Raman Microspectroscopic Study on Polymerization and Degradation Processes of a Diacetylene Derivative at Surface Enhanced Raman Scattering Active Substrates. 2. Confocal Raman Microscopic Observation of Polydiacetylene Adsorbed on Active Sites

2005 ◽  
Vol 109 (1) ◽  
pp. 271-276 ◽  
Author(s):  
K. Itoh ◽  
I. Kudryashov ◽  
J. Yamagata ◽  
T. Nishizawa ◽  
M. Fujii ◽  
...  
Keyword(s):  
Raman Scattering ◽  
Microscopic Observation ◽  
Active Sites ◽  
Surface Enhanced Raman Scattering ◽  
Degradation Processes ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering ◽  
Confocal Raman ◽  
Diacetylene Derivative

Mesoporous semiconducting TiO2 with rich active sites as a remarkable substrate for surface-enhanced Raman scattering

2017 ◽  
Vol 19 (28) ◽  
pp. 18731-18738 ◽  
Author(s):  
Libin Yang ◽  
Di Yin ◽  
Yu Shen ◽  
Ming Yang ◽  
Xiuling Li ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Raman Scattering ◽  
Active Sites ◽  
Surface Enhanced Raman Scattering ◽  
Transfer Mechanism ◽  
Charge Transfer Mechanism ◽  
Highly Active ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

Mesoporous TiO2 with highly active sites was used as an effective and recyclable substrate for SERS contributed by the charge-transfer mechanism.

Nature of Surface-Enhanced-Raman-Scattering Active Sites on Coldly Condensed Ag Films

1983 ◽  
Vol 51 (25) ◽  
pp. 2314-2317 ◽  
Author(s):  
E. V. Albano ◽  
S. Daiser ◽  
G. Ertl ◽  
R. Miranda ◽  
K. Wandelt ◽  
...  
Keyword(s):  
Raman Scattering ◽  
Active Sites ◽  
Surface Enhanced Raman Scattering ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

scholarly journals A DFT Approach to the Surface-Enhanced Raman Scattering of 4-Cyanopyridine Adsorbed on Silver Nanoparticles

Nanomaterials ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 1211 ◽  
Author(s):  
Isabel López-Tocón ◽  
Samuel Valdivia ◽  
Juan Soto ◽  
Juan Carlos Otero ◽  
Francesco Muniz-Miranda ◽  
...  
Keyword(s):  
Silver Nanoparticles ◽  
Raman Scattering ◽  
Active Sites ◽  
Density Functional ◽  
Surface Enhanced Raman Scattering ◽  
Sers Spectrum ◽  
Functional Theory ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

A Surface-Enhanced Raman Scattering (SERS) spectrum of 4-cyanopyridine (4CNPy) was recorded on silver plasmonic nanoparticles and analyzed by using Density Functional Theory (DFT) calculations. Two simple molecular models of the metal–4CNPy surface complex with a single silver cation or with a neutral dimer (Ag+–4CNPy, Ag2–4CNPy), linked through the two possible interacting sites of 4CNPy (aromatic nitrogen, N, and nitrile group, CN), were considered. The calculated vibrational wavenumbers and intensities of the adsorbate and the isolated species are compared with the experimental Raman and SERS results. The analysis of the DFT predictions and the experimental data indicates that 4CNPy adsorbs preferentially on neutral/charged active sites of the silver nanoparticles through the nitrogen atom of the aromatic ring with a perpendicular orientation.

Small cavities as major active sites for surface enhanced raman scattering

1985 ◽  
Vol 158 (1-3) ◽  
pp. A421
Author(s):  
H. Seki ◽  
T.J. Chuang ◽  
J.F. Escobar ◽  
H. Morawitz ◽  
E.V. Albano
Keyword(s):  
Raman Scattering ◽  
Active Sites ◽  
Surface Enhanced Raman Scattering ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering
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