Geometries and Electronic Structures of Group 10 and 11 Metal Carbonyl Cations, [M(CO)n]x+(Mx+= Ni2+, Pd2+, Pt2+, Cu+, Ag+, Au+;n= 1−4)

2003 ◽  
Vol 107 (19) ◽  
pp. 3812-3821 ◽  
Author(s):  
Koichi Mogi ◽  
Yoshiko Sakai ◽  
Takaaki Sonoda ◽  
Qiang Xu ◽  
Yoshie Souma
Keyword(s):  
Electronic Structures ◽  
Metal Carbonyl ◽  
Group 10

Syntheses and Electronic Structures of One-Electron-Oxidized Group 10 Metal(II)−(Disalicylidene)diamine Complexes (Metal = Ni, Pd, Pt)

2007 ◽  
Vol 129 (9) ◽  
pp. 2559-2568 ◽  
Author(s):  
Yuichi Shimazaki ◽  
Tatsuo Yajima ◽  
Fumito Tani ◽  
Satoru Karasawa ◽  
Koichi Fukui ◽  
...  
Keyword(s):  
Electronic Structures ◽  
Group 10

The Nature of Oxide Surfaces: Topographic and Electronic Structure

1993 ◽  
Vol 51 ◽  
pp. 966-967
Author(s):  
Dawn A. Bonnell ◽  
Yong Liang
Keyword(s):  
Transition Metal Oxides ◽  
Electronic Structures ◽  
Recent Progress ◽  
Spatial Localization ◽  
Level Of Detail ◽  
Scanning Tunneling ◽  
Oxide Surfaces ◽  
Tunneling Microscopy ◽  
Considerable Effort ◽  
Complete Understanding

Recent progress in the application of scanning tunneling microscopy (STM) and tunneling spectroscopy (STS) to oxide surfaces has allowed issues of image formation mechanism and spatial resolution limitations to be addressed. As the STM analyses of oxide surfaces continues, it is becoming clear that the geometric and electronic structures of these surfaces are intrinsically complex. Since STM requires conductivity, the oxides in question are transition metal oxides that accommodate aliovalent dopants or nonstoichiometry to produce mobile carriers. To date, considerable effort has been directed toward probing the structures and reactivities of ZnO polar and nonpolar surfaces, TiO2 (110) and (001) surfaces and the SrTiO3 (001) surface, with a view towards integrating these results with the vast amount of previous surface analysis (LEED and photoemission) to build a more complete understanding of these surfaces. However, the spatial localization of the STM/STS provides a level of detail that leads to conclusions somewhat different from those made earlier.

MULTIPLE SCATTERING EFFECTS IN THE COBALT K-EDGE EXAFS OF METAL CARBONYL COMPLEXES

1986 ◽  
Vol 47 (C8) ◽  
pp. C8-589-C8-592
Author(s):  
N. BINSTED ◽  
S. L. COOK ◽  
J. EVANS ◽  
R. J. PRICE ◽  
G. N. GREAVES
Keyword(s):  
Multiple Scattering ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes ◽  
Scattering Effects ◽  
Multiple Scattering Effects

Carbon Chain Growth by Sequential Reactions of CO and CO2 with a Transition Metal Carbonyl Complex

2018 ◽  
Author(s):  
Richard Kong ◽  
Mark Crimmin
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl ◽  
Carbon Chain ◽  
Chain Growth ◽  
Carbonyl Complex ◽  
Fischer Tropsch ◽  
Carbon Chains ◽  
Sequential Coupling ◽  
Energy Economy ◽  
Sequential Reactions

<i>The formation of carbon chains by the coupling of COx (X = 1 or 2) units on transition metals is a fundamental step relevant to Fischer-Tropsch catalysis. Fischer-Tropsch catalysis produces energy dense liquid hydrocarbons from synthesis gas (CO and H2) and has been a mainstay of the energy economy since its discovery nearly a century ago. Despite detailed studies aimed at elucidating the steps of catalysis, experimental evidence for chain growth (Cn to Cn+1 ; n > 2) from the reaction of CO with metal complexes is unprecedented. In this paper, we show that carbon chains can be grown from sequential reactions of CO or CO2 with a transition metal carbonyl complex. By exploiting the cooperative effect of transition and main group metals, we document the first example of chain propagation from sequential coupling of CO units (C1 to C3 to C4), along with the first example of incorporation of CO2 into the growing carbon chain.</i><br>

Influence of shift work on the formation of diseases of the digestive system

2020 ◽  
pp. 802-802
Author(s):  
E. F. Chernikova ◽  
M. M. Nekrasova ◽  
I. A. Potapova
Keyword(s):  
Shift Work ◽  
Police Officers ◽  
Digestive System ◽  
Traffic Police ◽  
Group 10

The analysis of the influence of the duration of shift work on the incidence of diseases of the digestive system (DDS) was carried out using the example of a group of traffic police officers. A significant increase in the incidence of DDS in the probation group 10 years or more compared to the group of up to 5 years indicates a high occupational conditionality of diseases of the digestive system.

Advanced Electronic Structures

1992 ◽  
Author(s):  
Mark van Schilfgaarde
Keyword(s):  
Electronic Structures
Sign in / Sign up

Export Citation Format

Share Document