Thermodynamic Properties of Dilute NaCl(aq) Solutions near the Critical Point of Water

2004 ◽  
Vol 108 (31) ◽  
pp. 11838-11849 ◽  
Author(s):  
Josef Sedlbauer ◽  
Robert H. Wood
Keyword(s):  
Thermodynamic Properties ◽  
Critical Point

A Rational Equation of State for Water and Water Vapor in the Critical Region

1964 ◽  
Vol 86 (3) ◽  
pp. 320-326 ◽  
Author(s):  
E. S. Nowak
Keyword(s):  
Water Vapor ◽  
Equation Of State ◽  
Thermodynamic Properties ◽  
Specific Heat ◽  
Critical Point ◽  
Critical Region ◽  
Constant Pressure ◽  
Parametric Equation ◽  
Enthalpy And Entropy ◽  
Specific Volumes

A parametric equation of state was derived for water and water vapor in the critical region from experimental P-V-T data. It is valid in that part of the critical region encompassed by pressures from 3000 to 4000 psia, specific volumes from 0.0400 to 0.1100 ft3/lb, and temperatures from 698 to 752 deg F. The equation of state satisfies all of the known conditions at the critical point. It also satisfies the conditions along certain of the boundaries which probably separate “supercritical liquid” from “supercritical vapor.” The equation of state, though quite simple in form, is probably superior to any equation heretofore derived for water and water vapor in the critical region. Specifically, the deviations between the measured and computed values of pressure in the large majority of the cases were within three parts in one thousand. This coincides approximately with the overall uncertainty in P-V-T measurements. In view of these factors, the author recommends that the equation be used to derive values for such thermodynamic properties as specific heat at constant pressure, enthalpy, and entropy in the critical region.

Numerical Performance and Flow Field Study of Centrifugal Compressor With Supercritical Carbon-Dioxide (SCO2)

2019 ◽  
Author(s):  
Hemant Kumar ◽  
Chetan S. Mistry
Keyword(s):  
Carbon Dioxide ◽  
Thermodynamic Properties ◽  
Critical Point ◽  
Mass Flow Rate ◽  
Mass Flow ◽  
Flow Rate ◽  
Centrifugal Compressor ◽  
Numerical Study ◽  
Pressure Ratio ◽  
Compressor Inlet

Abstract The Supercritical carbon-dioxide Brayton cycle main attraction is due to the Supercritical characteristic of the working fluid, carbon-dioxide (SCO2). Some of the advantages of using SCO2 are relatively low turbine inlet temperature, the compression work will be low, and the system will be compact due to the variation of thermodynamic properties (like density, and specific heat ratio) of SCO2 near the critical point. SCO2 behave more like liquid when its state is near the critical point (Total Pressure = 7.39 MPa, Total Temperature = 305 K), operating compressor inlet near critical point can minimize compression work. For present study the centrifugal compressor was designed to operate at 75,000 rpm with pressure ratio (P.R) = 1.8 and mass flow rate = 3.53 kg/s as available from Sandai report. Meanline design for centrifugal compressor with SCO2 properties was done. The blade geometry was developed using commercial CAD Ansys Bladegen. The flow domain was meshed using Ansys TurboGrid. ANSYS CFX was used as a solver for present numerical study. The thermodynamic properties of SCO2 were imported from the ANSYS flow material library using SCO2.RPG [NIST thermal physics properties of fluid system]. In order to ensure the change in flow physics the mesh independence study was also conducted. The present paper discuss about the performance and flow field study targeting different mass flow rates as exit boundary condition. The comparison of overall performance (Pressure Ratio, the Blade loading, Stage efficiency and Density variation) was done with three different mass flow rates. The designed and simulated centrifugal compressor meets the designed pressure rise requirement. The variation of mass flow rate on performance of centrifugal compressor was tend to be similar to conventional centrifugal compressor. The paper discusses about the effect of variation in density, specific heat ratio and pressure of SCO2 with different mass flow outlet condition. The performance map of numerical study were validated with experiment results and found in good agreement with experimental results. The change in flow properties within the rotor flow passage are found to be interesting and very informative for future such centrifugal compressor design for special application of SCO2 Brayton cycle. 80% mass flow rate has given better results in terms of aerodynamic performance. Abrupt change in thermodynamic properties was observed near impeller inlet region. Strong density variations are observed at compressor inlet.

Classical harmonic model for the behavior of pure fluids at the critical point

2019 ◽  
Vol 21 (15) ◽  
pp. 8004-8014 ◽  
Author(s):  
Elizabeth A. Ploetz ◽  
Paul E. Smith
Keyword(s):  
Simple Model ◽  
Thermodynamic Properties ◽  
Critical Point ◽  
Harmonic Model ◽  
Limiting Behavior ◽  
Pure Fluids ◽  
Classical Fluids

We present a simple model to explain the limiting behavior of many thermodynamic properties of pure classical fluids as one approaches the critical point.

Transport and thermodynamic properties ofSr3Ru2O7near the quantum critical point

2004 ◽  
Vol 69 (14) ◽  
Author(s):  
Z. X. Zhou ◽  
S. McCall ◽  
C. S. Alexander ◽  
J. E. Crow ◽  
P. Schlottmann ◽  
...  
Keyword(s):  
Thermodynamic Properties ◽  
Critical Point ◽  
Quantum Critical Point ◽  
Quantum Critical

scholarly journals Low-temperature thermodynamic properties near the field-induced quantum critical point in NiCl2-4SC(NH2)2

2012 ◽  
Vol 85 (18) ◽  
Author(s):  
Franziska Weickert ◽  
Robert Küchler ◽  
Alexander Steppke ◽  
Luis Pedrero ◽  
Michael Nicklas ◽  
...  
Keyword(s):  
Low Temperature ◽  
Thermodynamic Properties ◽  
Critical Point ◽  
Quantum Critical Point ◽  
Quantum Critical

Impact of Impurities in CO2-Fluids on CO2 Transport Process

2006 ◽  
Author(s):  
H. Li ◽  
J. Yan
Keyword(s):  
Thermodynamic Properties ◽  
Critical Point ◽  
Transport Process ◽  
Liquid Equilibrium ◽  
Vapor Liquid Equilibrium ◽  
Motor Carriers ◽  
Co2 Transport ◽  
Process Studies ◽  
The Common ◽  
The Impact

There are four possible transportation means that could be used to deliver CO2: motor carriers, railway carriers, water carriers, and pipeline. The impurities in CO2-fluids have significant impacts on the thermodynamic properties that will further affect the design, operation and cost of CO2 transport. This paper focuses on how impurities in CO2-fluids affect thermodynamic properties, and how the changes of properties affect CO2 transport process. Vapor-liquid equilibrium (VLE), critical point and densities are essential thermodynamic properties for designing a CO2 transport process. Studies on these properties will be carried out for CO2-mixtures based on the combinations of the common impurities such as SO2, H2S, CH4, Ar, O2 and N2. Moreover with a real case of pipeline for CO2 transport, the impact of impurities on transport process will be demonstrated in more details.

scholarly journals The Joule-Thomson Effect for Refrigerants with Dopants of the Fullerenes and Carbon Nanotubes

2018 ◽  
Vol 54 (4) ◽  
pp. 38-44
Author(s):  
М. Petrenko ◽  
S. Artemenko ◽  
D. Nikitin
Keyword(s):  
Carbon Dioxide ◽  
Carbon Nanotubes ◽  
Thermodynamic Properties ◽  
Phase Equilibria ◽  
Critical Point ◽  
Reduced Form ◽  
Thomson Effect ◽  
Nanoparticle Concentration ◽  
Classical Fluids ◽  
Working Media

The importance of thermodynamic and phase behavior of working fluids embedded with nanostructured materials is fundamental to new nanotechnology applications. The fullerenes (C60) and carbon nanotubes (CNT) adding to refrigerants change their thermodynamic properties the Joule – Thomson effect such as dislocation of critical point, gas – liquid equilibria shift at alias. Algorithm of refrigerant thermodynamic property calculations based on the NIST (National Institute of Standards and Technologies) equation of state at different carbon nanotube concentrations is proposed. Thermodynamic properties of carbon dioxide in the C60 and CNT presence are given.  Considering the extremely large number of different both nanoparticle types and reference fluids, it is obvious that there is need for developing theoretically sound methods of the prompt estimation thermodynamic properties and phase equilibria for emerging working media. The effect of nanoparticles on the critical point shift for classical fluids doped by nanoparticles is examined. The regular and singular parts of thermodynamic surface of reference fluid and nanofluid (volume nanoparticle concentration < 5%) are suggested to coincide in the reduced form. The shift of critical point for nanoliquids of industrial interest is theoretically predicted. Results of calculations of phase equilibria for some nanofluids are described.

Thermodynamic Scaling Near the Critical Point

2005 ◽  
Author(s):  
Eldred H. Chimowitz
Keyword(s):  
Thermal Conductivity ◽  
Thermodynamic Properties ◽  
Critical Point ◽  
Critical Phenomena ◽  
Isothermal Compressibility ◽  
Scaling Laws ◽  
Anomalous Behavior ◽  
Published Data ◽  
Limiting Behavior ◽  
Type Of Behavior

Thermodynamic scaling near the critical point is a signature of critical phenomena, and many useful applications of supercritical solvent fluids depend upon exploiting this behavior in some technologically interesting way. Near the critical point, many transport and thermodynamic properties show anomalous behavior which is usually linked to the divergence of certain thermodynamic properties, such as the fluid’s isothermal compressibility. In figures 3.1 and 3.2 we depict the near-critical behavior of both the density of xenon and the thermal conductivity of carbon dioxide, respectively, adapted from published data [1, 2]. The onset of what appear to be critical singularities in these properties is clearly evident in both instances. In this chapter, we focus upon the thermodynamic basis for this type of behavior. In the theory of critical phenomena, the limiting behavior of certain thermodynamic properties near the critical point assumes special significance. In particular, properties that diverge at the critical point are of interest, and this divergence is usually described in terms of scaling laws.

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