Branching Ratio and Pressure Dependent Rate Constants of Multichannel Unimolecular Decomposition of Gas-Phase α-HMX:  An Ab Initio Dynamics Study†

2001 ◽  
Vol 105 (11) ◽  
pp. 2427-2434 ◽  
Author(s):  
Shaowen Zhang ◽  
Thanh N. Truong
Keyword(s):  
Ab Initio ◽  
Gas Phase ◽  
Rate Constants ◽  
Branching Ratio ◽  
Unimolecular Decomposition ◽  
Dependent Rate

scholarly journals Kinetics of the gas-phase reactions of OH radicals with alkanes and cycloalkanes

2003 ◽  
Vol 3 (6) ◽  
pp. 2233-2307 ◽  
Author(s):  
R. Atkinson
Keyword(s):  
Gas Phase ◽  
Rate Constants ◽  
Relative Rate ◽  
Oh Radicals ◽  
Gas Phase Reactions ◽  
Temperature Dependent ◽  
Temperature Range ◽  
Dependent Rate ◽  
Temperature Ranges ◽  
Kinetics Of

Abstract. The available database concerning rate constants for gas-phase reactions of the hydroxyl (OH) radical with alkanes through early 2003 is presented over the entire temperature range for which measurements have been made (~180-2000 K). Measurements made using relative rate methods are re-evaluated using recent rate data for the reference compound (generally recommendations from this review). In general, whenever more than one study has been carried out over an overlapping temperature range, recommended rate constants or temperature-dependent rate expressions are presented. The recommended 298 K rate constants, temperature-dependent parameters, and temperature ranges over which these recommendations are applicable are listed in Table 1.

Temperature Dependent Rate Constants for the Gas-Phase Reaction between OH and CH3OCl

1996 ◽  
Vol 100 (9) ◽  
pp. 3601-3606 ◽  
Author(s):  
John N. Crowley ◽  
Pedro Campuzano-Jost ◽  
Geert K. Moortgat
Keyword(s):  
Gas Phase ◽  
Rate Constants ◽  
Phase Reaction ◽  
Temperature Dependent ◽  
Gas Phase Reaction ◽  
Dependent Rate

scholarly journals Kinetics of the gas-phase reactions of OH radicals with alkanes and cycloalkanes

2003 ◽  
Vol 3 (4) ◽  
pp. 4183-4358 ◽  
Author(s):  
R. Atkinson
Keyword(s):  
Gas Phase ◽  
Rate Constants ◽  
Relative Rate ◽  
Oh Radicals ◽  
Reference Compound ◽  
Gas Phase Reactions ◽  
Temperature Dependent ◽  
Temperature Range ◽  
Dependent Rate ◽  
Kinetics Of

Abstract. The available database concerning rate constants for gas-phase reactions of the hydroxyl (OH) radical with alkanes through early 2003 is presented ove the entire temperature range for which measurements have been made (~180–2000 K). Measurements made using relative rate methods are re-evaluated using recent rate data for the reference compound (generally recommendations from this review). In general, whenever more than one study has been carried out over an overlapping temperature range, recommended rate constants or temperature-dependent rate expressions are presented.

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