Triplet Topology of Self-Assembled Zinc Porphyrin−Pyridylfullerene Complex†

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An off-axis supramolecular rotor was composed of four components: a zinc-porphyrin based stator with four phenanthroline stations and a zinc-salphen based rotator were self-assembled with DABCO and four copper(i) ions to furnish the rotor ROT-2 in quantitative yield.


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