Anomalous Thermal Behavior of Salicylsalicylic Acid and Evidence for a Monotropic Transition to a Nematic Phase

2004 ◽  
Vol 108 (23) ◽  
pp. 7955-7962 ◽  
Author(s):  
Joaquim J. Moura Ramos ◽  
Hermínio P. Diogo ◽  
Maria Helena Godinho ◽  
Carlos Cruz ◽  
Katarzyna Merkel
2008 ◽  
Vol 373-374 ◽  
pp. 678-681 ◽  
Author(s):  
Chun Xiu Zhang ◽  
Zhi Qun He ◽  
Jia Ling Pu ◽  
Jun Jie Wang ◽  
Yong Sheng Wang ◽  
...  

A novel discotic triphenylene derivative bearing one triphenylene discogen as core and three cyano-biphenyl moieties was synthesized and its thermal behavior was studied using polarizing optical microscope, differential scanning calorimeter and X-ray diffraction. It was found that this molecule containing [decylene?] spacers showed nematic phase. After being mixed with methyl methacrylate (MMA), the discogen showed nematic phase at the mesophase temperature range (64~85 °C) and oriented spontaneously in the mixture after annealing for 2 hours in the mixture. The orientation can be stabilized by the polymerization of MMA. The orientation can be fixed by the polymerization of MMA. It was treated directly on glass substrate, which surface did not treat by polyimide film and confirmed the orientation was proved by X-ray diffraction. This offers If the alignment of the discotic molecules can be freely controlled and fixed, a useful mean to produce new area of optically anisotropic film will be produced with this material.


2020 ◽  
Vol 40 (suppl 2) ◽  
pp. 597-604
Author(s):  
Zahra NILCHIAN ◽  
Mohamad Reza EHSANI ◽  
Zahra PIRAVI-VANAK ◽  
Hossein BAKHODA

2019 ◽  
Vol 50 (17) ◽  
pp. 1721-1736
Author(s):  
Kaiqiang Hou ◽  
Xiaolong Weng ◽  
Wei Luo ◽  
Le Yuan ◽  
Wei Duan ◽  
...  

2011 ◽  
Vol 7 (2) ◽  
pp. 1338-1347
Author(s):  
Tarek Ali Fahad ◽  
Shaker.A.N. AL-Jadaan

Two new heterocyclic Organmercury compounds   were prepared from the reaction of Sulfamethaxazole and Sulfadiazine with 4-acetaminophenol as a coupler and separated as solids with characteristic colors. these compounds were characterized by F.T.IR-spectroscopy 1H-NMR , Micro-elemental Analysis and UV-Vis spectroscopic techniques . The work involves a study of acid – base properties compounds at different pH values, the ionization and protonation constants were calculated. The thermal behavior of these two compounds   were investigated on the basis of thermogravimetric (TGA) and differential thermogravimetric (DTG) analyses, Thermal decomposition of these compounds is multi-stage processes.


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