Correlation between Photovoltaic Performance and Impedance Spectroscopy of Dye-Sensitized Solar Cells Based on Ionic Liquids

2007 ◽  
Vol 111 (17) ◽  
pp. 6550-6560 ◽  
Author(s):  
Francisco Fabregat-Santiago ◽  
Juan Bisquert ◽  
Emilio Palomares ◽  
Luis Otero ◽  
Daibin Kuang ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Solar Cells ◽  
Impedance Spectroscopy ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Analysis of Charge Transport and Recombination Studied by Electrochemical Impedance Spectroscopy for Dye-sensitized Solar Cells With Atomic Layer Deposited Metal Oxide Treatment on TiO2 Surface

2010 ◽  
Vol 1270 ◽  
Author(s):  
Braden Bills ◽  
Mariyappan Shanmugam ◽  
Mahdi Farrokh Baroughi ◽  
David Galipeau
Keyword(s):  
Solar Cells ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Atomic Layer ◽  
Back Reaction ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

AbstractThe performance of dye-sensitized solar cells (DSSCs) is limited by the back-reaction of photogenerated electrons from the porous titanium oxide (TiO2) nanoparticles back into the electrolyte solution, which occurs almost exclusively through the interface. This and the fact that DSSCs have a very large interfacial area makes their performance greatly dependant on the density and activity of TiO2 surface states. Thus, effectively engineering the TiO2/dye/electrolyte interface to reduce carrier losses is critically important for improving the photovoltaic performance of the solar cell. Atomic layer deposition (ALD), which uses high purity gas precursors that can rapidly diffuse through the porous network, was used to grow a conformal and controllable aluminum oxide (Al2O3) and hafnium oxide (HfO2) ultra thin layer on the TiO2 surface. The effects of this interfacial treatment on the DSSC performance was studied with dark and illuminated current-voltage and electrochemical impedance spectroscopy (EIS) measurements.

Ionic Liquid Based Gel Electrolyte Compositions for Dye Sensitized Solar Cells

2002 ◽  
Vol 736 ◽  
Author(s):  
K. G. Chittibabu ◽  
S. Hadjikyriacou ◽  
L. Li
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Solar Cells ◽  
Metal Ion ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Extended Period ◽  
Gel Electrolyte ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

ABSTRACTKonarka Technologies has developed efficient electrolyte compositions based on nonvolatile ionic liquids. The electrolyte compositions were subsequently gelled using a metal ion complexation technique, without compromising the photovoltaic performance of the dye sensitized solar cells (DSSCs). The photovoltaic performance of the gel electrolyte incorporated DSSCs is quite stable for extended period of time even in the absence of sealing. Detailed results on performance and stability of the gel electrolyte incorporated DSSCs are presented.

Tetraphenylethylene-bridged double-branched sensitizers featuring hetero-donors for dye-sensitized solar cells

2020 ◽  
Vol 44 (30) ◽  
pp. 12909-12915
Author(s):  
Yi-Qiao Yan ◽  
Yi-Zhou Zhu ◽  
Pan-Pan Dai ◽  
Jun Han ◽  
Mao Yan ◽  
...  
Keyword(s):  
Solar Cells ◽  
Organic Dyes ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Effects of hetero-donors on the photovoltaic performance of tetraphenylethylene-based organic dyes were systematically investigated.

scholarly journals Eco-Friendly Dye-Sensitized Solar Cells Based on Water-Electrolytes and Chlorophyll

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2150
Author(s):  
Ji-Hye Kim ◽  
Sung-Yoon Park ◽  
Dong-Hyuk Lim ◽  
So-Young Lim ◽  
Jonghoon Choi ◽  
...  
Keyword(s):  
Solar Cells ◽  
Plasma Treatment ◽  
Ruthenium Complex ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Dye Adsorption ◽  
Synthesis Process ◽  
Dye Sensitized ◽  
Water Based ◽  
Sensitized Solar Cells

Organic solvents used for electrolytes of dye-sensitized solar cells (DSSCs) are generally not only toxic and explosive but also prone to leakage due to volatility and low surface tension. The representative dyes of DSSCs are ruthenium-complex molecules, which are expensive and require a complicated synthesis process. In this paper, the eco-friendly DSSCs were presented based on water-based electrolytes and a commercially available organic dye. The effect of aging time after the device fabrication and the electrolyte composition on the photovoltaic performance of the eco-friendly DSSCs were investigated. Plasma treatment of TiO2 was adopted to improve the dye adsorption as well as the wettability of the water-based electrolytes on TiO2. It turned out that the plasma treatment was an effective way of improving the photovoltaic performance of the eco-friendly DSSCs by increasing the efficiency by 3.4 times. For more eco-friendly DSSCs, the organic-synthetic dye was replaced by chlorophyll extracted from spinach. With the plasma treatment, the efficiency of the eco-friendly DSSCs based on water-electrolytes and chlorophyll was comparable to those of the previously reported chlorophyll-based DSSCs with non-aqueous electrolytes.

scholarly journals In Depth Analysis of Photovoltaic Performance of Chlorophyll Derivative-Based “All Solid-State” Dye-Sensitized Solar Cells

Molecules ◽  
2020 ◽  
Vol 25 (1) ◽  
pp. 198 ◽  
Author(s):  
Michèle Chevrier ◽  
Alberto Fattori ◽  
Laurent Lasser ◽  
Clément Kotras ◽  
Clémence Rose ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solid State ◽  
Density Functional ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Hole Transport ◽  
Tio2 Electrode ◽  
Dye Sensitized ◽  
Depth Analysis ◽  
Sensitized Solar Cells

Chlorophyll a derivatives were integrated in “all solid-state” dye sensitized solar cells (DSSCs) with a mesoporous TiO2 electrode and 2′,2′,7,7′-tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9′-spirobifluorene as the hole-transport material. Despite modest power conversion efficiencies (PCEs) between 0.26% and 0.55% achieved for these chlorin dyes, a systematic investigation was carried out in order to elucidate their main limitations. To provide a comprehensive understanding of the parameters (structure, nature of the anchoring group, adsorption …) and their relationship with the PCEs, density functional theory (DFT) calculations, optical and photovoltaic studies and electron paramagnetic resonance analysis exploiting the 4-carboxy-TEMPO spin probe were combined. The recombination kinetics, the frontier molecular orbitals of these DSSCs and the adsorption efficiency onto the TiO2 surface were found to be the key parameters that govern their photovoltaic response.

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