Rate Constants for D + C2H2→ C2HD + H at High Temperature:  Implications to the High Pressure Rate Constant for H + C2H2→ C2H3†

2003 ◽  
Vol 107 (49) ◽  
pp. 10533-10543 ◽  
Author(s):  
J. V. Michael ◽  
M.-C. Su ◽  
J. W. Sutherland ◽  
L. B. Harding ◽  
A. F. Wagner
Keyword(s):  
High Pressure ◽  
High Temperature ◽  
Rate Constant ◽  
Rate Constants

scholarly journals Rate constants for D+C2H4→C2H3D+H at high temperature: implications to the high pressure rate constant for H+C2H4→C2H5

2005 ◽  
Vol 30 (1) ◽  
pp. 965-973 ◽  
Author(s):  
J.V. Michael ◽  
M.-C. Su ◽  
J.W. Sutherland ◽  
L.B. Harding ◽  
A.F. Wagner
Keyword(s):  
High Pressure ◽  
High Temperature ◽  
Rate Constant ◽  
Rate Constants

The Rate-Constant for the Recombination of Methyl Radicals

1986 ◽  
Vol 39 (8) ◽  
pp. 1257 ◽  
Author(s):  
NL Arthur ◽  
JC Biordi
Keyword(s):  
Experimental Data ◽  
High Pressure ◽  
Rate Constant ◽  
Rate Constants ◽  
The Other ◽  
Methyl Radicals ◽  
Experimental Conditions ◽  
Temperature Range ◽  
Best Value ◽  
Limiting Value

Rate constants for the recombination of CH3 radicals have been measured by means of the rotating sector technique in the temperature range 373- 463 K, and at a pressure of 30 Torr . CH3 radicals were produced by the photolysis of acetone, and the experimental data were fitted to sector curves generated from Shepp's theory. The results give kb = (2.81�0.22)×1013 cm3 mol-1 s-1, which, under the chosen experimental conditions, is close to its high-pressure limiting value. A comparison is made with the other values of the rate constant reported in the literature, and a best value is suggested.

scholarly journals Anharmonic effect of the rate constant of the reactions of CH3SCH2OO system in high-temperature combustion

2017 ◽  
Vol 95 (10) ◽  
pp. 1064-1072 ◽  
Author(s):  
Yu Hao ◽  
Xinxiang Pan ◽  
Liguo Song ◽  
Yang Ding ◽  
Wenwen Xia ◽  
...  
Keyword(s):  
High Temperature ◽  
Total Energy ◽  
Rate Constant ◽  
Rate Constants ◽  
Transition States ◽  
Main Reaction ◽  
Anharmonic Effect ◽  
Barrier Heights ◽  
Temperature Combustion ◽  
High Temperature Combustion

The study mainly focuses on the anharmonic effect of the reactions of CH3SCH2OO system. The geometries of the reactants and the transition states are optimized with Gaussian 09. The barrier heights are calculated with the energy of the reactants and the transition states. The RRKM theory is utilized to calculate the anharmonic and harmonic rate constants of the reactions. The anharmonic effect of these reactions can be clearly demonstrated by our results. Generally speaking, in the study, for most reactions, the rate constants increase with the temperature in the canonical case and the total energy in the microcanonical case, and the anharmonic effect of these reactions is significant and should not be neglected in high-temperature combustion. In CH3SCH2OO system, CH3SCH2OO → CH2SCH2OOH → CH2S + CH2O + OH is the main reaction channel. After a series of calculations, the anharmonic effect is remarkable, especially in high-temperature combustion. By analyzing other meaningful reactions that followed that channel above, the anharmonic effect of these reactions is generally obvious enough, especially for those reactions whose barrier heights are relatively low.

Microstructural Study of Diamond Deformed Under High Pressure and Temperature

1985 ◽  
Vol 43 ◽  
pp. 230-231
Author(s):  
E. F. Koch
Keyword(s):  
High Pressure ◽  
High Temperature ◽  
Lattice Structure ◽  
Diamond Particle ◽  
Polycrystalline Diamond ◽  
Sintering Process ◽  
Ion Milling ◽  
Sintered Compact ◽  
Transmission Electron ◽  
High Pressure Sintering

Because of the extremely rigid lattice structure of diamond, generating new dislocations or moving existing dislocations in diamond by applying mechanical stress at ambient temperature is very difficult. Analysis of portions of diamonds deformed under bending stress at elevated temperature has shown that diamond deforms plastically under suitable conditions and that its primary slip systems are on the ﹛111﹜ planes. Plastic deformation in diamond is more commonly observed during the high temperature - high pressure sintering process used to make diamond compacts. The pressure and temperature conditions in the sintering presses are sufficiently high that many diamond grains in the sintered compact show deformed microtructures.In this report commercially available polycrystalline diamond discs for rock cutting applications were analyzed to study the deformation substructures in the diamond grains using transmission electron microscopy. An individual diamond particle can be plastically deformed in a high pressure apparatus at high temperature, but it is nearly impossible to prepare such a particle for TEM observation, since any medium in which the diamond is mounted wears away faster than the diamond during ion milling and the diamond is lost.

YSS YXM4

Alloy Digest ◽  
2019 ◽  
Vol 68 (11) ◽  
Keyword(s):  
High Pressure ◽  
High Temperature ◽  
Physical Properties ◽  
Tool Steel ◽  
High Speed ◽  
Temperature Performance

Abstract YSS YXM4 is a cobalt-alloyed molybdenum high-speed tool steel with resistance to abrasion, seizure, and deformation under high pressure. This datasheet provides information on composition, physical properties, and hardness. It also includes information on high temperature performance. Filing Code: TS-780. Producer or source: Hitachi Metals America, Ltd.

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