transfer ◽  
Acceptor Molecule ◽  
Donor Acceptor

Through-bond modulation of intramolecular electron transfer in rigidly linked donor-acceptor systems

1989 ◽  
Vol 164 (2-3) ◽  
pp. 120-125 ◽  
Author(s):  
James M. Lawson ◽  
Donald C. Craig ◽  
Michael N. Paddon-Row ◽  
Jan Kroon ◽  
Jan W. Verhoeven
Keyword(s):  
Electron Transfer ◽  
Intramolecular Electron Transfer ◽  
Donor Acceptor

Performance enhancement of a dye-sensitized solar cell by peripheral aromatic and heteroaromatic functionalization in di-branched organic sensitizers

2018 ◽  
Vol 42 (11) ◽  
pp. 9281-9290 ◽  
Author(s):  
N. Manfredi ◽  
V. Trifiletti ◽  
F. Melchiorre ◽  
G. Giannotta ◽  
P. Biagini ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Solar Cell ◽  
Performance Enhancement ◽  
Dye Sensitized Solar Cell ◽  
Back Reaction ◽  
Intramolecular Electron Transfer ◽  
Dye Sensitized ◽  
Donor Acceptor ◽  
Organic Sensitizers

Suppression of back reaction and enhanced photoinduced intramolecular electron transfer through peripheral functionalization of triphenylamino based dibranched donor–acceptor dyes.

scholarly journals Electronics Communication and Photoinduced Intramolecular Electron Transfer in Hybrid Ru(II)-Re(I) Complexes Using Eigenstate-Based and Diabatic-State-Based Models

2021 ◽  
Author(s):  
Rangsiman Ketkaew
Keyword(s):  
Electron Transfer ◽  
Density Functional ◽  
Reduction Reaction ◽  
Vital Role ◽  
Energy Curve ◽  
Intramolecular Electron Transfer ◽  
Oxidation Reduction ◽  
Donor And Acceptor ◽  
Donor Acceptor ◽  
Adiabatic State

Photoinduced intramolecular electron transfer (PIET) plays a vital role in the efficiency of electronics communication in transition metal complexes catalysing oxidation-reduction reaction. In this work, we theoretically calculate the rate of electron transfer(ET) in Ru(II)-BL-Ru(I) hybrid complexes; where BL is bridging ligand. A brief concept of ET in the basis of Marcus theory, which is extended to address a variety of different type of ET, is provided. We show that, in the case of Ru(II)-BL-Ru(I) complex, ET involves a non-adiabatic state which thanks to a fast electronics communication between donor and acceptor connected by BL and becomes rigid complex. Single electron transferring in Ru(II)-BL-Ru(I) complex governed by PIET constructed by potential energy curve as change of structural transformation over time-evolution. We also investigate the mechanism of PIET involving a redox reaction in excited state, wherein the oxidation state of Ru(II) (donor) and Ru(I) (acceptor) changes. To access non-adiabatic state of Ru(II)-BL-Ru(I), we use constrained density functional theory to allow ground state calculation to be performed along with geometry constraints. We also systematically study the role of distance of donor-acceptor separation on kinetics of PIET

Sign in / Sign up

Export Citation Format

Share Document