Solvent Mediated Intramolecular Photoinduced Electron Transfer in a Fluorene-Perylene Bisimide Derivative

2006 ◽  
Vol 110 (45) ◽  
pp. 12363-12371 ◽  
Author(s):  
Edda E. Neuteboom ◽  
Stefan C. J. Meskers ◽  
Edwin H. A. Beckers ◽  
Stéphanie Chopin ◽  
René A. J. Janssen
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Perylene Bisimide

Synthesis and photoinduced electron transfer characteristic of a bis (zinc porphyrin)-perylene bisimide array

2011 ◽  
Vol 24 (11) ◽  
pp. 1101-1109 ◽  
Author(s):  
Fuling Wang ◽  
Jianguo Tang ◽  
Jixian Liu ◽  
Yao Wang ◽  
Rui Wang ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Transfer Characteristic ◽  
Zinc Porphyrin ◽  
Perylene Bisimide

Photoinduced electron transfer (PET) versus excimer formation in supramolecular p/n-heterojunctions of perylene bisimide dyes and implications for organic photovoltaics

2015 ◽  
Vol 185 ◽  
pp. 507-527 ◽  
Author(s):  
Agnieszka Nowak-Król ◽  
Benjamin Fimmel ◽  
Minjung Son ◽  
Dongho Kim ◽  
Frank Würthner
Keyword(s):  
Electron Transfer ◽  
Organic Solar Cells ◽  
Photoinduced Electron Transfer ◽  
Transient Absorption ◽  
Model Systems ◽  
Transient Absorption Spectroscopy ◽  
Time Resolved ◽  
Perylene Bisimide ◽  
Excimer Formation ◽  
Molecular Semiconductor

Foldamer systems comprised of two perylene bisimide (PBI) dyes attached to the conjugated backbones of 1,2-bis(phenylethynyl)benzene and phenylethynyl-bis(phenylene)indane, respectively, were synthesized and investigated with regard to their solvent-dependent properties. UV/Vis absorption and steady-state fluorescence spectra show that both foldamers exist predominantly in a folded H-aggregated state consisting of π–π-stacked PBIs in THF and in more random conformations with weaker excitonic coupling between the PBIs in chloroform. Time-resolved fluorescence spectroscopy and transient absorption spectroscopy reveal entirely different relaxation pathways for the photoexcited molecules in the given solvents, i.e. photoinduced electron transfer leading to charge separated states for the open conformations (in chloroform) and relaxation into excimer states with red-shifted emission for the stacked conformations (in THF). Supported by redox data from cyclic voltammetry and Rehm–Weller analysis we could relate the processes occurring in these solution-phase model systems to the elementary processes in organic solar cells. Accordingly, only if relaxation pathways such as excimer formation are strictly avoided in molecular semiconductor materials, excitons may diffuse over larger distances to the heterojunction interface and produce photocurrent via the formation of electron/hole pairs by photoinduced electron transfer.

Photoinduced Electron Transfer in Hydrogen-Bonded Oligo(p-phenylene vinylene)−Perylene Bisimide Chiral Assemblies

2002 ◽  
Vol 124 (35) ◽  
pp. 10252-10253 ◽  
Author(s):  
Albertus P. H. J. Schenning ◽  
Jeroen v. Herrikhuyzen ◽  
Pascal Jonkheijm ◽  
Zhijian Chen ◽  
Frank Würthner ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Phenylene Vinylene ◽  
Perylene Bisimide ◽  
Hydrogen Bonded

Computationally Assisted Design of High Signal-to-Noise Photoinduced Electron Transfer-Based Voltage-Sensitive Dyes

2020 ◽  
Author(s):  
Rishikesh Kulkarni ◽  
Anneliese Gest ◽  
Chun Kei Lam ◽  
Benjamin Raliski ◽  
Feroz James ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Dft Calculations ◽  
Photoinduced Electron Transfer ◽  
Density Functional ◽  
Embryonic Stem ◽  
High Sensitivity ◽  
Md Simulations ◽  
High Signal ◽  
Signal To Noise ◽  
Green Fluorescent

<p>High signal-to-noise optical voltage indicators will enable simultaneous interrogation of membrane potential in large ensembles of neurons. However, design principles for voltage sensors with high sensitivity and brightness remain elusive, limiting the applicability of voltage imaging. In this paper, we use molecular dynamics (MD) simulations and density functional theory (DFT) calculations to guide the design of a bright and sensitive green-fluorescent voltage-sensitive fluorophore, or VoltageFluor (VF dye), that uses photoinduced electron transfer (PeT) as a voltage-sensing mechanism. MD simulations predict an 11% increase in sensitivity due to membrane orientation, while DFT calculations predict an increase in fluorescence quantum yield, but a decrease in sensitivity due to a decrease in rate of PeT. We confirm these predictions by synthesizing a new VF dye and demonstrating that it displays the expected improvements by doubling the brightness and retaining similar sensitivity to prior VF dyes. Combining theoretical predictions and experimental validation has resulted in the synthesis of the highest signal-to-noise green VF dye to date. We use this new voltage indicator to monitor the electrophysiological maturation of human embryonic stem cell-derived medium spiny neurons. </p>

Photoinduced electron transfer in mechanically interlocked suit[3]ane systems

2021 ◽  
Author(s):  
Anton J Stasyuk ◽  
Olga A. Stasyuk ◽  
Miquel Solà ◽  
Alexander Voityuk
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
New Class ◽  
Transfer Processes ◽  
Two Component ◽  
Electron Transfer Processes

Suitanes, a new class of two-component mechanically interlocked systems, have recently been developed. In this work, we report a detailed study of photoinduced electron transfer processes in the suit[3]anes consisting...

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