Calorimetric Features of High-Enthalpy Amorphous Solids and Glass-Softening Temperature of Water

2003 ◽  
Vol 107 (34) ◽  
pp. 9063-9070 ◽  
Author(s):  
G. P. Johari
2013 ◽  
Vol 573 ◽  
pp. 31-35
Author(s):  
His Wen Yang ◽  
Jin Ming Zhu ◽  
Yu Xiang Tsai ◽  
Chun Hsiung Lin ◽  
Cheng Hsing Hsu ◽  
...  

The physical and optical properties of P2O5-Al2O3-ZnO glasses doped with different concentration of Yb3+ions were investigated. The experimental results indicated that density, chemical durability, glass transition temperature (Tg) and glass softening temperature (Td) of glasses increase with increasing the Yb2O3content of glasses. However, the coefficient of thermal expansion (α) for glasses decrease with increasing the Yb2O3content. From the results of Fourier transform infrared spectroscopy, the numbers of (-P-O-P-) bonds decrease and (-P-O-M+-) bonds increase with increasing the Yb2O3content. Increase of non-bridge oxygen (-P-O-M+-) raise the refractive index of glasses. Moreover, the results of absorption spectra indicate that the absorption peak of glasses are observed at both wavelengths of 916nm and 977nm. As increasing the concentration of Yb2O3, the absorption efficiencies become stronger. In accordance with the results of fluorescence spectra, the fluorescence emission of glasses are detected at wavelengths of 970nm, 995nm, 1020nm and 1048nm, respectively. The intensity of the fluorescence emission peaks significantly decrease at wavelengths of 970nm and 995nm as the concentration of Yb2O3increases. However, the intensity of the fluorescence emission peaks significantly increase at wavelength of 1048nm under the same condition.


2008 ◽  
Vol 281 (10) ◽  
pp. 2933-2937 ◽  
Author(s):  
B. Karthikeyan ◽  
M. Anija ◽  
C.S. Suchand Sandeep ◽  
T.M. Muhammad Nadeer ◽  
Reji Philip

2010 ◽  
Vol 156-157 ◽  
pp. 1559-1563
Author(s):  
Xiao Qing Liu ◽  
Jun Lin Xie

To optimize production technology of oxy-fuel float glass, a series of float glass with lower sulphate contents and 1%~5% carbon contents in glass batch were prepared under simulated oxy-fuel melting conditions. Infrared spectroscopy,thermal dilatometer and microscope were used to study water content and its state in glass melts, the change of coefficient of thermal expansion of glass, the glass softening temperature and transition temperature, and the number of bubbles in glass, respectively. The results show that the change of carbon content will slightly changes the water content, thermo properties of glass and the number of bubbles in glass. With the increase of carbon content, the coefficient of thermal expansion and the water content of glass generally decrease, while the number of bubbles, the softening temperature and the glass transition temperature increase. When the content of sulphate is 2%, the glass with 2% carbon content has the biggest water content and the best fining effect.


2000 ◽  
Vol 278 (1-3) ◽  
pp. 58-68 ◽  
Author(s):  
G.P. Johari ◽  
M. Beiner ◽  
C. Macdonald ◽  
J. Wang

1992 ◽  
Vol 89 ◽  
pp. 2073-2089 ◽  
Author(s):  
GP Johari
Keyword(s):  

1991 ◽  
Vol 01 (C7) ◽  
pp. C7-439-C7-442 ◽  
Author(s):  
N. V. GRUZDEV ◽  
E. G. SIL'KIS ◽  
V. D. TITOV ◽  
Yu. G. VAINER

1981 ◽  
Vol 42 (C6) ◽  
pp. C6-125-C6-127
Author(s):  
R. Vacher ◽  
J. Pelous
Keyword(s):  

1985 ◽  
Vol 46 (C8) ◽  
pp. C8-281-C8-286 ◽  
Author(s):  
C. Tête ◽  
D. Boumazouza ◽  
G. Marchal ◽  
Ph. Mangin ◽  
J. Bouillot ◽  
...  

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