Thermal Stability of Au Nanoparticles in O2and Air on Fully Oxidized TiO2(110) Substrates at Elevated Pressures. An AFM/XPS Study of Au/TiO2Model Systems

2004 ◽  
Vol 108 (50) ◽  
pp. 19184-19190 ◽  
Author(s):  
S. Kielbassa ◽  
M. Kinne ◽  
R. J. Behm
2020 ◽  
Author(s):  
O. S. Bezkrovnyi ◽  
P. Kraszkiewicz ◽  
W. Mista ◽  
L. Kepinski

Abstract The thermal stability of Au nanoparticles on ceria support of various morphology (nanocubes, nanooctahedra, and {111}-nanofacetted nanocubes) in oxidizing and reducing atmospheres was investigated by electron microscopy. A beneficial effect of the reconstruction of edges of ceria nanocubes into zigzagged {111}-nanofacetted structures on the inhibition of sintering of Au nanoparticles was shown. The influence of different morphology of Au particles on various ceria supports on the reducibility and catalytic activity in CO oxidation, and CO PROX of Au/ceria catalysts was also investigated and discussed. It was shown, that ceria nanocubes with flat {110} terminated edges are more suitable as a support for Au nanoparticles, used to catalyze CO oxidation, than zigzagged {111}- nanofacetted structures. Graphic Abstract


2017 ◽  
Vol 31 (07) ◽  
pp. 1741001
Author(s):  
Yanlin Jia ◽  
Siqi Li ◽  
Weihong Qi ◽  
Mingpu Wang ◽  
Zhou Li ◽  
...  

Molecular dynamics (MDs) simulations were used to explore the thermal stability of Au nanoparticles (NPs) with decahedral, cuboctahedral, icosahedral and Marks NPs. According to the calculated cohesive energy and melting temperature, the Marks NPs have a higher cohesive energy and melting temperature compared to these other shapes. The Lindemann index, radial distribution function, deformation parameters, mean square displacement and self-diffusivity have been used to characterize the structure variation during heating. This work may inspire researchers to prepare Marks NPs and apply them in different fields.


1986 ◽  
Vol 5 (4) ◽  
pp. 238-251 ◽  
Author(s):  
Laurence G. Britton ◽  
D. Alex Taylor ◽  
Donald C. Wobser

2019 ◽  
Author(s):  
Tetsuya Miyazawa ◽  
Masashi Kurihara ◽  
Shinya Ohno ◽  
Takashi Kikuchi ◽  
Kazuhiko Mase

2019 ◽  
Vol 7 (18) ◽  
pp. 10980-10987 ◽  
Author(s):  
Xiaoqing Cao ◽  
Jun Zhou ◽  
Hongna Wang ◽  
Song Li ◽  
Wei Wang ◽  
...  

Abnormal thermal stability and high catalytic activity of sub-10 nm Au nanoparticles prepared by novel interfacial plasma electrolytic oxidation.


Langmuir ◽  
2012 ◽  
Vol 28 (14) ◽  
pp. 6045-6051 ◽  
Author(s):  
Yonghe Pan ◽  
Yan Gao ◽  
Dandan Kong ◽  
Guodong Wang ◽  
Jianbo Hou ◽  
...  

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