Methyl Radical Addition to CS Double Bonds:  Kinetic versus Thermodynamic Preferences

Michelle L. Coote; Geoffrey P. F. Wood; Leo Radom

doi:10.1021/jp0267656

Methyl Radical Addition to CS Double Bonds: Kinetic versus Thermodynamic Preferences

The Journal of Physical Chemistry A ◽

10.1021/jp0267656 ◽

2002 ◽

Vol 106 (50) ◽

pp. 12124-12138 ◽

Cited By ~ 40

Author(s):

Michelle L. Coote ◽

Geoffrey P. F. Wood ◽

Leo Radom

Keyword(s):

Radical Addition ◽

Double Bonds ◽

Methyl Radical

Download Full-text

Comparison of the Kinetics and Thermodynamics for Methyl Radical Addition to CC, CO, and CS Double Bonds

Journal of the American Chemical Society ◽

10.1021/ja039139a ◽

2004 ◽

Vol 126 (6) ◽

pp. 1732-1740 ◽

Cited By ~ 39

Author(s):

David J. Henry ◽

Michelle L. Coote ◽

Rodolfo Gómez-Balderas ◽

Leo Radom

Keyword(s):

Radical Addition ◽

Double Bonds ◽

Methyl Radical ◽

Kinetics And Thermodynamics

Download Full-text

Free Radical Addition of Butanethiol to Vegetable Oil Double Bonds

Journal of Agricultural and Food Chemistry ◽

10.1021/jf802774g ◽

2009 ◽

Vol 57 (4) ◽

pp. 1282-1290 ◽

Cited By ~ 83

Author(s):

Grigor B. Bantchev ◽

James A. Kenar ◽

Girma Biresaw ◽

Moon Gyu Han

Keyword(s):

Free Radical ◽

Vegetable Oil ◽

Radical Addition ◽

Double Bonds ◽

Free Radical Addition

Download Full-text

A Theoretical Study of Chlorine Atom and Methyl Radical Addition to Nitrogen Bases: Why Do Cl Atoms Form Two-Center−Three-Electron Bonds Whereas CH3Radicals Form Two-Center−Two-Electron Bonds?

Journal of the American Chemical Society ◽

10.1021/ja9613973 ◽

1996 ◽

Vol 118 (43) ◽

pp. 10571-10576 ◽

Cited By ~ 29

Author(s):

Michael L. McKee ◽

Athanassios Nicolaides ◽

Leo Radom

Keyword(s):

Chlorine Atom ◽

Theoretical Study ◽

Radical Addition ◽

Methyl Radical ◽

Nitrogen Bases ◽

Cl Atoms

Download Full-text

The Competition Kinetics of Unbranched Chain Processes of Free-Radical Addition to Double Bonds of Molecules with the Formation of 1:1 Adducts

International Journal of Polymeric Materials ◽

10.1080/00914030008033886 ◽

2000 ◽

Vol 46 (3-4) ◽

pp. 435-449

Author(s):

Michael M. Silaev

Keyword(s):

Free Radical ◽

Radical Addition ◽

Double Bonds ◽

Chain Processes ◽

Kinetics Of ◽

Free Radical Addition

Download Full-text

Calculations on the Kinetics, Thermodynamics, and Selectivity of Methyl Radical Addition to Olefins Coordinated to d8and d0Transition-Metal Fragments: Two Distinct and Opposite anti-Evans−Polanyi Effects with Potential Practical Implications

Organometallics ◽

10.1021/om8007212 ◽

2008 ◽

Vol 27 (21) ◽

pp. 5426-5429 ◽

Cited By ~ 8

Author(s):

Faraj Hasanayn ◽

Samer Gozem

Keyword(s):

Radical Addition ◽

Methyl Radical ◽

Practical Implications

Download Full-text

Synthesis of β,β-Dichloro-α,β-unsaturated Ketones by Trichloro-methyl Radical Addition/Elimination of Enol Silyl Ethers

Chinese Journal of Organic Chemistry ◽

10.6023/cjoc201911023 ◽

2020 ◽

Vol 40 (6) ◽

pp. 1625

Author(s):

Haochen Ge ◽

Keying Du ◽

Weijian Sheng

Keyword(s):

Radical Addition ◽

Methyl Radical ◽

Silyl Ethers ◽

Unsaturated Ketones ◽

Enol Silyl Ethers

Download Full-text

Methyl radical addition to nitroalkane aci-anions in aqueous solution: rate constants and optical absorption spectra

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/p29820001143 ◽

1982 ◽

pp. 1143 ◽

Cited By ~ 6

Author(s):

Dieter Veltwisch ◽

Klaus-Dieter Asmus

Keyword(s):

Aqueous Solution ◽

Optical Absorption ◽

Absorption Spectra ◽

Rate Constants ◽

Radical Addition ◽

Solution Rate ◽

Optical Absorption Spectra ◽

Methyl Radical

Download Full-text

AM1 studies on methyl radical additions to C=N and N=N double bonds in aza and azo compounds

Reaction Kinetics and Catalysis Letters ◽

10.1007/bf02076042 ◽

1995 ◽

Vol 56 (2) ◽

pp. 371-376

Author(s):

T. Kőrtvélyesi ◽

L. Seres

Keyword(s):

Azo Compounds ◽

Double Bonds ◽

Methyl Radical

Download Full-text

ChemInform Abstract: Prediction of Methyl Radical Addition Rate Constants from Molecular Structure.

ChemInform ◽

10.1002/chin.199931283 ◽

2010 ◽

Vol 30 (31) ◽

pp. no-no

Author(s):

Gregory A. Bakken ◽

Peter C. Jurs

Keyword(s):

Molecular Structure ◽

Rate Constants ◽

Radical Addition ◽

Methyl Radical ◽

Addition Rate ◽

Addition Rate Constants

Download Full-text

Regioselectivity of methyl radical addition to fluoroethenes: a quantum mechanical study

Chemical Physics Letters ◽

10.1016/s0009-2614(98)00797-0 ◽

1998 ◽

Vol 293 (3-4) ◽

pp. 295-301 ◽

Cited By ~ 7

Author(s):

Roger Arnaud ◽

Valentina Vetere ◽

Vincenzo Barone

Keyword(s):

Radical Addition ◽

Quantum Mechanical ◽

Methyl Radical ◽

Mechanical Study ◽

Quantum Mechanical Study

Download Full-text