Competitive Marcus-Type Electron Transfer and Energy Transfer from the Higher Triplet Excited State

2004 ◽  
Vol 108 (50) ◽  
pp. 10941-10948 ◽  
Author(s):  
Masanori Sakamoto ◽  
Xichen Cai ◽  
Michihiro Hara ◽  
Sachiko Tojo ◽  
Mamoru Fujitsuka ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Energy Transfer ◽  
Excited State ◽  
Triplet Excited State

scholarly journals Orthogonally Aligned Cyclic BODIPY Arrays with Long-lived Triplet Excited States as Efficient Heavy-Atom-Free Photosensitizers

2021 ◽  
Author(s):  
Zhaoyang Zhu ◽  
Xue Zhang ◽  
Xing Guo ◽  
Qing-Hua Wu ◽  
Zhongxin Li ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Energy Transfer ◽  
Excited State ◽  
Excited States ◽  
Heavy Atom ◽  
Triplet Excited State ◽  
Transfer Processes ◽  
Excited State Lifetimes ◽  
Triplet Excited States

Photosensitizers with long triplet excited state lifetimes are key to their efficient electron transfer or energy transfer processes. Herein, we report a novel class of cyclic trimeric BODIPY arrays which...

Preparation of Bodipy–ferrocene dyads and modulation of the singlet/triplet excited state of bodipy via electron transfer and triplet energy transfer

2016 ◽  
Vol 4 (14) ◽  
pp. 2843-2853 ◽  
Author(s):  
Xueyan Wu ◽  
Wenting Wu ◽  
Xiaoneng Cui ◽  
Jianzhang Zhao ◽  
Mingbo Wu
Keyword(s):  
Electron Transfer ◽  
Energy Transfer ◽  
Excited State ◽  
Excited States ◽  
Singlet Excited State ◽  
Triplet Excited State ◽  
Triplet Energy ◽  
Triplet Excited States ◽  
Triplet Energy Transfer

Bodipy–ferrocene dyads were prepared for reversible electrochemical switching of the singlet excited state (fluorescence), as well as the triplet excited states of Bodipy.

Light harvesting phthalocyanine/subphthalocyanine system: intermolecular electron-transfer and energy-transfer reactions via the triplet subphthalocyanine

2011 ◽  
Vol 15 (02) ◽  
pp. 111-117 ◽  
Author(s):  
Mohamed E. El-Khouly ◽  
Shunichi Fukuzumi
Keyword(s):  
Electron Transfer ◽  
Energy Transfer ◽  
Excited State ◽  
Transfer Process ◽  
Radical Anion ◽  
Transient Absorption ◽  
Nanosecond Laser ◽  
Triplet Excited State ◽  
Intermolecular Electron Transfer ◽  
Absorption Bands

Photoinduced electron transfer from the electron-donating zinc tetra-tert-butylphthalocyanine, ZnTBPc , to the electron-accepting dodecafluorosubphthalocyanine, SubPcF12 , in the polar benzonitrile has been investigated with nanosecond laser photolysis method. The examined ZnTBPc/SubPcF12 mixture absorbs the light in a wide section of the UV/vis/NIR spectra. Owing to the particular electronic properties of both entities, such combination seems to be perfectly suited for the study of intermolecular electron-transfer process in the polar solvents via the triplet-excited state of SubPcF12 . Upon excitation of SubPcF12 with 570 nm laser light in polar benzonitrile (εs = 25.2), the electron transfer from ZnTBPc to the triplet-excited state of SubPcF12 was confirmed by observing the transient absorption bands of ZnTBPc radical cation and SubPcF12 radical anion in the visible and near-IR region. On addition of an appropriate electron acceptor with excellent electron-accepting properties, namely dicyanoperylene-3,4,9,10-bis(dicarboximide) ( PDICN2 ), the anion radical of SubPcF12 transfers to the PDICN2 yielding the PDICN2 radical anion. These observations confirm the photosensitized electron-transfer/electron-mediating cycle of ZnTBPc/SubPcF12/PDICN2 system. In non-polar toluene (εs = 2.2), the energy-transfer process from the triplet-excited state of SubPcF12 to the low-lying triplet state of ZnTBPc was confirmed by the consecutive appearance of the triplet ZnTBPc .

Near-infrared-induced electron transfer of an uranyl macrocyclic complex without energy transfer to dioxygen

2015 ◽  
Vol 51 (31) ◽  
pp. 6757-6760 ◽  
Author(s):  
Christina M. Davis ◽  
Kei Ohkubo ◽  
I-Ting Ho ◽  
Zhan Zhang ◽  
Masatoshi Ishida ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Energy Transfer ◽  
Excited State ◽  
Near Infrared ◽  
State Energy ◽  
Macrocyclic Complex ◽  
Triplet Excited State ◽  
Excited State Energy

An uranyl macrocyclic complex acts as an NIR-absorbing photosensitiser with a low triplet excited state energy, undergoing NIR-induced electron transfer.

scholarly journals Electron Transfer Initiated Reactions Photoinduced by Pterins

Pteridines ◽  
2011 ◽  
Vol 22 (1) ◽  
pp. 111-119 ◽  
Author(s):  
Carolina Lorente ◽  
Gabriela Petroselli ◽  
M. Laura Dántola ◽  
Esther Oliveros ◽  
Andrés H. Thomas
Keyword(s):  
Electron Transfer ◽  
Excited State ◽  
Redox Reactions ◽  
Type I ◽  
Biological Processes ◽  
Type Ii ◽  
Triplet Excited State ◽  
Oxygen Production ◽  
Production Type ◽  
Transfer Mechanisms

Abstract Interest in the photochemistry and photophysics of pterins has increased since the participation of this family of compounds in different photobiological processes has been suggested or demonstrated in recent decades. Pterins participate in relevant biological processes, such as metabolic redox reactions, and can photoinduce the oxidation of biomolecules through both electron transfer mechanisms (Type I) and singlet oxygen production (Type II). This article describes recent findings on electron transfer-initiated reactions photoinduced by the triplet excited state of pterins and connects them in the context of photosensitized processes of biological relevance.

scholarly journals Sensitization of ultra-long-range excited-state electron transfer by energy transfer in a polymerized film

2012 ◽  
Vol 109 (38) ◽  
pp. 15132-15135 ◽  
Author(s):  
Akitaka Ito ◽  
David J. Stewart ◽  
Zhen Fang ◽  
M. Kyle Brennaman ◽  
Thomas J. Meyer
Keyword(s):  
Electron Transfer ◽  
Energy Transfer ◽  
Excited State ◽  
Charge Transfer ◽  
Long Range ◽  
Methyl Viologen ◽  
Polymer Network ◽  
Triplet Energy ◽  
Ligand Charge Transfer ◽  
Triplet Energy Transfer

Distance-dependent energy transfer occurs from the Metal-to-Ligand Charge Transfer (MLCT) excited state to an anthracene-acrylate derivative (Acr-An) incorporated into the polymer network of a semirigid poly(ethyleneglycol)dimethacrylate monolith. Following excitation, to Acr-An triplet energy transfer occurs followed by long-range, Acr-3An—Acr-An → Acr-An—Acr-3An, energy migration. With methyl viologen dication (MV2+) added as a trap, Acr-3An + MV2+ → Acr-An+ + MV+ electron transfer results in sensitized electron transfer quenching over a distance of approximately 90 Å.

Sign in / Sign up

Export Citation Format

Share Document