Field Dependence of Chemically Induced Dynamic Nuclear Polarization (CIDNP) in the Photoreaction ofN-Acetyl Histidine with 2,2‘-Dipyridyl in Aqueous Solution

2001 ◽  
Vol 105 (26) ◽  
pp. 6311-6319 ◽  
Author(s):  
Stefan Grosse ◽  
Alexandra V. Yurkovskaya ◽  
Jakob Lopez ◽  
Hans-Martin Vieth
Keyword(s):  
Aqueous Solution ◽  
Field Dependence ◽  
Dynamic Nuclear Polarization ◽  
Nuclear Polarization ◽  
Chemically Induced

Chemisch induzierte Kernpolarisation von Phenylhalogeniden bei der Photolyse von Aroylperoxiden

1969 ◽  
Vol 24 (11) ◽  
pp. 1771-1778 ◽  
Author(s):  
M. Lehnig ◽  
H. Fischer
Keyword(s):  
Magnetic Field ◽  
Field Dependence ◽  
Dynamic Nuclear Polarization ◽  
Nmr Spectra ◽  
Magnetic Field Dependence ◽  
Nuclear Polarization ◽  
Radical Reactions ◽  
Chemically Induced ◽  
Polarization Mechanism ◽  
The Magnetic Field

Abstract By a flow technique chemically induced nuclear polarization is observed in the NMR-spectra of phenylhalides formed during photolysis of aroylperoxides in solution. The main features of the polarization are quantitatively explained by dynamic nuclear polarization (CIDNP) of protons in the intermediate phenyl radicals. Some details however indicate that a second polarization mechanism is also present. This mechanism leads to a multiplet-effect type polarization and operates presumably during bond fromation in the radical reactions. Some results on the magnetic field dependence of the nuclear polarizations are given.

Photoinitiated oxidation of NADH catalyzed by horseradish peroxidase studied by chemically induced dynamic nuclear polarization

2006 ◽  
Vol 55 (7) ◽  
pp. 1132-1136 ◽  
Author(s):  
M. S. Afanasyeva ◽  
P. A. Purtov ◽  
M. B. Taraban ◽  
T. V. Leshina ◽  
C. B. Grissom
Keyword(s):  
Horseradish Peroxidase ◽  
Dynamic Nuclear Polarization ◽  
Nuclear Polarization ◽  
Chemically Induced
Sign in / Sign up

Export Citation Format

Share Document