High-Surface-Area Catalyst Design:  Synthesis, Characterization, and Reaction Studies of Platinum Nanoparticles in Mesoporous SBA-15 Silica†

2005 ◽  
Vol 109 (6) ◽  
pp. 2192-2202 ◽  
Author(s):  
R. M. Rioux ◽  
H. Song ◽  
J. D. Hoefelmeyer ◽  
P. Yang ◽  
G. A. Somorjai
Keyword(s):  
Surface Area ◽  
Platinum Nanoparticles ◽  
High Surface ◽  
High Surface Area ◽  
Catalyst Design ◽  
Design Synthesis

Oriented Catalytic Platinum Nanoparticles on High Surface Area Strontium Titanate Nanocuboids

Nano Letters ◽  
2011 ◽  
Vol 11 (3) ◽  
pp. 993-997 ◽  
Author(s):  
James A. Enterkin ◽  
Kenneth R. Poeppelmeier ◽  
Laurence D. Marks
Keyword(s):  
Surface Area ◽  
Strontium Titanate ◽  
Platinum Nanoparticles ◽  
High Surface ◽  
High Surface Area

scholarly journals Catalysis of Methanol-Air Mixture Using Platinum Nanoparticles for Microscale Combustion

2012 ◽  
Vol 2012 ◽  
pp. 1-8 ◽  
Author(s):  
James R. Applegate ◽  
Howard Pearlman ◽  
Smitesh D. Bakrania
Keyword(s):  
Surface Area ◽  
Platinum Nanoparticles ◽  
Flow Reactor ◽  
Catalyst Activity ◽  
High Surface ◽  
High Surface Area ◽  
Catalyst Loading ◽  
Bulk Temperature ◽  
Flow Parameters ◽  
The Stability

High surface area, active catalysts containing dispersed catalytic platinum nanoparticles (dp∼11.6 nm) on a cordierite substrate were fabricated and characterized using TEM, XRD, and SEM. The catalyst activity was evaluated for methanol oxidation. Experimental results were obtained in a miniature-scale continuous flow reactor. Subsequent studies on the effect of catalyst loading and reactor flow parameters are reported. Repeat tests were performed to assess the stability of the catalyst and the extent of deactivation, if any, that occurred due to restructuring and sintering of the particles. SEM characterization studies performed on the postreaction catalysts following repeat tests at reasonably high operating temperatures (∼500°C corresponding to ∼0.3Tmfor bulk platinum) showed evidence of sintering, yet the associated loss of surface area had minimal effect on the overall catalyst activity, as determined from bulk temperature measurements. The potential application of this work for improving catalytic devices including microscale reactors is also briefly discussed.

Oriented Catalytic Platinum Nanoparticles on High Surface Area Strontium Titanate Nanocuboids

Nano Letters ◽  
2011 ◽  
Vol 11 (8) ◽  
pp. 3510-3510 ◽  
Author(s):  
James A. Enterkin ◽  
Kenneth R. Poeppelmeier ◽  
Laurence D. Marks
Keyword(s):  
Surface Area ◽  
Strontium Titanate ◽  
Platinum Nanoparticles ◽  
High Surface ◽  
High Surface Area

Tenacious Mass Transfer Limitations Drive Catalytic Selectivity during Electrochemical Carbon Dioxide Reduction

2019 ◽  
Author(s):  
Kailun Yang ◽  
Recep Kas ◽  
Wilson A. Smith
Keyword(s):  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Catalyst Layer ◽  
Active Surface ◽  
Active Surface Area ◽  
High Concentration ◽  
Copper Electrodes ◽  
Surface Enhanced ◽  
Local Current

<p>This study evaluated the performance of the commonly used strong buffer electrolytes, i.e. phosphate buffers, during CO<sub>2</sub> electroreduction in neutral pH conditions by using in-situ surface enhanced infrared absorption spectroscopy (SEIRAS). Unfortunately, the buffers break down a lot faster than anticipated which has serious implications on many studies in the literature such as selectivity and kinetic analysis of the electrocatalysts. Increasing electrolyte concentration, surprisingly, did not extend the potential window of the phosphate buffers due to dramatic increase in hydrogen evolution reaction. Even high concentration phosphate buffers (1 M) break down within the potentials (-1 V vs RHE) where hydrocarbons are formed on copper electrodes. We have extended the discussion to high surface area electrodes by evaluating electrodes composed of copper nanowires. We would like highlight that it is not possible to cope with high local current densities on these high surface area electrodes by using high buffer capacity solutions and the CO<sub>2</sub> electrocatalysts are needed to be evaluated by casting thin nanoparticle films onto inert substrates as commonly employed in fuel cell reactions and up to now scarcely employed in CO<sub>2</sub> electroreduction. In addition, we underscore that normalization of the electrocatalytic activity to the electrochemical active surface area is not the ultimate solution due to concentration gradient along the catalyst layer.This will “underestimate” the activity of high surface electrocatalyst and the degree of underestimation will depend on the thickness, porosity and morphology of the catalyst layer. </p> <p> </p>

scholarly journals Rugae-like FeP nanocrystal assembly on a carbon cloth: an exceptionally efficient and stable cathode for hydrogen evolution

Nanoscale ◽  
2015 ◽  
Vol 7 (25) ◽  
pp. 10974-10981 ◽  
Author(s):  
Xiulin Yang ◽  
Ang-Yu Lu ◽  
Yihan Zhu ◽  
Shixiong Min ◽  
Mohamed Nejib Hedhili ◽  
...  
Keyword(s):  
Gas Phase ◽  
Surface Area ◽  
Hydrogen Evolution ◽  
Hydrogen Generation ◽  
High Surface ◽  
High Surface Area ◽  
Catalytic Efficiency ◽  
Carbon Cloth ◽  
Nanocrystal Assembly

High surface area FeP nanosheets on a carbon cloth were prepared by gas phase phosphidation of electroplated FeOOH, which exhibit exceptionally high catalytic efficiency and stability for hydrogen generation.

High Surface Area NiCoP Nanostructure as Efficient Water Splitting Electrocatalyst for the Oxygen Evolution Reaction

2021 ◽  
pp. 111312
Author(s):  
Sisir Maity ◽  
Dheeraj Kumar Singh ◽  
Divya Bhutani ◽  
Suchitra Prasad ◽  
Umesh V. Waghmare ◽  
...  
Keyword(s):  
Surface Area ◽  
Water Splitting ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Surface ◽  
High Surface Area

scholarly journals Fast synthesis of high surface area bio-based porous carbons for p-nitrophenol removal

MethodsX ◽  
2021 ◽  
pp. 101464
Author(s):  
Yichen Wu ◽  
Nan Zhang ◽  
Charles-François de Lannoy
Keyword(s):  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Porous Carbons ◽  
Fast Synthesis

Synthesis of high surface area and functionalized nanoporous biocarbons and their efficiency for CO2 capture and supercapacitors

2021 ◽  
Author(s):  
Gurwinder Singh ◽  
Rohan Bahadur ◽  
Ajanya Maria Ruban ◽  
Jefrin Marykala Davidraj ◽  
Dawei Su ◽  
...  
Keyword(s):  
Energy Storage ◽  
Surface Area ◽  
Co2 Capture ◽  
Water Purification ◽  
High Surface ◽  
High Surface Area ◽  
Energy Storage And Conversion ◽  
Waste Biomass ◽  
Fabrication Technology ◽  
Significant Attention

Nanoporous biocarbons derived from waste biomass have created significant attention owing to their great potential for energy storage and conversion and water purification. However, the fabrication technology for these materials...

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