Vibrational Structures of Dimethyl Sulfide and Ethylene Sulfide Cations Studied by Vacuum-Ultraviolet Mass-Analyzed Threshold Ionization (MATI) Spectroscopy

2006 ◽  
Vol 110 (49) ◽  
pp. 13183-13187 ◽  
Author(s):  
Sunyoung Choi ◽  
Kyo-Won Choi ◽  
Sang Kyu Kim ◽  
Sangyoon Chung ◽  
Sungyul Lee
2017 ◽  
Vol 19 (45) ◽  
pp. 30362-30369 ◽  
Author(s):  
Sung Man Park ◽  
Yu Ran Lee ◽  
Do Won Kang ◽  
Hong Lae Kim ◽  
Chan Ho Kwon

One-photon vacuum ultraviolet mass-analyzed threshold ionization (VUV-MATI) spectroscopy was used to characterize the essential conformations of tetrahydrofuran (THF) and thus determine the stereochemistry of the furanose ring constituting the backbones of DNA and RNA.


RSC Advances ◽  
2021 ◽  
Vol 11 (60) ◽  
pp. 38240-38246
Author(s):  
Sung Man Park ◽  
Chan Ho Kwon

We measured the conformer-specific vibrational spectra of C4H6O isomers in neutral and cationic states using IR resonant vacuum ultraviolet mass-analyzed threshold ionization (VUV-MATI) spectroscopy for the first time.


2005 ◽  
Vol 30 (1-2) ◽  
pp. 115-125 ◽  
Author(s):  
Mahendra P. Deeyamulla ◽  
David Husain

Reaction rates of atomic carbon in its electronic ground state, C[2p2 (3PJ)], with a range of large sulfur-containing molecules have been investigated using time-resolved atomic spectroscopy in the vacuum ultraviolet following pulsed irradiation. Absolute rate data for the collisional removal at 300 K of C(23PJ) by the gases 1-propanethiol, 1-butanethiol, 1-pentanethiol, 2-propanethiol, 2-methyl-1-propanethiol, 2-methyl-2-propanethiol and dimethyl sulfide are reported. All processes proceed at rates of the order of the collision numbers, supporting an overall mechanism of C-atom insertion into the S–H bond following initial addition, which is energetically favourable, a mechanism demonstrated analogously hitherto with H2S and where H-atom abstraction would also be endothermic.


LAP 2012 ◽  
2012 ◽  
pp. 85-88
Author(s):  
Jae Han Kim ◽  
Do Won Kang ◽  
Yong Jun Hong ◽  
Hyonseok Hwang ◽  
Hong Lae Kim ◽  
...  

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