Excited-State Energy Transfer Processes in Phenylene- and Biphenylene-Linked and Directly-Linked Zinc(II) and Free-Base Hybrid Diporphyrins

2001 ◽  
Vol 105 (17) ◽  
pp. 4200-4210 ◽  
Author(s):  
Hyun Sun Cho ◽  
Dae Hong Jeong ◽  
Min-Chul Yoon ◽  
Yong Hee Kim ◽  
Yong-Rok Kim ◽  
...  
1983 ◽  
Author(s):  
J. R. Barthel ◽  
R. E. Duff ◽  
W. J. Proffer

1999 ◽  
Vol 38 (21) ◽  
pp. 4849-4853 ◽  
Author(s):  
Philippe Hascoat ◽  
Sung Ik Yang ◽  
Robin K. Lammi ◽  
Jennifer Alley ◽  
David F. Bocian ◽  
...  

2003 ◽  
Vol 42 (21) ◽  
pp. 6629-6647 ◽  
Author(s):  
Lianhe Yu ◽  
Kannan Muthukumaran ◽  
Igor V. Sazanovich ◽  
Christine Kirmaier ◽  
Eve Hindin ◽  
...  

2001 ◽  
Vol 05 (07) ◽  
pp. 600-607 ◽  
Author(s):  
ISABELLE M. DIXON ◽  
JEAN-PAUL COLLIN

Four diads consisting of a free-base or zinc aryl-porphyrin associated with two ruthenium(II) bis(terdentate) complexes (non-cyclometallated Ru ( N 6) or cylometallated Ru ( N 5 C )) have been synthesized. The strong electron-withdrawing properties of the Ru ( N 6) as compared to the Ru ( N 5 C ) complex have been illustrated by their electrochemical and spectroscopic properties. Emission spectra of the diads and the reference compounds have shown that very efficient fluorescence quenching occurs, probably by energy transfer processes from the porphyrin to the 3MLCT excited state of the ruthenium unit.


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