A Kinetic and Mechanistic Study of the Cl/F Exchange Reaction of CCl3F, CCl2F2, and CClF3with Prefluorided Chromia

2002 ◽  
Vol 106 (37) ◽  
pp. 9567-9575 ◽  
Author(s):  
A. Farrokhnia ◽  
B. Sakakini ◽  
K. C. Waugh
Keyword(s):  
Exchange Reaction ◽  
Mechanistic Study

Mechanistic Study on Aryl-Exchange Reaction of Diaryl-λ3-iodane with Aryl Iodide

2017 ◽  
Vol 83 (1) ◽  
pp. 289-295 ◽  
Author(s):  
Yui Masumoto ◽  
Kazunori Miyamoto ◽  
Takuto Iuchi ◽  
Masahito Ochiai ◽  
Keiichi Hirano ◽  
...  
Keyword(s):  
Exchange Reaction ◽  
Mechanistic Study ◽  
Aryl Iodide

H/D Exchange Reaction between Isobutane and Acidic USY Zeolite: A Mechanistic Study by Mass Spectrometry and in Situ NMR

2001 ◽  
Vol 204 (2) ◽  
pp. 460-465 ◽  
Author(s):  
Weiming Hua ◽  
Alain Sassi ◽  
Alain Goeppert ◽  
Francis Taulelle ◽  
Chantal Lorentz ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Exchange Reaction ◽  
Mechanistic Study ◽  
Zeolite A ◽  
Usy Zeolite ◽  
In Situ Nmr

scholarly journals Ligand Exchange Reaction on a Ru(II)–Pheox Complex as a Mechanistic Study of Catalytic Reactions

ACS Omega ◽  
2018 ◽  
Vol 3 (9) ◽  
pp. 11286-11289 ◽  
Author(s):  
Yoko Nakagawa ◽  
Yusuke Imokawa ◽  
Ikuhide Fujisawa ◽  
Naofumi Nakayama ◽  
Hitoshi Goto ◽  
...  
Keyword(s):  
Exchange Reaction ◽  
Ligand Exchange ◽  
Catalytic Reactions ◽  
Mechanistic Study ◽  
Ligand Exchange Reaction

Mechanistic Study of a Place-Exchange Reaction of Au Nanoparticles with Spin-Labeled Disulfides

Langmuir ◽  
2004 ◽  
Vol 20 (26) ◽  
pp. 11536-11544 ◽  
Author(s):  
Petre Ionita ◽  
Agneta Caragheorgheopol ◽  
Bruce C. Gilbert ◽  
Victor Chechik
Keyword(s):  
Exchange Reaction ◽  
Au Nanoparticles ◽  
Mechanistic Study ◽  
Place Exchange

Pyridyl disulfide-based thiol–disulfide exchange reaction: shaping the design of redox-responsive polymeric materials

2020 ◽  
Vol 11 (48) ◽  
pp. 7603-7624
Author(s):  
Ismail Altinbasak ◽  
Mehmet Arslan ◽  
Rana Sanyal ◽  
Amitav Sanyal
Keyword(s):  
Exchange Reaction ◽  
Functional Materials ◽  
Polymeric Materials ◽  
Disulfide Exchange ◽  
Redox Responsive ◽  
Synthetic Approaches

This review provides an overview of synthetic approaches utilized to incorporate the thiol-reactive pyridyl-disulfide motif into various polymeric materials, and briefly highlights its utilization to obtain functional materials.

Mechanistic study of proliferation induced by Angelica sinensis in gastric epithelial cells

2001 ◽  
Vol 120 (5) ◽  
pp. A145-A145
Author(s):  
C CHO ◽  
Y YE ◽  
E LIU ◽  
V SHIN ◽  
N SHAM
Keyword(s):  
Epithelial Cells ◽  
Mechanistic Study ◽  
Angelica Sinensis ◽  
Gastric Epithelial Cells

Mechanistic study on the cardioprotective and chemosensitizing effects of a novel danshensu derivative

Planta Medica ◽  
2014 ◽  
Vol 80 (16) ◽  
Author(s):  
L Wang ◽  
L Shan ◽  
G Cui ◽  
Y Chen ◽  
J li ◽  
...  
Keyword(s):  
Mechanistic Study

Mechanistic Study and Development of Catalytic Reactions of Sm(II)

2018 ◽  
Author(s):  
Sandepan Maity ◽  
Robert Flowers
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Proton Donor ◽  
Catalytic Reactions ◽  
Mechanistic Study ◽  
Mechanistic Studies ◽  
Cyclization Reactions ◽  
Mechanistic Approach ◽  
Donor Source

Despite the broad utility and application of SmI<sub>2</sub>in synthesis, the reagent is used in stoichiometric amounts and has a high molecular weight, resulting in a large amount of material being used for reactions requiring one or more equivalents of electrons. We report mechanistic studies on catalytic reactions of Sm(II) employing a terminal magnesium reductant and trimethyl silyl chloride in concert with a non-coordinating proton donor source. Reactions using this approach permitted reductions with as little as 1 mol% Sm. The mechanistic approach enabled catalysis employing HMPA as a ligand, facilitating the development of catalytic Sm(II) 5-<i>exo</i>-<i>trig </i>ketyl olefin cyclization reactions.

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