In Situ Direct Sampling Mass Spectrometric Study on Formation of Polycyclic Aromatic Hydrocarbons in Toluene Pyrolysis

2007 ◽  
Vol 111 (34) ◽  
pp. 8308-8324 ◽  
Author(s):  
Bikau Shukla ◽  
Akio Susa ◽  
Akira Miyoshi ◽  
Mitsuo Koshi
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Mass Spectrometric Study ◽  
Mass Spectrometric ◽  
Spectrometric Study ◽  
Direct Sampling ◽  
Polycyclic Aromatic

scholarly journals Multi-Stage Redox Systems Based on Dicationic P-Containing Polycyclic Aromatic Hydrocarbons

2019 ◽  
Author(s):  
Thomas Delouche ◽  
Antoine Vacher ◽  
Elsa Caytan ◽  
Thierry Roisnel ◽  
Boris Le Guennic ◽  
...  
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Organic Radical ◽  
Electrochemical Studies ◽  
Redox Systems ◽  
Redox States ◽  
Multi Stage ◽  
Polycyclic Aromatic ◽  
The Impact

In this communication, we report the straightforward<br>synthesis of unprecedented electron-acceptors based on dicationic P-containing PAHs (Polycyclic Aromatic Hydrocarbons) where two phosphoniums are connected through various PAHs backbones. The impact of pi-extension on both the optical and redox properties is investigated using a joint experimental/theoretical approach.<br>Finally, (spectro)-electrochemical studies prove that these<br>compounds possess three redox states and EPR studies confirms the in situ formation of an organic radical.

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