Development of New Photocatalytic Water Splitting into H2and O2using Two Different Semiconductor Photocatalysts and a Shuttle Redox Mediator IO3-/I-

2005 ◽  
Vol 109 (33) ◽  
pp. 16052-16061 ◽  
Author(s):  
Ryu Abe ◽  
Kazuhiro Sayama ◽  
Hideki Sugihara
2019 ◽  
Vol 9 (8) ◽  
pp. 2019-2024 ◽  
Author(s):  
Yugo Miseki ◽  
Kazuhiro Sayama

Surface-modified WO3, as an oxygen evolution photocatalyst for Z-scheme water splitting employing a [Fe(CN)6]3−/4− redox mediator, is successfully constructed.


2016 ◽  
Vol 518 ◽  
pp. 158-166 ◽  
Author(s):  
Sheng-Hung Yu ◽  
Cheng-Wei Chiu ◽  
Yi-Ting Wu ◽  
Chi-Hung Liao ◽  
Van-Huy Nguyen ◽  
...  

2015 ◽  
Vol 5 (5) ◽  
pp. 2640-2648 ◽  
Author(s):  
Hajime Suzuki ◽  
Osamu Tomita ◽  
Masanobu Higashi ◽  
Ryu Abe

Two-step water splitting into H2 and O2 is demonstrated using KCa2Nb3O10 and its derivatives as O2-evolving photocatalysts combined with a H2-evolving photocatalyst in the presence of IO3−/I− or Fe3+/Fe2+ as an electron mediator.


2020 ◽  
Vol 8 (40) ◽  
pp. 20963-20969 ◽  
Author(s):  
Wei Chen ◽  
Guo-Bo Huang ◽  
Hao Song ◽  
Jian Zhang

An efficient charge transfer channel for improving the photocatalytic water splitting activity and durability of CdS without sacrificial agents.


Materials ◽  
2020 ◽  
Vol 13 (6) ◽  
pp. 1338 ◽  
Author(s):  
Klara Perović ◽  
Francis M. dela Rosa ◽  
Marin Kovačić ◽  
Hrvoje Kušić ◽  
Urška Lavrenčič Štangar ◽  
...  

Clean water and the increased use of renewable energy are considered to be two of the main goals in the effort to achieve a sustainable living environment. The fulfillment of these goals may include the use of solar-driven photocatalytic processes that are found to be quite effective in water purification, as well as hydrogen generation. H2 production by water splitting and photocatalytic degradation of organic pollutants in water both rely on the formation of electron/hole (e−/h+) pairs at a semiconducting material upon its excitation by light with sufficient photon energy. Most of the photocatalytic studies involve the use of TiO2 and well-suited model compounds, either as sacrificial agents or pollutants. However, the wider application of this technology requires the harvesting of a broader spectrum of solar irradiation and the suppression of the recombination of photogenerated charge carriers. These limitations can be overcome by the use of different strategies, among which the focus is put on the creation of heterojunctions with another narrow bandgap semiconductor, which can provide high response in the visible light region. In this review paper, we report the most recent advances in the application of TiO2 based heterojunction (semiconductor-semiconductor) composites for photocatalytic water treatment and water splitting. This review article is subdivided into two major parts, namely Photocatalytic water treatment and Photocatalytic water splitting, to give a thorough examination of all achieved progress. The first part provides an overview on photocatalytic degradation mechanism principles, followed by the most recent applications for photocatalytic degradation and mineralization of contaminants of emerging concern (CEC), such as pharmaceuticals and pesticides with a critical insight into removal mechanism, while the second part focuses on fabrication of TiO2-based heterojunctions with carbon-based materials, transition metal oxides, transition metal chalcogenides, and multiple composites that were made of three or more semiconductor materials for photocatalytic water splitting.


Sign in / Sign up

Export Citation Format

Share Document