The Influence of Solvent Polarity and Metalation on Energy and Electron Transfer in Porphyrin−Phthalocyanine Heterotrimers

2007 ◽  
Vol 111 (28) ◽  
pp. 8053-8062 ◽  
Author(s):  
Sebastian Tannert ◽  
Eugeny A. Ermilov ◽  
Jörn Oliver Vogel ◽  
Michael T. M. Choi ◽  
Dennis K. P. Ng ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Solvent Polarity ◽  
Energy And Electron Transfer ◽  
Influence Of Solvent ◽  
Porphyrin Phthalocyanine

A zinc phthalocyanine–benzoperylenetriimide conjugate for solvent dependent ultrafast energy vs. electron transfer

2019 ◽  
Vol 55 (99) ◽  
pp. 14946-14949 ◽  
Author(s):  
Valeria Navarro-Pérez ◽  
Ana M. Gutiérrez-Vílchez ◽  
Javier Ortiz ◽  
Ángela Sastre-Santos ◽  
Fernando Fernández-Lázaro ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Transient Absorption ◽  
Solvent Polarity ◽  
Zinc Phthalocyanine ◽  
Femtosecond Transient Absorption ◽  
Energy And Electron Transfer ◽  
Absorption Technique

Ultrafast energy and electron transfer as a function of solvent polarity has been demonstrated using a femtosecond transient absorption technique in a zinc phthalocyanine–benzoperylenetriimide conjugate.

Control of Photoinduced Energy- and Electron-Transfer Steps in Zinc Porphyrin−Oligothiophene−Fullerene Linked Triads with Solvent Polarity

2005 ◽  
Vol 109 (30) ◽  
pp. 14365-14374 ◽  
Author(s):  
Takumi Nakamura ◽  
Jun-ya Ikemoto ◽  
Mamoru Fujitsuka ◽  
Yasuyuki Araki ◽  
Osamu Ito ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Solvent Polarity ◽  
Zinc Porphyrin ◽  
Energy And Electron Transfer

Influence of solvent polarity on the dual fluorescence of p-N,N-dimethylaminobenzonitrile: An AM1 theoretical study

1990 ◽  
Vol 55 (8) ◽  
pp. 1891-1895 ◽  
Author(s):  
Peter Ertl
Keyword(s):  
Excited State ◽  
Theoretical Study ◽  
Solvent Polarity ◽  
Semiempirical Method ◽  
Dual Fluorescence ◽  
Long Wavelength ◽  
Polar Media ◽  
Wavelength Emission ◽  
Ground State Geometry ◽  
Influence Of Solvent

Twisting of the NMe2 group in p-N,N-dimethylaminobenzonitrile (DMABN) was investigated using AM1 semiempirical method with configuration interaction. Effect of polar media was considered by placing + and - charge centers ("sparkles") at appropriate places opposite the molecule. Optimized ground state geometry of DMABN is slightly twisted with the lowest vertical excited state of 1B character. As the polarity of media increases and/or the - NMe2 group twists, the symmetric 1A excited state having considerable charge separation becomes energetically favorable. Anomalous long-wavelength emission of DMABN comes from this state.

scholarly journals Photophysical Properties of Protoporphyrin IX, Pyropheophorbide-a, and Photofrin® in Different Conditions

2021 ◽  
Vol 14 (2) ◽  
pp. 138
Author(s):  
Bauyrzhan Myrzakhmetov ◽  
Philippe Arnoux ◽  
Serge Mordon ◽  
Samir Acherar ◽  
Irina Tsoy ◽  
...  
Keyword(s):  
Singlet Oxygen ◽  
Photophysical Properties ◽  
Protoporphyrin Ix ◽  
Fluorescence Emission ◽  
Solvent Polarity ◽  
Visible Absorption ◽  
Light Dosimetry ◽  
Time Resolved ◽  
Pyropheophorbide A ◽  
Influence Of Solvent

Photodynamic therapy (PDT) is an innovative treatment of malignant or diseased tissues. The effectiveness of PDT depends on light dosimetry, oxygen availability, and properties of the photosensitizer (PS). Depending on the medium, photophysical properties of the PS can change leading to increase or decrease in fluorescence emission and formation of reactive oxygen species (ROS) especially singlet oxygen (1O2). In this study, the influence of solvent polarity, viscosity, concentration, temperature, and pH medium on the photophysical properties of protoporphyrin IX, pyropheophorbide-a, and Photofrin® were investigated by UV-visible absorption, fluorescence emission, singlet oxygen emission, and time-resolved fluorescence spectroscopies.

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