Two-Dimensional Correlation Infared Analysis (2D-IR) Based on Dynamic Infrared Spectroscopy Used as a Probe of the Viscoelastic Behavior of Side Chain Liquid Crystalline Polyurethanes

2002 ◽  
Vol 106 (43) ◽  
pp. 11108-11113 ◽  
Author(s):  
Vasilis G. Gregoriou ◽  
Sheila E. Rodman ◽  
Bindu R. Nair ◽  
Paula T. Hammond
1993 ◽  
Vol 47 (9) ◽  
pp. 1386-1389 ◽  
Author(s):  
Ray Hasegawa ◽  
Masanori Sakamoto ◽  
Hideyuki Sasaki

The dynamic behavior of a polymer-dispersed liquid crystal (PDLC) under an electric field has been studied by static and two-dimensional infrared spectroscopy. The PDLC sample was prepared by polymerization-induced phase separation of a mixture of nematic liquid crystal E7 and acrylate. 2D IR correlation analysis indicates that the rigid core of the liquid crystal molecules reorients as a unit, and suggests that the polymer side chain existing in the interface between the polymer and the liquid crystals may reorient in phase with the liquid crystal reorientation by interaction with the liquid crystal molecules.


2009 ◽  
Vol 113 (14) ◽  
pp. 4940-4946 ◽  
Author(s):  
Sri Ram G. Naraharisetty ◽  
Valeriy M. Kasyanenko ◽  
Jörg Zimmermann ◽  
Megan C. Thielges ◽  
Floyd E. Romesberg ◽  
...  

The Analyst ◽  
2015 ◽  
Vol 140 (13) ◽  
pp. 4336-4349 ◽  
Author(s):  
Amanda L. Le Sueur ◽  
Rachel E. Horness ◽  
Megan C. Thielges

The potential of 2D IR spectroscopy is illustrated through select examples of recent applications in chemistry and biology.


The Analyst ◽  
2020 ◽  
Vol 145 (6) ◽  
pp. 2014-2024
Author(s):  
Robby Fritzsch ◽  
Samantha Hume ◽  
Lucy Minnes ◽  
Matthew J. Baker ◽  
Glenn A. Burley ◽  
...  

Recent progress in laser technology and data analysis methods has enabled high throughput applications of ultrafast two-dimensional infrared (2D-IR) spectroscopy measurements and opened the door to analytical applications.


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