Hydrogen Bonding in Concentrated Aqueous Solutions of 1,2-Dimethoxyethane:  Formation of Water Clusters

2001 ◽  
Vol 105 (48) ◽  
pp. 10884-10889 ◽  
Author(s):  
Zhorro S. Nickolov ◽  
Nikolay Goutev ◽  
Hiroatsu Matsuura
Keyword(s):  
Hydrogen Bonding ◽  
Aqueous Solutions ◽  
Water Clusters ◽  
Concentrated Aqueous Solutions

Raman spectra of rnercury(II) nitrate in aqueous solution and as the crystalline hydrate

1969 ◽  
Vol 22 (2) ◽  
pp. 337 ◽  
Author(s):  
RPJ Cooney ◽  
JR Hall
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Bonding ◽  
Aqueous Solutions ◽  
Crystal Lattice ◽  
Raman Spectra ◽  
Raman Line ◽  
Covalent Bond ◽  
Crystalline Hydrate ◽  
Concentrated Aqueous Solutions ◽  
Mercury Nitrate

Raman spectra of mercury(II) nitrate in concentrated aqueous solutions (0.7-7.0M) indicate that the nitrate groups are present as associated ions or covalently bound groups. A gradual alteration in the appearance of the nitrate spectrum with increasing concentration is explained in terms of changes in the nature of mercury-nitrate interaction. A Raman line assignable to the stretching of a mercury-nitrate covalent bond has been observed at c. 270 cm-1. The spectrum of solid Hg(NO3)2,H2O differs from spectra of the aqueous solutions, mainly in the region 1300-1450 cm-1. Additional features are attributed to the influence of hydrogen bonding in the crystal lattice or to correlation field effects (anion-anion coupling).

The Structure of Hydroxylamine – Water Mixtures

1995 ◽  
Vol 50 (2-3) ◽  
pp. 263-273 ◽  
Author(s):  
Sergi Vizoso ◽  
Bernd M. Rode
Keyword(s):  
Monte Carlo ◽  
Hydrogen Bonding ◽  
Angular Distribution ◽  
Aqueous Solutions ◽  
Monte Carlo Simulations ◽  
Coordination Number ◽  
Water Clusters ◽  
Pure Water ◽  
Distribution Functions ◽  
Pair Energy

Abstract Monte Carlo simulations have been carried our for 5, 25, 50, and 75 weight% aqueous solutions of hydroxylamine. Changes in the microstructure of the solutions have been evaluated by means of radial and angular distribution functions, coordination number distributions and pair energy anal­ysis. The structure of liquid hydroxylamine is strongly altered by even small amounts of water, whereas water clusters similar to the pure water are maintained up to higher NH2OH concentra­tions. The structural entities in the mixtures are determined by hydrogen bonding and electrostatic arrangement of ligands.

Interaction of Gold Atom with Clusters of Water: Few Computational Mise-En-Scènes with Hydrogen Bonding Motif

2008 ◽  
Vol 73 (11) ◽  
pp. 1457-1474 ◽  
Author(s):  
Eugene S. Kryachko
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Computational Model ◽  
Photoelectron Spectroscopy ◽  
Water Clusters ◽  
Gold Atom ◽  
Proton Acceptor ◽  
Anion Photoelectron Spectroscopy ◽  
Relationship Of ◽  
First Time

The present work outlines the fair relationship of the computational model with the experiments on anion photoelectron spectroscopy for the gold-water complexes [Au(H2O)1≤n≤2]- that is established between the auride anion Au- and water monomer and dimer thanks to the nonconventional hydrogen bond where Au- casts as the nonconventional proton acceptor. This work also extends the computational model to the larger complexes [Au(H2O)3≤n≤5]- where gold considerably thwarts the shape of water clusters and even particularly breaks their conventional hydrogen bonding patterns. The fascinating phenomenon of the lavish proton acceptor character of Au- to form at least six hydrogen bonds with molecules of water is computationally unveiled in the present work for the first time.

Intramolecular Hydrogen Bonding Facilitates Electrocatalytic Reduction of Nitrite in Aqueous Solutions

2019 ◽  
Vol 58 (14) ◽  
pp. 9443-9451 ◽  
Author(s):  
Song Xu ◽  
Hyuk-Yong Kwon ◽  
Daniel C. Ashley ◽  
Chun-Hsing Chen ◽  
Elena Jakubikova ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Aqueous Solutions ◽  
Intramolecular Hydrogen Bonding ◽  
Electrocatalytic Reduction ◽  
Intramolecular Hydrogen
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