A CASPT2//CASSCF Study of Vertical and Adiabatic Electron Transitions of Acrolein in Water Solution

2007 ◽  
Vol 111 (33) ◽  
pp. 9864-9870 ◽  
Author(s):  
Aurora Muñoz Losa ◽  
Ignacio Fdez. Galván ◽  
Manuel A. Aguilar ◽  
M. Elena Martín
Keyword(s):  
Water Solution ◽  
Electron Transitions

Chemical Species Identification in an SEM by Changes in Emitted X-Ray Energies

1974 ◽  
Vol 32 ◽  
pp. 570-571
Author(s):  
R. H. Duff
Keyword(s):  
Species Identification ◽  
Valence Electron ◽  
Chemical Species ◽  
X Rays ◽  
Chemical Bonds ◽  
Small Shift ◽  
X Ray ◽  
Electron Transitions ◽  
Peak Energy ◽  
Chemical Combination

A material irradiated with electrons emits x-rays having energies characteristic of the elements present. Chemical combination between elements results in a small shift of the peak energies of these characteristic x-rays because chemical bonds between different elements have different energies. The energy differences of the characteristic x-rays resulting from valence electron transitions can be used to identify the chemical species present and to obtain information about the chemical bond itself. Although these peak-energy shifts have been well known for a number of years, their use for chemical-species identification in small volumes of material was not realized until the development of the electron microprobe.

Linear and Nonlinear Optical Properties of Natural Dyes Freestanding Films and Application in Optical Limiting

2020 ◽  
pp. 139-143
Keyword(s):  
Absorption Coefficient ◽  
Water Solution ◽  
Optical Limiting ◽  
Refraction Index ◽  
Laser Wavelength ◽  
Solid State Laser ◽  
Natural Dyes ◽  
Linear And Nonlinear ◽  
532 Nm ◽  
Absorbance Spectra

Natural dyes were followed and prepared from a pomegranate, purple carrot, and eggplant peel. The absorbance spectra was measured in the wavelength range 300-800 nm. The linear properties measurements of the prepared natural dye freestanding films were determined include absorption coefficient (α0), extinction coefficient (κ), and linear refraction index (n). The nonlinear refractive index n2 and nonlinear absorption coefficient β2 of the natural dyes in the water solution were measured by the optical z-scan technique under a pumped solid state laser at a laser wavelength of 532 nm. The results indicated that the pomegranate dye can be promising candidates for optical limiting applications with significantly low optical limiting of 3.5 mW.

Shake-up processes accompanying electron transitions in atoms

1982 ◽  
Vol 138 (12) ◽  
pp. 573 ◽  
Author(s):  
V.I. Matveev ◽  
E.S. Parilis
Keyword(s):  
Electron Transitions

Synthesis and phase morphology investigation of simultaneous organic-inorganic IPNs based on diisocyanate, dimethacrylate, and water solution of sodium silicate

2015 ◽  
Vol 37 (2) ◽  
pp. 179-185 ◽  
Author(s):  
О.O. Brovko ◽  
◽  
L.A. Gorbach ◽  
О.D. Lutsyk ◽  
L.M. Sergeeva ◽  
...  
Keyword(s):  
Sodium Silicate ◽  
Water Solution ◽  
Phase Morphology

Investigation of characteristics of pulse discharge about surface water solution of zinc chloride

2016 ◽  
Vol 39 (0) ◽  
pp. 100-105
Author(s):  
В. В. Данило ◽  
І. В. Шевера ◽  
Й. О. Миня ◽  
З. Т. Гомокі ◽  
Д. А. Калімуліна ◽  
...  
Keyword(s):  
Surface Water ◽  
Zinc Chloride ◽  
Water Solution ◽  
Pulse Discharge

Development of corrosion flaws for the production of realistic test specimens

2020 ◽  
Vol 64 (1) ◽  
pp. 23-28
Author(s):  
J. Hodač ◽  
Z. Fulín ◽  
P. Mareš ◽  
J. Veselá ◽  
O. Chocholatý
Keyword(s):  
Power Plants ◽  
Galvanic Corrosion ◽  
Water Solution ◽  
Erosive Wear ◽  
Corrosion Damage ◽  
Water Mist ◽  
Carbon Steels ◽  
Bending Stress ◽  
Solution Flow ◽  
Mechanical Bending

AbstractTo produce realistic test specimens with realistic flaws, it is necessary to develop appropriate procedure for corrosion flaw production. Tested specimens are made from steels commonly used in power plants, such as carbon steels, stainless steels and their dissimilar weldments. In this study, corrosion damage from NaCl water solution and NaCl water mist are compared. Specimens were tested with and without mechanical bending stress. The corrosion processes produced plane, pitting and galvanic corrosion. On dissimilar weldments galvanic corrosion was observed and resulted to the deepest corrosion damage. Deepest corrosion flaws were formed on welded samples. The corrosion rate was also affected by the solution flow in a contact with the specimens, which results in a corrosion-erosive wear. Produced flaws are suitable as natural crack initiators or as realistic corrosion flaws in test specimens.

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