Unsteady-State Direct Partial Oxidation of Methane to Synthesis Gas in a Fixed-Bed Reactor Using AFeO3(A = La, Nd, Eu) Perovskite-Type Oxides as Oxygen Storage

2006 ◽  
Vol 110 (45) ◽  
pp. 22525-22531 ◽  
Author(s):  
Xiao Ping Dai ◽  
Ran Jia Li ◽  
Chang Chun Yu ◽  
Zheng Ping Hao
Keyword(s):  
Partial Oxidation ◽  
Synthesis Gas ◽  
Fixed Bed ◽  
Partial Oxidation Of Methane ◽  
Fixed Bed Reactor ◽  
Oxygen Storage ◽  
Unsteady State ◽  
Oxidation Of Methane ◽  
Direct Partial Oxidation ◽  
Perovskite Type

CFD s tudy on partial oxidation of methane in fixed‐bed reactor

2019 ◽  
Vol 98 (3) ◽  
pp. 757-766
Author(s):  
Yonghui Li ◽  
Chao Lu ◽  
Xingxing Cao ◽  
Zhongfeng Geng ◽  
Minhua Zhang
Keyword(s):  
Partial Oxidation ◽  
Fixed Bed ◽  
Partial Oxidation Of Methane ◽  
Fixed Bed Reactor ◽  
Oxidation Of Methane

Direct Partial Oxidation of Methane to Synthesis Gas by Cerium Oxide

1998 ◽  
Vol 175 (2) ◽  
pp. 152-160 ◽  
Author(s):  
Kiyoshi Otsuka ◽  
Ye Wang ◽  
Eiyuh Sunada ◽  
Ichiro Yamanaka
Keyword(s):  
Cerium Oxide ◽  
Partial Oxidation ◽  
Synthesis Gas ◽  
Partial Oxidation Of Methane ◽  
Oxidation Of Methane ◽  
Direct Partial Oxidation

Direct partial oxidation of methane into synthesis gas over Rh|YSZ|Ag

1996 ◽  
Vol 29 (1-4) ◽  
pp. 397-402 ◽  
Author(s):  
K. Takehira ◽  
T. Hayakawa ◽  
S. Hamakawa ◽  
T. Tsunoda ◽  
K. Sato ◽  
...  
Keyword(s):  
Partial Oxidation ◽  
Synthesis Gas ◽  
Partial Oxidation Of Methane ◽  
Oxidation Of Methane ◽  
Direct Partial Oxidation

scholarly journals Oleylamine-modified impregnation method for the preparation of a highly efficient Ni/SiO2 nanocatalyst active in the partial oxidation of methane to synthesis gas

2017 ◽  
Vol 23 (2) ◽  
pp. 259-267
Author(s):  
Davarani Hosseini ◽  
Hassan Hashemipour ◽  
Alireza Talebizadeh
Keyword(s):  
Partial Oxidation ◽  
Fixed Bed ◽  
Catalytic Performance ◽  
Partial Oxidation Of Methane ◽  
Fixed Bed Reactor ◽  
High Catalytic Activity ◽  
Impregnation Method ◽  
Oxidation Of Methane ◽  
Temperature Programmed ◽  
H2 Yield

In this research, a novel modified wet impregnation method has been successfully developed to synthesize 5% Ni/SiO2 nanocatalyst with high catalytic activity and stability for the partial oxidation of methane. Oleylamine was used as a capping agent in the impregnation solution to improve Ni dispersion and interaction with silica surfaces. The product was analyzed and characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, N2 physisorption measurement and transmission electron microscopy (TEM) and temperature- -programmed H2 reduction (H2-TPR). Partial oxidation of methane over the modified catalyst was performed in a continues-flow fixed-bed reactor under atmospheric pressure at 700?C. The modified catalyst showed 91% CH4 conversion, 86% H2 yield and 95% CO selectivity, and these results almost remained constant within 5 h reaction on stream. The excellent catalytic performance of the catalyst was reasonably attributed to the small and uniform distribution of Ni nanoparticles on the support, and structural characterization confirmed this conclusion.

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