Influence of the Environment on Photoinduced Electron Transfer:  Comparison between Organized Monolayers at the Air−Water Interface and Monolayer Assemblies on Glass

2005 ◽  
Vol 109 (47) ◽  
pp. 22386-22391 ◽  
Author(s):  
I. Sández-Macho ◽  
J. Gonzalez-López ◽  
A. Suárez-Varela ◽  
D. Möbius
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Water Interface ◽  
Air Water Interface

Photoinduced electron transfer in a monolayer at the air-water interface

1992 ◽  
Vol 96 (14) ◽  
pp. 5939-5942 ◽  
Author(s):  
Mutsuyoshi Matsumoto ◽  
Ramesh C. Ahuja ◽  
Dietmar Moebius
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Water Interface ◽  
Air Water Interface

Electron Transfer Photofragmentation Reactions in Monolayer Films at the Air/Water Interface

Langmuir ◽  
1998 ◽  
Vol 14 (13) ◽  
pp. 3663-3672 ◽  
Author(s):  
Lucian A. Lucia ◽  
Kataryna Wyrozebski ◽  
Liaohai Chen ◽  
Cristina Geiger ◽  
David G. Whitten
Keyword(s):  
Electron Transfer ◽  
Water Interface ◽  
Monolayer Films ◽  
Air Water Interface

Photoinduced electron transfer in molecular organizates at the gas-water interface

1994 ◽  
Vol 243 (1-2) ◽  
pp. 564-568 ◽  
Author(s):  
Pier-Lorenzo Caruso ◽  
Ramesh C. Ahuja ◽  
Dietmar Möbius ◽  
Gerald Wildburg ◽  
Helmut Ringsdorf
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Water Interface

Photoinduced electron transfer in monolayers at the monolayer-water interface

1992 ◽  
Vol 210-211 ◽  
pp. 335-337 ◽  
Author(s):  
Gabriella Caminati ◽  
Ramesh C. Ahuja ◽  
Dietmar Möbius
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Water Interface

Sampling and analysis of the air-water interface with SEM and EDS of microlayers

1989 ◽  
Vol 47 ◽  
pp. 1004-1005
Author(s):  
Randall W. Smith ◽  
John Dash
Keyword(s):  
Heavy Metals ◽  
Surface Microlayer ◽  
Surface Films ◽  
Water Interface ◽  
Physical Processes ◽  
Infrared Spectroscopic Analysis ◽  
Eds Analysis ◽  
Air Water Interface ◽  
Significant Area ◽  
Bulk Chemical

The structure of the air-water interface forms a boundary layer that involves biological ,chemical geological and physical processes in its formation. Freshwater and sea surface microlayers form at the air-water interface and include a diverse assemblage of organic matter, detritus, microorganisms, plankton and heavy metals. The sampling of microlayers and the examination of components is presently a significant area of study because of the input of anthropogenic materials and their accumulation at the air-water interface. The neustonic organisms present in this environment may be sensitive to the toxic components of these inputs. Hardy reports that over 20 different methods have been developed for sampling of microlayers, primarily for bulk chemical analysis. We report here the examination of microlayer films for the documentation of structure and composition.Baier and Gucinski reported the use of Langmuir-Blogett films obtained on germanium prisms for infrared spectroscopic analysis (IR-ATR) of components. The sampling of microlayers has been done by collecting fi1ms on glass plates and teflon drums, We found that microlayers could be collected on 11 mm glass cover slips by pulling a Langmuir-Blogett film from a surface microlayer. Comparative collections were made on methylcel1ulose filter pads. The films could be air-dried or preserved in Lugol's Iodine Several slicks or surface films were sampled in September, 1987 in Chesapeake Bay, Maryland and in August, 1988 in Sequim Bay, Washington, For glass coverslips the films were air-dried, mounted on SEM pegs, ringed with colloidal silver, and sputter coated with Au-Pd, The Langmuir-Blogett film technique maintained the structure of the microlayer intact for examination, SEM observation and EDS analysis were then used to determine organisms and relative concentrations of heavy metals, using a Link AN 10000 EDS system with an ISI SS40 SEM unit. Typical heavy microlayer films are shown in Figure 3.

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