Electron Transport Across the Alkanethiol Self-assembled Monolayer/Au(111) Interface:  Role of the Chemical Anchor

2005 ◽  
Vol 109 (46) ◽  
pp. 21492-21495 ◽  
Author(s):  
C. D. Lindstrom ◽  
M. Muntwiler ◽  
X.-Y. Zhu
Keyword(s):  
Electron Transport ◽  
Self Assembled Monolayer ◽  
Self Assembled

Experiments and Molecular Simulations to Study the Role of Coadsorption of Oil in Corrosion Inhibitor Films in Improving Corrosion Mitigation

CORROSION ◽  
10.5006/3606 ◽  
2020 ◽  
Vol 76 (11) ◽  
Author(s):  
Xueying Ko ◽  
Juan Dominguez Olivo ◽  
Bruce Brown ◽  
Srdjan Nešić ◽  
Sumit Sharma
Keyword(s):  
Aqueous Solution ◽  
Corrosion Inhibitor ◽  
Metal Surfaces ◽  
Laboratory Experiments ◽  
Field Experience ◽  
Molecular Simulations ◽  
Self Assembled Monolayer ◽  
Polar Head ◽  
Self Assembled

While both field experience and laboratory experiments have shown that the efficiency of adsorbed corrosion inhibitor films improves upon exposure of the aqueous solution to a hydrocarbon phase, a credible explanation of these results is lacking. Using a combination of experiments and molecular simulations, this study examines how exposure to oil molecules affects the nature of adsorbed corrosion inhibitor films on metal surfaces. It is found that oil molecules get coadsorbed in the corrosion inhibitor films, making them more hydrophobic, structurally more ordered, and well packed. Corrosion inhibitor molecules with a bulky polar head adsorb in nonplanar, cylinder-like morphologies. Coadsorption of oil molecules changes the morphology of these films to a planar self-assembled monolayer.

Electron Transport through a Self-Assembled Monolayer of Thiol-End-Functionalized Tetraphenylporphines and Metal Tetraphenylporphines

Langmuir ◽  
2006 ◽  
Vol 22 (7) ◽  
pp. 3035-3039 ◽  
Author(s):  
Xiaoquan Lu ◽  
Minrui Li ◽  
Chunhe Yang ◽  
Limin Zhang ◽  
Yongfang Li ◽  
...  
Keyword(s):  
Electron Transport ◽  
Self Assembled Monolayer ◽  
Self Assembled

scholarly journals Molecular gate effects observed in fluoroalkylsilane self-assembled monolayer grafted on LiNi0.5Mn1.5O4 cathodes: An application to efficient ion-exchanging reaction

2021 ◽  
Author(s):  
Youn Charles-Blin ◽  
Hitomi Todoki ◽  
Nobuyuki Zettsu ◽  
Katsuya Teshima
Keyword(s):  
High Voltage ◽  
Self Assembled Monolayers ◽  
Self Assembled Monolayer ◽  
Electrolyte Interface ◽  
Assembled Monolayers ◽  
Self Assembled

We demonstrated the role of fluoroalkylsilane (FAS) self-assembled monolayers in improving the high-voltage durability and C-rate capabilities of spinel LiNi0.5Mn1.5O4 (LNMO) cathodes. The influence of the cathode–electrolyte interface (CEI) layer...

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