Unusual Solvent Effect on a SN2 Reaction. A Quantum-Mechanical and Kinetic Study of the Menshutkin Reaction between 2-Amino-1-methylbenzimidazole and Iodomethane in the Gas Phase and in Acetonitrile

2006 ◽  
Vol 110 (4) ◽  
pp. 1877-1888 ◽  
Author(s):  
André Melo ◽  
António J. I. Alfaia ◽  
João Carlos R. Reis ◽  
António R. T. Calado
Keyword(s):  
Solvent Effect ◽  
Kinetic Study ◽  
Gas Phase ◽  
Quantum Mechanical ◽  
Menshutkin Reaction ◽  
Sn2 Reaction

Reesterification of ethyl acetate by propanol catalysed by glycidyl methacrylate copolymers containing sulphonic acid groups

1981 ◽  
Vol 46 (8) ◽  
pp. 1941-1946 ◽  
Author(s):  
Karel Setínek
Keyword(s):  
Liquid Phase ◽  
Ethyl Acetate ◽  
Kinetic Study ◽  
Gas Phase ◽  
Nonlinear Regression ◽  
Kinetic Data ◽  
Glycidyl Methacrylate ◽  
Kinetic Equations ◽  
Methacrylate Copolymers ◽  
Styrene Divinylbenzene

A series of differently crosslinked macroporous 2,3-epoxypropyl methacrylate-ethylenedimethacrylate copolymers with chemically bonded propylsulphonic acid groups were used as catalysts for the kinetic study of reesterification of ethyl acetate by n-propanol in the liquid phase at 52 °C and in the gas phase at 90 °C. Analysis of kinetic data by the method of nonlinear regression for a series of equations of the Langmuir-Hinshelwood type showed that kinetic equations which describe best the course of the reaction are the same as for the earlier studied sulphonated macroporous styrene-divinylbenzene copolymers. Compared types of catalysts differ, however, in the dependence of their activity on the degree of crosslinking of the copolymer used.

An homogeneous growth model of gallium arsenide epitaxial layers from the gas phase

1989 ◽  
Vol 54 (11) ◽  
pp. 2933-2950
Author(s):  
Emerich Erdös ◽  
Petr Voňka ◽  
Josef Stejskal ◽  
Přemysl Klíma
Keyword(s):  
Experimental Data ◽  
Gallium Arsenide ◽  
Kinetic Study ◽  
Gas Phase ◽  
Growth Model ◽  
Epitaxial Layers ◽  
Inhomogeneous Model ◽  
Homogeneous Models ◽  
Active Centres

This paper represents a continuation and ending of the kinetic study of the gallium arsenide formation, where a so-called inhomogeneous model is proposed and quantitatively formulated in five variants, in which two kinds of active centres appear. This model is compared both with the experimental data and with the previous sequence of homogeneous models.

Kinetic Study of the Gas-Phase Reactions of Cl Radicals with 3-Pentanone and 3-Hexanone

2004 ◽  
Vol 108 (34) ◽  
pp. 7027-7031 ◽  
Author(s):  
Alfonso Aranda ◽  
Yolanda Díaz de Mera ◽  
Ana Rodríguez ◽  
Lorena Morales ◽  
Ernesto Martínez
Keyword(s):  
Kinetic Study ◽  
Gas Phase ◽  
Gas Phase Reactions

SN2 reaction profiles in the gas phase and aqueous solution

1984 ◽  
Vol 106 (10) ◽  
pp. 3049-3050 ◽  
Author(s):  
Jayaraman Chandrasekhar ◽  
Scott F. Smith ◽  
William L. Jorgensen
Keyword(s):  
Aqueous Solution ◽  
Gas Phase ◽  
Sn2 Reaction

Photocatalytic Degradation of Tetrachloroethylene in Gas Phase on TiO2Films:  A Kinetic Study

2005 ◽  
Vol 44 (16) ◽  
pp. 6075-6085 ◽  
Author(s):  
Gustavo E. Imoberdorf ◽  
Horacio A. Irazoqui ◽  
Alberto E. Cassano ◽  
Orlando M. Alfano
Keyword(s):  
Photocatalytic Degradation ◽  
Kinetic Study ◽  
Gas Phase

Mechanism and kinetic study on the gas-phase reactions of OH radical with carbamate insecticide isoprocarb

2012 ◽  
Vol 60 ◽  
pp. 460-466 ◽  
Author(s):  
Chenxi Zhang ◽  
Wenbo Yang ◽  
Jing Bai ◽  
Yuyang Zhao ◽  
Chen Gong ◽  
...  
Keyword(s):  
Kinetic Study ◽  
Gas Phase ◽  
Oh Radical ◽  
Gas Phase Reactions ◽  
Carbamate Insecticide
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