Oxygen Uptake upon Photolysis of 1,4-Benzoquinones and 1,4-Naphthoquinones in Air-Saturated Aqueous Solution in the Presence of Formate, Amines, Ascorbic Acid, and Alcohols

2007 ◽  
Vol 111 (15) ◽  
pp. 2814-2819 ◽  
Author(s):  
Helmut Görner
Keyword(s):  
Aqueous Solution ◽  
Ascorbic Acid ◽  
Oxygen Uptake ◽  
Saturated Aqueous Solution

Darstellung und röntgenographische Untersuchung von drei Strontiumazidhydraten

1973 ◽  
Vol 137 (4) ◽  
Author(s):  
H. Krischner ◽  
H. E. Roth
Keyword(s):  
Aqueous Solution ◽  
Saturated Aqueous Solution

AbstractThree different hydrates of strontiumazide have been prepared by crystallization from saturated aqueous solution. Sr(N

scholarly journals Spectrophotometric determination of phosphorus in coal and coal ash using bismuth-phosphomobybdate complex

2003 ◽  
Vol 68 (1) ◽  
pp. 65-73 ◽  
Author(s):  
Randjel Mihajlovic ◽  
Natasa Ignjatovic ◽  
Marija Todorovic ◽  
Ivanka Holclajtner-Antunovic ◽  
Vesna Kaljevic
Keyword(s):  
Aqueous Solution ◽  
Ascorbic Acid ◽  
Acid Medium ◽  
Spectrophotometric Method ◽  
Methyl Ketone ◽  
Coal Ash ◽  
Molar Absorptivity ◽  
Stable Complex ◽  
Tolerance Limits

A modified spectrophotometric method using the bismuth phosphomolybdate complex for the determination of phosphorus in coal and coal ash is suggested. Bismuth together with phosphate and molybdate forms a very stable complex in acid medium which turns blue ("molibdenum blue") by reduction with ascorbic acid. The apparent molar absorptivity of PBiMo is 1.66x104 dm3 mol-1cm-1 at 720 nm and 2.10x104 dm3 mol-1cm-1 at 670 nm isobutyl methyl ketone (MIBK). Interference caused by the ions present are within the tolerance limits (?2 %). Beer?s law is obeyed in the for concentration range to 0.6 ?g/mL (aqueous solution) and to 1.2 ?g/mL P (MIBK). The sensitivity of the proposed method is 0.0078 ?g/mL (aqueous solution) and 0.0066 ?g/mL (MIBK).

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